Authors: Ho Jun Lee, Boum Young Park, Hyun Seop Lee, Suk Hoon Jeong, Heon Deok Seo, Suk Bae Joo, Hae Do Jeong, Hyoung Jae Kim
Abstract: Silicon carbide (SiC) is a wide band gap semiconductor being developed for high
temperature, high power, and high frequency device applications. For the manufacturing of SiC to
semiconductor substrate, many researchers have studied on the subject of SiC polishing. However,
SiC faces many challenges for wafer preparation prior to epitaxial growth due to its high hardness and
remarkable chemical inertness. A smooth and defect free substrate surface is important for obtaining
good epitaxial layers. Therefore, hybrid process, chemical mechanical polishing (CMP) has been
proposed to achieve epi-ready surface.
In this paper, the material removal rate (MRR) is investigated to recognize how long the CMP
process continues to remove a damaged layer by mechanical polishing using 100 nm sized diamond,
and the authors tried to find the dependency of mechanical factors such as pressure, velocity and
abrasive concentration using single abrasive slurry (SAS). Especially, the authors tried to get an
epi-ready surface with mixed abrasive slurry (MAS). The addition of the 25nm sized diamond in
MAS provided strong synergy between mechanical and chemical effects resulting in low subsurface
damage. Through experiments with SAS and MAS, it was found that chemical effect (KOH based)
was essential and atomic-bit mechanical removal was efficient to remove residual scratches in MAS.
This paper concluded that SiC CMP mechanism was quite different from that of relatively soft
material to achieve both of high quality surface and MRR.
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Authors: Han Chul Cho, Suk Hoon Jeong, Jae Hong Park, Ho Jun Lee, Ji Heon Oh, Hyoung Jae Kim, Hae Do Jeong
Abstract: Lithium niobate (LN, LiNbO3) is a kind of artificial crystal with piezoelectricity,
pyroelectricity and ferroelectricity, which has been widely used in electron components. The large
difference in thermal expansion coefficients between Si and LN causes a serious thermal stress during
the thermal-pressure bonding process. Therefore room temperature bonding would be the best
candidate to make strong and stress-free interface between Si and LN. However, room temperature
bonding requires lower surface roughness (Ra<2nm) and lower defects on the LN wafer surface than
those of thermal bonding. Chemical mechanical polishing (CMP) process helps LN to obtain the high
quality surface and thin wafer suited in room temperature bonding. The LN wafer was polished using
colloidal silica slurry, resulting in high material removal rate (MRR) and fine surface quality under
the condition of low pH, high abrasive concentration and low flow rate. The polishing mechanism of
LN was discussed by mechanical, chemical and thermal analysis.
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Authors: Suk Hoon Jeong, Suk Bae Joo, Ho Jun Lee, Boum Young Park, Hyoung Jae Kim, Hae Do Jeong
Abstract: Chemical mechanical polishing (CMP) has been used as planarization process in the
fabrication of semiconductor devices. The CMP process is required to planarize the overburden film
in an interconnect process by high relative velocity between head and platen, high pressure of head
and chemical effects of an aqueous slurry. But, a variety of defects such as dishing, delamination and
metal layer peering are caused by CMP factors such as high pressure, pad bending and strong
chemical effect. The electrical energy of the electro-chemical mechanical planarization (ECMP)
dissolves copper (Cu) solid into copper ions electrochemically in an aqueous electrolyte. The
dissolved copper complex layer or passivation layer is removed by the mechanical abrasions of
polishing pad and abrasive. Therefore the ECMP process realizes low pressure processing of soft
metals to reduce defects comparing to traditional CMP process. But, if projected metal patterns were
removed and not remained on whole wafer surface in final processing stage, Cu layer could not be
removed by ECMP process.
The two-step process consists of the ECMP and the conventional CMP used in micro patterned Cu
wafers. First, the ECMP process removed several tens 'm of bulk copper on Cu patterned wafer
within shorter process time than the Cu CMP. Next, residual Cu layer was completely removed by the
Cu CMP under low pressure. Total time and process defects are extremely reduced by the two-step
process.
117
Authors: Suk Hoon Jeong, Heon Deok Seo, Boum Young Park, Jae Hong Park, Sung Min Park, Sang Chul Kim, Kee Ho Kim, Hae Do Jeong
Abstract: As copper technology moves from pilot to volume manufacturing, semiconductor
fabrication is focused on methods to improve device yield. In especially semiconductor
manufacturing, electrochemically deposited copper is the material of choice for advanced
interconnect applications. Electrochemical deposition (ECD) employs copper plating electrolytes
with organic additives to achieve bottom-up filling of small vias and trench with high aspect-ratios.
However, for features with small aspect-ratios, the ECD process yields conformal layers because
the additives and the bottom-up fill mechanism are not operative in such large features. So, ECD
process does not achieve within-die and within-wafer planarity of the deposited copper layer. For
planarization of large features and obtaining globally and locally flat films, an electro-chemical
mechanical deposition (ECMD) method has been employed. ECMD process is a novel technique
that has ability to deposit planar conductive films on non-planar substrate surfaces. Technique
involves simultaneous ECD roles and mechanical sweeping of the substrate surface. Copper layer
deposited by the ECMD process grows preferentially in cavities on the wafer surface yielding flat
profiles and much reduced overburden thickness. Preferential deposition into the cavities on the
substrates surface may be achieved through two different mechanisms. The first mechanism is more
mechanical in nature and it involves material removal from the top surface. The second mechanism
is more chemical in nature and it involves enhancing deposition into the cavities where mechanical
sweeping does not reach, and reducing deposition onto surfaces that are swept. Planar layers
obtained by the ECMD technique are suitable for low stress material removal processes. Planar
layers also yield improved parametric results in device structures after the material removal step. In
this study, we demonstrate mechanical role of pad gives effects in ECMD process. So we evaluate
gap-filling and planarization between ECMD and ECD.
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