Papers by Author: Katja Tonisch

Abstract: Scandium aluminum nitride (ScxAl1-xN) is a promising material for sensor applications as it exhibits enhanced piezoelectric properties compared to pristine AlN while maintaining other advantageous properties like high thermal stability. Magnetoelectric sensors in particular are used to detect magnetic fields which leads to special requirements regarding the investigated ScAlN in order to achieve high sensor sensitivities. Co-sputtered ScAlN layers are investigated in this work using XRD, XPS, FTIR and Raman spectroscopy for scandium concentrations from 0 to 34 %. The impact of Sc incorporation regarding residual biaxial strain and bond softening is discussed on basis of the experimental results. The activity of the B1 and E2 modes found in the FTIR measurements is of special interest as the presumably oxygen related excitation is expected to influence the piezoelectric properties.

Abstract: Al0.35Ga0.65N/GaN- and Al0.2Ga0.8N/AlN/GaN-heterostructures high electron mobility transistors (HEMTs) with a gate length (LG) varying from 1.2 to 0.08 µm were fabricated on silicon Si(111) substrates using a 3C-SiC transition layer. Metal organic chemical vapour deposition (MOCVD) was used to growth the AlGaN-heterostructures and a low pressure chemical vapour deposition (LPCVD) to create the 3C-SiC(111) transition layer preventing Ga-induced melt back etching and Si-out diffusion. Reduced Al content and an AlN interlayer improved the device performance. The HEMTs with LG=0.08µm had a maximum drain current density of 1.25 A/mm and a peak extrinsic transconductance of 400 mS/mm. A unity current gain cut-off frequency (ƒT) of 180 GHz and maximum frequency (ƒmax) of 70 GHz were measured on these devices.

Abstract: The growth of AlGaN solid solutions on 3C-SiC(111)/Si(111) is demonstrated. The residual stress of the grown layer was investigated by high resolution X-ray diffraction (HRXRD) and infrared ellipsometry. Analysis of the HRXRD data showed that the observed lattice distortion was caused partially by hydrostatic pressure and partially by biaxial tension. The residual stress depends on the layer composition and weakly on the growth temperature.

Abstract: Heteroepitaxial AlGaN/GaN on SiC/Si pseudosubstrate was used to fabricate three-terminal junction devices. Narrow bar and wide bar type active regions were fabricated. The measurement at room temperature showed predicted nonlinear behavior (previously reported about as negative type rectification). Unusual, positive type rectification for two dimensional electron gases was also observed. The electrical characteristics depend on the geometrical configuration of the devices.

Abstract: The manipulation of nucleation and growth conditions with Ge deposition prior to the carbonization and epitaxial growth changes the residual stress and the material quality of 3C-SiC(100)-layers grown on Si(100). This enables the modification of quality factor and resonant frequency of microelectromechanical systems (MEMS) based on 3C-SiC-layers. Measured resonant frequencies and quality factors of the magnetomotively actuated MEMS exhibit a dependence on the Ge amount at the interface of the Si/SiC heterostructure. This offers a degree of freedom to adjust the MEMS properties within a certain range to the requirements necessary for specific applications. The observed dependencies of the Young’s modulus are in good agreement with the trends of residual stress and Young’s modulus, which were determined on as grown 3C-SiC(100):Ge samples by fourier transform infrared (FTIR) spectroscopy and nanoindentation.

Abstract: We present the realization of high electron mobility transistors (HEMTs) based on AlGaN/GaN heterostructures grown on silicon substrates using a SiC transition layer. The growth of AlGaN/GaN heterostructures on Si (111) was performed using metalorganic chemical vapour deposition (MOCVD). The (111) SiC transition layer was realized by low pressure CVD and prevented Ga-induced meltback etching and Si-outdiffusion in the subsequent MOCVD growth. The two-dimensional electron gas (2DEG) formed at the AlGaN/GaN interface showed an electron sheet density of 1.5x1013 cm-3 and a mobility of 870 cm²/Vs proving the high structural quality of the heterostructure. Device processing was done using electron beam lithography. DC and RF characteristics were analysed and showed a peak cut-off frequency as high as 6 GHz for a 1.2 µm gate HEMT.

Abstract: In order to realize complex three dimensional or free standing structures on SiC substrates, an undercut, i.e. a selective isotropic etching process of SiC, is required. This was realized using an electron cyclotron resonance etching set up with pure SF6 and a SF6/Ar gas composition at elevated substrate temperatures. Above 350°C a significant lateral etch component was observed, which rose to a value of 50-70 nm/min increasing the substrate temperature up to 570°C during the etching process. Depending on substrate temperature the etching profiles and surface roughness were studied. Based on an analysis of the influence of microwave power, working pressure, bias voltage, gas flow and gas mixture on the etching behavior a novel isotropic, high selective, residue free etch process for SiC was developed, which allows for example the fabrication of piezoelectric actuated AlGaN/GaN resonators grown on SiC substrates.

Abstract: With the increasing requirements for microelectromechanical systems (MEMS) regarding stability, miniaturization and integration, novel materials such as wide band gap semiconductors are receiving more attention. The outstanding properties of group III-nitrides offer many more possibilities for the implementation of new functionalities and a variety of technologies are available to realize group III-nitride based MEMS. In this work we demonstrate the application of these techniques for the fabrication of full-nitride MEMS. It includes a novel actuation and sensing principle based on the piezoelectric effect and employing a two-dimensional electron gas confined in AlGaN/GaN heterostructures as integrated back electrode. Furthermore, the actuation of flexural and longitudinal vibration modes in resonator bridges are demonstrated as well as their sensing properties.

Abstract: Electrical, thermal and chemical properties of Ti/Al/Ti/Au ohmic contacts with different former Ti-Al ratio are investigated for application in GaN HEMTs. Lowest resistivity of 4.22x10-5 Ω.cm2 has been obtained to the channel of the HEMT structure. It is found out that the initial Ti/Al ratio influences the optimal annealing temperature at which the lowest resistivity is obtained and the element distribution and interface chemistry of the annealed contacts. XPS analysis revealed two compounds contributing to ohmic properties: an intermetal compound AlAu2 in the contact layer and a semimetal TiN at the interface with GaN.

Abstract: Cubic gallium nitride epitaxial layers grown on differently carbonized silicon substrates were studied by high resolution X-ray diffraction. In the case of cubic GaN layers with equal layer thickness an improvement of the layer quality in terms of full width of the half maximum can be achieved by using higher carbonization temperatures. The higher crystalline quality led to an in¬crease of the residual stress in the grown layer. An increase in the thickness of the cubic Gallium Nitride allows to improve the crystallinity and to reduce the residual stress.