Papers by Author: Joong Hwan Jun

Abstract: Mechanical treatments such as deep rolling are known to affect the strength and toughness of metallic glass due to the residual stress. It is well known that compressive residual stress states usually enhance the mechanical properties in conventional metallic materials. We present investigations on the change of fracture behavior related with mechanical properties of “brittle” bulk metallic glass by cold rolling at room temperature. Improvement of the intrinsic plasticity is observed not only after constrained cyclic compression but also after cold rolling. Moreover, neither nanocrystallization nor phase separation occurs during deformation. By these findings we provide a unique fundamental basis by considering the introduction of structural inhomogeneity and ductility improvement in metallic glasses. The experimental evidence clearly supports that such an inhomogeneous glassy can be produced by residual stress in well known “brittle” bulk metallic glasses, and does not depend on a specific pinpointed chemical composition.

Abstract: Influences of Gd or Y addition on microstructures and tensile properties at room and elevated temperatures were investigated for T6-treated Mg-3%Nd-0.5%Zn-0.4%Zr casting alloys, on the basis of experimental results from X-ray diffractometry, scanning electron microscopy, transmission electron microscopy, energy dispersive spectroscopy, tensile and creep tests. Microstructures of the T6-treated alloys are characterized by recrystallized α-(Mg) grains containing various nano-sized precipitates such as Mg41Nd5, Zn2Zr3 and Zr particles. In T6 condition, most of added Gd and Y elements are dissolved in Mg41Nd5 precipitates rather than formation of new phases. Tensile properties and creep resistance of the Mg-3%Nd-0.5%Zn-0.4%Zr alloy are remarkably increased by the addition of Gd or Y, but their efficiencies are substantially the same.

Abstract: Influences of Ca addition on microstructures and mechanical properties at room and elevated temperatures have been investigated for Mg-1.5%Nd-1.0%RE-0.5%Zn-(0~1.0)%Ca casting alloys, on basis of experimental results from X-ray diffractometry (XRD), scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDS), tensile and creep tests. Microstructures of the alloys are characterized by dendritic α-(Mg) grains surrounded by Mg12Nd-Zn-(Ca) eutectic network phase. The average size of α grains decreases gradually with an increase in Ca content. At room temperature, yield strength (YS) is enhanced with increasing Ca content with a decrease in ultimate tensile strength (UTS) and elongation to fracture, whereas the Ca addition leads to greater YS and UTS at 175oC. The tensile creep strain and secondary creep rate, measured at 150 and 200oC under 100MPa for 100hrs, become lower with the increase in Ca content. The obtained tensile properties at elevated temperature demonstrate that the addition of Ca plays a role in improving high temperature mechanical properties including creep resistance for the Mg-Nd-RE-Zn-(Ca) alloys. In view of microstructural evolution, this would be attributed to the refined primary α grains and higher thermal stability of the Mg12Nd-Zn-Ca eutectic strengthening phase.

Abstract: Mg-3%Zn-0.2%Zr based alloy sheets with various alloying elements additions were fabricated through thermo-mechanical process, and their microstructure and mechanical properties were investigated at room and elevated temperatures. CCV(conical cup value) and V-bend tests were also carried out to evaluate the formability of the fabricated alloy sheets. The experimental results showed that small amounts of Sn or Sr additions could improve the elongation at elevated temperatures, even though the room temperature tensile properties were slightly deteriorated by the Sr addition.

Abstract: Two-step isothermal heating and conventional one-step heating processes were used to produce the semi-solid slurry of Mg-5%Zn-0.5%Zr alloys with and without 1%RE. It was found that the slurry with better semi-solid characteristics could be fabricated by the two-step heating compared to the conventional process. Only the small amount of RE addition to the Mg-5%Zn- 0.5%Zr alloy was observed to reduce the solid particle size of slurry significantly and to improve the tensile strength at 150oC, probably owing to Mg-Zn-RE phase with a high thermal stability.

Abstract: Changes in microstructure and damping capacity with aging time for solutionized AZ91 (Mg-9%Al-1%Zn-0.2%Mn) alloy have been investigated based on experimental results from optical micrography, X-ray diffractometry, hardness test and damping capacity measurement vibrating in a flexural mode. Discontinuous β (Mg17Al12) precipitates form along the primary grain boundaries, the amount of which increases as the aging time increases. The hardness of α matrix with respect to aging shows a typical “S” shape, indicating a generation of fine continuous precipitation in the matrix during aging. The peak level of damping capacity for the AZ91 alloy is obtained after 1 hour of aging, over which the damping capacity becomes deteriorated continuously. The optimum density of continuous β precipitates with fine morphology, which may well act as pinning points for dislocation lines, might be responsible for the improvement of damping capacity.

Abstract: A small amount of Zn or Sn was added to Mg-3%Al alloy to improve the formability of alloy. The elongation of as-rolled alloy was increased at both room temperature and 300oC by addition of Sn or Zn, even though the tensile strength at room temperature was remarkably increased only by Zn. When the as-rolled alloy was annealed to be fully recrystallized, the ductility at room temperature was significantly enhanced, however the elongation at 300oC was rather decreased probably attributed to the dynamic recrystallization occurred during the tensile test.

Abstract: The Effects of Li content and annealing treatment on microstructure and damping capacity for Mg-X%Li alloys have been investigated, based on experimental results from X-ray diffractometry (XRD), optical microscopy (OM), hardness tests and vibration damping tests in a flexural mode. The Mg-X%Li alloys containing Li of 3%, 8% and 13% consist of α (HCP) single phase, (α + β (BCC)) dual phases and β single phase, respectively. In as-rolled state, the damping capacity for Mg-Li alloys shows a similar level regardless of Li content. The annealing treatments at 200oC and 400οC give rise to an enhancement of damping capacity only for the Mg-3%Li and Mg-8%Li alloys containing α phase, and at the same annealing temperature, the Mg-3%Li alloy with fully α structure exhibits higher damping capacity. This result indicates that the damping capacity of Mg-Li alloys depends principally on α phase, and that the annealing treatment is necessary to improve its damping capacity.

Abstract: Microstructures and damping properties of semi-solid AM50 (Mg-5%Al-0.3%Mn) alloy were investigated and compared with those of die-cast AM50 alloy, based on experimental results of X-ray diffractometry (XRD), optical microscopy (OM), hardness tests and damping tests in a flexural mode. The semi-solid AM50 specimens show higher damping capacity than die-cast one in as-fabricated state, and the higher the fraction of solid α-(Mg), the greater the damping capacity. The annealing at 200oC deteriorates the damping properties of the semi-solid and die-cast specimens. This would be due to the segregation of solute atoms on dislocation lines, which eventually leads to lower internal friction by the restriction of dislocation movement. The peak damping values of the AM50 specimens are obtained after annealing at 400oC. The disappearance of segregates acting as pinning points of dislocations is thought to be responsible for the improvement in damping capacity. This result implies that the presence of solid α-(Mg) phase and annealing treatment at high temperature are beneficial to damping property of AM50 alloy.