Authors: Dang Quan Zhang, Qing Zhi Ma, Qi Mei Liu, Wan Xi Peng, Huai Yun Zhang, Kuan Peng, Zheng Jun Gu, Mo Hua Yang
Abstract: Pinus massoniana Lamb has been used to heal some specific diseases in the Chinese Folk for a long time. In order to explore the wide utilization in biomedicine and spicery, the chemical components of helium extractives from the fresh wood of Pinus massoniana Lamb was studied by TD-GC/MS. The results showed that the main components were 1,4-Methanoazulene, decahydro-4,8, 8-trimethyl-9-methylene- (29.98%), 1,4-Methanoazulen-9-ol, decahydro-1,5,5,8a-tetramethyl- (10.32%), 1R-.alpha.-Pinene (8.33%), 1,2,4-Methenoazulene, decahydro-1, 5,5,8a-tetramethyl- (4.72%), Borneol (2.99%), Thujopsene (2.80%), 1-Phenanthrenecarboxaldehyde, 7-ethenyl-1,2,3,4,4a,4b, 5,6,7,9,10,10a- dodecahydro-1,4a,7-trimethyl- (2.53%), Bicyclo[2.2.1]heptan-2-one, 1,7,7- trimethyl-, (1R)- (2.52%), Caryophyllene oxide (2.40%), Tricyclo[5.4.0.0(2,8)]undec-9-ene, 2,6,6,9-tetramethyl- (2.32%), 1,3-Benzodioxole, 5-(2-propenyl)- (2.274%), Acetic acid (2.07%), Eucalyptol (1.70%), Eucalyptol (1.70%), Benzaldehyde, 4-hydroxy- (1.61%), etc. The analytical result suggested that the helium extractives from the fresh wood of Pinus massoniana Lamb could be used as industrial materials of biomedicines and spicery.
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Authors: Zhong Feng Zhang, Ming Long Zhang, Feng Juan Wu, Wan Xi Peng
Abstract: Pinus massoniana resources have been used as meidicine for a long time. Therefore, the 120°С volatiles of Pinus massoniana biomass were identified by TD-GC/MS. The main function components of Pinus massoniana Lamb biomass at 120°С were 1,4-methanoazulene, decahydro-4,8, 8-trimethyl-9-methylene-(36.04%), 1,4-methanoazulen-3-ol, decahydro-1,5,5,8a-tetramethyl-(13.95%), .alpha.-pinene(9.36%), 1,2,4-methenoazulene,decahydro-1,5,5,8a-tetramethyl-(5.95%), tricyclo[5.4.0.0(2,8)]undec-9-ene, 52,6,6,9-tetramethyl-(3.74%), caryophyllene oxide(2.9%), tricyclo[5.4.0.0(2,8)]undec-9-ene, 2,6,6,9-tetramethyl-(2.87%), bicyclo[2.2.1]heptan-2-one, 1,7,7- trimethyl-, (1r)- (2.82%), p-menth-1-en-8-ol(1.92%), 1,3-benzodioxole, 5-(2-propenyl)- (1.4%), (+)-longicamphenylone(1.39%), eucalyptol(1.21%), etc. It showed that the volatiles of Pinus massoniana Lamb biomass at 120°С had some biohealth function.
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Authors: Wan Xi Peng, Qiu Xue, Feng Juan Wu, Xu Zhang, Zhong Feng Zhang
Abstract: In order to evaluate its potential health risk to human settlements, the volatiles of Pinus massoniana biomass which was used indoor, were adsorbed and determined by TD-GC-MS. And the main constituents of volatiles at 40°С were 1,4-methanoazulene,decahydro-4,8,8-trimethyl-9- methylene-(53.09%), bicyclo[2.2.1]heptan-2-one, 1,7,7- trimethyl-(11.4%), cyclooctasiloxane, hexadecamethyl-(9.28%), octasiloxane, 1,1,3,3,5,5,7,7,9,9, 11,11,13,13,15,15-hexadecamethyl- (5.09%), 1,3-benzodioxole, 5-(2-propenyl)- (3.19%), p-menth-1-en-8-ol(2.93%), tricyclo[5.4.0.0 (2,8)] \undec-9-ene, 2,6,6,9-tetramethyl-(2.43%), eucalyptol(2.03%), etc. The main constituents of volatiles at 60°С were 1,4-methanoazulene,decahydro-4,8, 8-trimethyl-9-methylene-(43.43%), bicyclo[2.2.1]heptan-2-one, 1,7,7- trimethyl-, (1r)- (7.34%), 1,6,10-dodecatriene, 7,11-dimethyl-3- methylene-(6.63%), 1,4-methanoazulen-9-ol,decahydro-1,5,5,8a-tetramethyl-(5.9%), octasiloxane, 1,1,3,3,5,5,7,7,9,9, 11,11,13,13,15,15-hexadecamethyl-(4.24%), 1r-.alpha.-pinene(4.1%), etc. So the Pinus massoniana biomass was safe under 60°С.
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Authors: Qing Zhi Ma, Feng Juan Wu, Dang Quan Zhang, Wan Xi Peng
Abstract: Black bamboo is becoming a major biomass in rooms. Therefore, the chemical components from black bamboo were identified by TD-GC/MS. The main function components of black bamboo biomass at 40°С were acetic acid(24.71%), 1,1,1,5,7,7,7-heptamethyl-3,3-bis(trimethylsiloxy)tetrasiloxane(17.58%), 1h-indole-2-carboxylic acid,6-(4-ethoxyphenyl)-3-methyl-4-oxo-4,5,6,7-tetrahydro-, isopropyl ester(16.85%), cyclooctasiloxane, hexadecamethyl-(15.28%), cyclotrisiloxane, hexamethyl-(4%), etc. And the main function components at 50°С were acetic acid(40.39%), 1,1,1,5,7,7,7-heptamethyl-3,3-bis(trimethylsiloxy)tetrasiloxane(24.47%), octasiloxane,1,1,3,3,5,5,7,7,9,9, 11,11,13,13,15,15-hexadecamethyl-(16.39%), bicyclo[2.2.1]heptan -2-one, 1,7,7- trimethyl-, (1s)- (3.73%), tricyclo[2.2.1.0(2,6)]heptane, 1,7-dimethyl-7-(4-methyl-3-pentenyl)- , (-)-(3.57%), etc. Black bamboo biomass was more healthy to human at 40°С than 60°С. So black bamboo biomass was fit to use in rooms.
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Authors: Wan Xi Peng, Lan Sheng Wang, Qing Ding Wu, Shi Long Xiang
Abstract: Poplar composite biomaterial, which self bonded under high temperature and pressure, is a new indoors materials. In order to evaluate its potential health risk to human settlements, the volatile organic compounds of poplar composite biomaterial were adsorbed and determined by TD-GC-MS. The result were: (1) The main constituents of volatiles at 40°С were acetic acid(50.6%), 1,2-benzenedicarboxylic acid, mono(2-ethylhexyl) ester(8.48%), [1,1':3',1''-terphenyl]-2'-ol(3.98%), 1,2-propanediol, 3-benzyloxy-1,2-d iacetyl-(3.12%), etc. (2) The main constituents of volatiles at 60°С were acetic acid(46.7%), 1,2-benzenedicarboxylic acid, mono(2-ethylhexyl) ester(7.93%), cedrol(5.53%), butane, 1-(benzyloxy)-2-[(benzylox y)methyl]- (5.43%), [1,1':3',1''-terphenyl]- 2'-ol(3.72%), 1-propene, 3-(2-cyclopentenyl)-2-m ethyl-1,1- diphenyl-(3.18%), etc. Generally, the poplar composite biomaterial was safe under 40-60°С.
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Authors: Qing Zhi Ma, Feng Juan Wu¨, Dang Quan Zhang, Wan Xi Peng
Abstract: Phyllostachys heterocycla, who was considered to have biohealth function in folk, is becoming a major biomass in rooms. Therefore, the chemical components from Phyllostachys heterocycla were identified by TD-GC/MS at different temperature. The main function components of Phyllostachys heterocycla biomass at 40°С were 1,2-benzenedicarboxylic acid, mono(2-ethylhexyl) ester(21.32%), [1,1':3',1''-terphenyl]-2'-ol(9.16%), (2,3-diphenylcyclopropyl)methyl ph enyl sulfoxide, trans-(6.54%), cedrol(6.11%), bicyclo[2.2.1]heptan-2-one, 1,7,7- trimethyl-, (1r)- (6.04%), 1,6-cyclodecadiene, 1-methyl-5-met hylene-8-(1-methylethyl)- (4.82%), 1-heptadecanamine(4.79%), propanedioic acid, methyl-, diethy l ester(4.36%), squalene(4.25%), etc. And the main function components at 60°С were1,2-benzenedicarboxylic acid, mono(2-ethylhexyl) ester(14.02%), camphor(10.57%), [1,1':3',1''-terphenyl]-2'-ol(6.91%), pentanoic acid, 2-benzenmethanimin yl-5-guanidinyl-(5.68%), 1,6-cyclodecadiene, 1-methyl-5-methyl- (5.27%), cedrol(4.83%), 2-bromo-2,2-dichloroethylcarbamic acid, ethyl ester(4.56%), n-n-butylpropionamide(4.49%), bicyclo[3.1.1]heptane, 6,6-dimethy l-2-methylene-, (1s)- (4.12%), etc. Phyllostachys heterocycla biomass was more healthy to human at 40°С than 60°С. So Phyllostachys heterocycla biomass was fit to use after drying.
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