Influence of Curing Systems on Mechanical, Dynamic, and Morphological Properties of Dynamically Cured Epoxidized Natural Rubber/ Copolyamide Blends

Article Preview

Abstract:

Thermoplastic elastomers (TPEs) based on dynamically cured epoxidized natural rubber/copolyamide (ENR/COPA) blends were prepared. Influence of curing systems (i.e., sulphur, peroxide, mixed sulphur and peroxide and phenolic resin cured systems on mechanical, dynamic and morphological properties of the blends were investigated. It was found that the blend with phenolic cured system exhibited superior mechanical and set properties. That is higher tendency to recover to its original shape after a prolong extension. It was also found that the blend with peroxide cured system exhibited higher storage modulus and complex viscosity than those of the blends with mixed sulphur and peroxide, phenolic and sulphur cured system, respectively. Furthermore, the TPVs blend with peroxide cured system showed the smallest vulcanized rubber particles.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

81-84

Citation:

Online since:

November 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] A. Ibrahim and M. Dahlan, Thermoplastic Natural Rubber Blends, Prog. Polym. Sci. 23 (1998) 665-706.

Google Scholar

[2] U. S. Ishiaku, B. T. Poh, A. Mohd Ishak and D. Ng, Mechanical and Thermo-oxidative Properties of Blends of Poly(vinyl chloride) with Epoxidized Natural Rubber and Acrylonitrile Butadiene Rubber in the Presence of an Antioxidant and a Base, Polym. Int. 39 (1996).

DOI: 10.1002/(sici)1097-0126(199601)39:1<67::aid-pi452>3.0.co;2-t

Google Scholar

[3] C. Nakason, A. Tobprakhon and A. Kaesaman, Thermoplastic Vulcanizates Based on Poly (methyl methacrylate) /Epoxidized Natural Rubber Blends: Mechanical, Thermal, and Morphological Properties, J. Appl. Polym. Sci. 98 (2005) 1251-1261.

DOI: 10.1002/app.21908

Google Scholar

[4] M. Narathichat, C. Kummerlowe, N. Vennemann and C. Nakason, Thermoplastic Natural Rubber Based on Polyamide-12: Influence of Blending Technique and Type of Rubber on Temperature Scanning Stress Relaxation and Other Related Properties, J. Appl. Polym. Sci. 121 (2011).

DOI: 10.1002/app.33528

Google Scholar

[5] I.K. Yang and P.H. Tsai, Intercalation and Viscoelasticity of Poly (ether-block-amide) Copolymer/Montmorillonite Nanocomposites: Effect of Surfactant. Polym. 47 (2006) 5131–5140.

DOI: 10.1016/j.polymer.2006.04.065

Google Scholar

[6] C. Nakason, M. Jarnthong, A. Kaesaman and S. Kiatkamjornwong, Influences of Blend Cured Proportions and Curing Systems on Dynamic, Mechanical, and Morphological Properties of Dynamically Epoxidized Natural Rubber/High-Density Polyethylene Blends, Polym. Eng. Sci. 49 (2009).

DOI: 10.1002/pen.21256

Google Scholar