Papers by Author: Mok Soon Kim

Abstract: The rod-shaped bulk composites consisting of Al-10Ni-6Ce and Al-4Fe-0.6Mo-1.1V- 0.3Zr alloy (mixing ratio; 0.7:0.3, 0.5:0.5 and 0.3:0.7) and corresponding monolithic alloys were produced to a full density via powder forging process. The process involved pre-compaction of rapidly solidified alloy powders and subsequent isothermal forging at 673K. The forged Al-10Ni- 6Ce alloy exhibited nano-scaled crystalline particles, such as fcc-Al, Al3Ni, Al4Ce and Al11Ce3 phase, coexisting with an amorphous phase. In the case of the forged Al-4Fe-0.6Mo-1.1V-0.3Zr alloy, an equiaxed grain structure was observed to exist with uniformly distributed nano-scaled Al- Fe based intermetallics. The monolithic Al-10Ni-6Ce alloy had a considerably high maximum compressive strength (MCS) of 1.35 GPa without showing any compressive plastic strain (CPS). In contrast, the monolithic Al-4Fe-0.6Mo-1.1V-0.3Zr alloy possessed noticeably high CPS of 25% with the MCS of 0.71GPa. The composites acquired the CPS varying from 1 to 5.8 % and the MCS from 1.26 to 0.74 GPa, with increment of the volume fraction of Al-4Fe-0.6Mo-1.1V-0.3Zr alloy from 0.3 to 0.7.

Abstract: We report on advanced Ni3Al based high temperature structural alloys with refractory alloying elements such as Zr and Mo to be apllied in the fields of die-casting and high temperature press forming as die materials. The duplex microstructure consisting of L12 structured Ni3Al phase and Ni5Zr intermetallic dispersoids was observed to display the microstructural feature for the present alloys investigated. Depending on alloying elements, the volume fraction of 2nd phase was measured to be different, indicating a difference in solid solubility of alloying elements in the matrix γ’ phase. Lattice parameter of matrix phase increased with increasing content of alloying elements. In the higher temperature region more than 973K, the present alloys appeared to show their higher strength compared to those obtained in conventional superalloys. On the basis of experimental results obtained, it is suggested that refractory alloying elements have an effective role to improve the high temperature strength in terms of enhanced thermal stability and solid solution hardening.

Abstract: The mechanical properties of pre-sintered Al-10Si-5Fe-1Cu-0.5Mg-1Zr (wt%) alloy were investigated in the temperature range from 673K to 813K and at initial strain rates from 10-4 to 100 s-1. In the high temperature range of 793K and 813K, the strain rate sensitivity index was close to that for superplasticity (0.3). Stress exponent was estimated to be 2 and 5 in the temperature range from 793K to 813K and from 673K to 773K, respectively. The activation energies for the plastic flow were calculated to 77kJ/mol for the n=2 region and 127kJ/mol for the n=5 region. These values were close to that for grain boundary diffusion and self-diffusion in pure aluminum, respectively. We found that a dynamic recrystallization (DRX) and grain boundary sliding (GBS) occur depending on the test temperature and stain rate. A filament-like phase containing Cu and Mg was observed in the cracked surface of the specimen deformed at 793K and 813K.

Abstract: Three layer clad brazing sheets composed of Al-7.5Si alloy (filler, thickness:10 ㎛ )/Al-1.2Mn-2Zn-(0.04-1.05)Si alloy (core, thickness:80 ㎛)/Al-7.5Si alloy (filler, thickness:10 ㎛), were produced by laboratory fabrication, through casting, hot rolling, cold rolling, intermediate annealing, and final cold rolling. The effects of Si content in the core(0.04-1.05wt.%) and reduction rate of the final cold rolling(10-45%) on microstructure and brazing behavior were investigated. The results revealed that the microstructure and brazeability of the brazing sheet are governed both by Si content in the core and by the reduction rate of the final cold rolling. The excellent brazeability was obtained when the core alloy has the Si content of/cold rolled to 0.04%/10-45%, 0.41%/20-45% and 0.64%/30-45%. In these cases, a coarse grain structure was developed in the core during the brazing process, which suppressed the penetration of melting filler into the core.

Abstract: Mechanical properties of a nano-structured Al-8Fe-2Mo-2V-1Zr alloy produced by spray forming and subsequent hot-extrusion at 420°C were investigated in terms of tensile test as a function of temperature. Warm rolling was adapted as an additional process to expect further refinement in microstructure. Well-defined equiaxed grain structure and finely distributed dispersoids with nano-scale in particle size were observed in the spray formed and hot extruded sample (as-received sample). The average grain size and particle size were measured to 500 nm and 50 nm, respectively. While it was found that warm rolling gives rise to precipitate fine dispersoids less than 10 nm without influencing the grain size of matrix phase, in the temperature range of RT∼150°C, distinguishable changes in ultimate tensile strength were not found between the as-received and warm-rolled samples. At elevated temperatures ranging from 350 to 550°C, warm-rolled sample showed a higher value of elongation than as-received one although similar values of elongation were observed between two samples at temperatures lower than 350°C.

Abstract: Microstructure and mechanical property at room temperature and at 1773 K of Nb-Si based refractory intermetallic alloys were investigated in terms of compression and fracture toughness test. Mo and V were chosen as ternary alloying elements because of their high melting points, atomic sizes smaller than Nb. Both ternary alloying elements were found to have a significant role in modifying the microstructure from dispersed structure to eutectic-like structure in Nb solid solution/Nb5Si3 intermetallic composites. The 0.2% offset yield strength at room temperature increased with increasing content of ternary elements in Nb solid solution and volume fraction of Nb5Si3. At 1773 K, Mo addition has a positive role in increasing the yield strength. On the other hand, V addition has a role in decreasing the yield strength. The fracture toughness of ternary alloys was superior to binary alloys. Details will be discussed in correlation with ternary alloying, volume fraction of constituent phase, and the microstructure.

Abstract: It is well known that magnesium alloys have difficulties in room temperature formability because of their HCP structure. As a basic approach to enhance a cold formability, a new combination process including an extrusion followed by a cold equal channel angular pressing (ECAP) was attempted. ECAP die has an inner die corner angle of 135 degree, the fillet angle of 45 degree and thickness of 5mm. A finite element analysis with a three-dimensional thermo-coupled elasto-plastic model was also carried out to understand the change of stress and strain during ECAP. Experiments showed that the AZ31 alloy, which is extruded at a ratio of 20 and is heat-treated at 350°C, was successful in a cold ECAP. From the simulated results, it was found that the effective strain gradually decreased from the inner die side (0.533) to the outer die side. This was confirmed by the analytical analysis via von Mises criterion. Furthermore, it also matched well with the experiments, which showed a uniform shear deformation band. It was also interesting to note that compressive yield strength was drastically increased, which is caused by the occurrence of numerous twins spread across the materials during a cold ECAP.

Abstract: The bulk Al84Ni10Ce6 alloy was fabricated by a powder forging process. The process involved pre-compaction of amorphous powder by cold pressing and subsequent isothermal forging at temperatures from 523 to 823K with the strain rate of 10-2 s-1. The porosity decreased rapidly with increasing forging temperature up to 648K, and a fully dense bulk specimen with the porosity less than 1% was achieved when the forging was carried out at and above 648K. TEM observation on the fully dense bulk alloys revealed a mixed structure consisting of nano-scaled crystalline particles and amorphous matrix. It was also revealed that the size and volume fraction of the crystalline phases increased with increasing forging temperature. Noticeably high compressive fracture strength of 1355MPa and Vickers hardness number of 530 were obtained at room temperature for the fully dense bulk specimen forged at 648K, which contains the refined crystalline particles (average size: 28nm, volume fraction: 44%) in an amorphous matrix.

Abstract: The microstructure and mechanical property of Al 5083 alloy produced by spray forming and then subsequent hot extrusion at 693 K were investigated. In order to compare the mechanical property and microstructure permanent casting and hot extrusion was also carried out in air. The spray formed Al 5083 alloy showed the microstructure consisting of Al matrix phase, MnAl6, FeAl6 and Mg2Al3 dispersoids. This microstructural feature analyzed is quite similar to Al5083 alloy prepared by conventional casting. However, a noticeable difference in grain size appeared between those alloys with different processing. It is found that spray forming plays an effective role to reduce the grain size of the present Al 5083 alloy. At room temperature, the yield strength of spray formed alloy was higher than that of permanent casting alloy. At high temperature, spray forming appeared to display a higher elongation value than conventional casting. It is therefore suggested that spray forming of the present Al 5083 alloy promotes to increase yield strength at room temperature and to increase elongation at high temperature. Details will be discussed in relation with the results obtained.

Abstract: The porous Ti-45at.%Al-1.6at.%Mn intermetallic alloys were fabricated by reactive sintering process using warm extruded mixtures consisting of elemental titanium and aluminum alloy powders and subsequent heat treatment. At the extrusion stage, three different extrusion ratios were tried in order to provide the various types of porous structure in the microstructure. It was clearly found that the shape of pore and porosity are largely dependent on extrusion ratio. With increasing extrusion ratio the porosity decreased, on the other hand, aspect ratio of porous structure increased. The porosity measured was in the range from 35% to 45%. The maximum porosity of 45% can be obtained when the specimen was reactively sintered with the extrusion ratio of 1. A directionality of pores oriented parallel to the extrusion direction was found when the extrusion ratio of powder mixtures is 6 and above.