Papers by Author: P. R. Munroe

Abstract: Lamellar bands are the primary structural features in accumulative roll bonding (ARB) of sheet metals. The structural refinement in ARB sheets occur by forming a dense distribution of lamellar band boundaries. The lamellar band boundaries initiate as low angle interfaces, parallel to the existing lamellar band boundaries, irrespective of the crystallographic orientations of the parent lamellar bands. From an extensive investigation it was found that the transverse directions across the lamellar band boundaries are rotated by an angle equal to their misorientations. Such a phenomenon is not sustained when the boundaries turn to high angle.

Abstract: Cu-(2.5 or 5.0vol.%)Al2O3 nanocomposite balls and granules and Cu-(2.5vol.% or 5.0vol.%)Pb alloy powder were prepared by high energy mechanical milling (HEMM) of mixtures of Cu and either Al2O3 or Pb powders. It was observed that with the increase of the content of Al2O3 nanoparticles from 2.5vol.% to 5vol.% in the powder mixture, the product of HEMM changed from hollow balls into granules and the average grain size and microhardness changed from approximately 130nm and 185HV to 100nm and 224HV, respectively. On the other hand, HEMM of Cu–(2.5 or 5.0vol.%) Pb powder mixtures under the same milling conditions failed to consolidate the powder in-situ. Instead, it led to formation of nanostructured fine powders with an average grain size of less than 50nm. Energy dispersive X-ray mapping showed homogenous distribution of Pb in the powder particles in Cu–5vol.%Pb alloy powder produced after 12 hours of milling. With the increase of the Pb content from 2.5 to 5.0 vol.%, the average microhardness of the Cu-Pb alloy powder particles increases from 270 to 285 HV. The mechanisms of the effects are briefly discussed.

Abstract: The wear behaviour of Ca a-sialon ceramics of two distinct microstructures, fine equiaxed grains (EQ) and large elongated grains (EL), with the same chemical composition was investigated as a function of apparent contact pressure and sliding speed, using ball-on-disc type tribometers at room temperature and at 600°C. For room temperature tests, the EL microstructure exhibited a lower wear rate than EQ in the severe wear regime due to a greater resistance to large crack-induced material removal. As the apparent contact pressure decreased, mild wear appeared for both microstructures. The mechanism that dominated the material removal in EQ was grain pullout. In contrast, the controlling mechanism for EL was transgranular fracture. Therefore, EL had a lower wear rate than EQ in the mild wear regime. For wear tests at 600°C, crack-induced severe wear occurs in both EQ and EL samples for all contact pressures. EL had a slightly lower wear rate than EQ. Wear particles were generated on the wear track, but no tribofilm was observed and no oxidation products were detected. Wear models revealed that the grain aspect ratio plays a more important role than grain diameter in influencing the crack propagation during severe wear and grain pull-out during mild wear.