Papers by Author: Hai Yang Bo

Abstract: Octadecyltrichlorosilane (OTS) was prepared on glass substrate to form self-assembled monolayer (OTS-SAM). The OTS-SAM was then UV-irradiated to endow the film with good chemisorption ability. Zirconia films were formed on silanol SAM by the LPD method. The phase structure and surface configuration of the zirconia films were studied by XRD and SEM respectively. The XRD results indicate that the as-deposited ZrO2 thin films are pure tetragonal phase after being annealed at 500°C for 1 h. SEM images show the zirconia film is uniform, but not very compacted.

Abstract: Polycrystalline BiFeO3 (BFO) thin films were grown via metal organic deposition method on OH-functionalized organic self-assembled monolayers (SAMs) on glass. The stable BiFeO3 precursor solutions were obtained by using iron nitrate and bismuth nitrate as raw materials, acetic acid and glycol as solvent and citric acid as chelating agent. Firstly, the preparation and functionalization of octadecyltrichlorosilane (OTS) self-assembled monolayers on the hydroxylated glass substrates was investigated. Water contact angle measurement and atomic force microscopy (AFM) confirmed the presence of a uniform, complete monolayer. After BiFeO3 was prepared on glass substrates, the film- forming and heat treatment processing of BiFeO3 films were studied. The BFO film was characterized with X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersion spectrograph (EDS). XRD pattern indicated that the grains of sample began to grow at 450 °C, and which was made up of BiFeO3 and some impure phase. With the increase of temperature, impure phase were disappeared and the intensity of diffraction peaks strengthened. Pure BiFeO3 phase were obtained at 500 °C ~ 600 °C. When the heat treatment temperature increased above 650 °C, the impure phase appeared. SEM showed that the BFO thin film possessed a dense microstructure on OH-functionalized SAMs.

Abstract: Bismuth ferrite powders were synthesized by a simple citric acid complexing co-precipitation method at much lower temperature of 600°C. The work studies the calcination temperature and molar ratio of Fe and Bi on the structure and morphology. The as-prepared BiFeO3 powder was characterized by X-ray diffraction, field emission scanning electron microscopy, transmission electron microscope and Fourier transform infrared spectrophotometer. The result shows that the phase pure BiFeO3 powders with cubic morphology were prepared as the calcination temperature was 600°C and molar ratio of Fe and Bi was 1:1. The nanoparticles was uniform with the size of about 200nm.

Abstract: HfO2 thin film was successfully prepared on the silicon substrate by the Liquid Phase Deposition (LPD) and functionalized organic self-assembled monolayers (SAMs) method. Measurement of contact angle showed that SAMs surface characteristics changed from hydrophobic to hydrophilic after UV irradiation. Photographs of Metallographic Microscope showed that octadecyl trichlorosilane-self- assembled monolayers (OTS-SAMs) had an active effect on the deposition of HfO2 thin film. XRD, SEM and AFM images indicated that the HfO2 thin film with cubic crystal structure was smooth, uniform and dense. Its grain size was between 40-100 nm and the height of thin film varies between 20 and 100 nm.