Authors: Ke Wei Fang, Guan Jun Li, Guang Fu Li, Wu Yang, Mao Long Zhang, Zhi Yuan Sun
Abstract: The microstructures and mechanical properties of a dissimilar metal weld A508/52M/316L used in the primary water system of pressurized water reactor (PWR) nuclear power plants were investigated. The weld exhibits complicated microstructures, with significant change around the interfaces A508/52M and 52M/316L. The variations of main elements in 52M weld metal are greater than those in the A508 and 316L, with significant changes in the zones closed to the interfaces. The bulk 52M weld metal has higher and more uneven hardness than both of the base metals A508 and 316L. The HAZ of A508 exhibits the highest hardness value in the weld. The area around the A508/52M interface is the most weak part for stress corrosion cracking (SCC) resistance of the weld in simulated PWR primary water at 290°C. SCC was only found in the specimens tested at +200mV(SHE) but not in those tested at both -780mV and Ecorr (about -500mV).
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Authors: Guang Fu Li, Chun Bo Huang, Hao Guo, Wu Yang
Abstract: Stress corrosion cracking (SCC) behaviors of pipeline steel X70 in various near-neutral pH
soil environments with characteristics of eastern China have been studied through electrochemical
measurements and slow strain rate tests (SSRT) at various electrode potentials in four solutions
containing different typical soils in eastern China as well as in NS-4 solution. The SCC susceptibility
in the four soil solutions was generally higher than that in NS-4 solution. There was a general trend
that SCC susceptibility increased with decreasing the potential, suggesting that hydrogen induced
cracking probably plays a key role in the cracking at least at low potentials and the parameters of
cathodic protection in engineering should be carefully optimized to avoid SCC.
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Authors: Guang Fu Li, Guo Liang Zhang, Jian Jiang Zhou, Chun Bo Huang, Wu Yang
219
Authors: Hao Guo, Guang Fu Li, Xun Cai, Jiasheng Bai, Wu Yang
Abstract: Crack propagation of X-70 pipeline steel in near-neutral pH solution was studied under different modes of cyclic loading. A revised equation of crack growth rate vs. Δ K was obtained. Average crack growth rate increased with cycles under conditions of different R values. Linear shape notch specimen made cracks much easier to initiate and propagate than V-shaped notch specimen did. For different R values, the curves of crack growth rate with cycles were similar, but the platform
propagation period and quick propagation period were different obviously. Crack growth rate at both periods increased and thus failure time decreased markedly with decrease of R value. The propagation directions of cracks were different under different cyclic loading conditions. Under mode I (single tensile stress) cyclic loading, cracks were straight and perpendicular to the tensile stress axis, while under mixed-mode I/III (tensile/shear stress) cyclic loading, cracks were sinuous
and did not propagate in the direction perpendicular to the main tensile stress axis.
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Authors: Chun Bo Huang, Guang Fu Li, Zhan Peng Lu, Jian Min Zeng, Wu Yang
Abstract: The effects of cold working and heat treatment on caustic stress corrosion cracking (SCC) of mill annealed (MA) alloy 800M in boiling solution of 50%NaOH+0.3%SiO2+0.3%Na2S2O3 were investigated by means of microstructure examination, tensile test, X-ray stress analysis, SCC testing of C-rings, Auger electron spectroscopy (AES), scanning electron microscopy (SEM) and metallography.
The microstructure of alloy 800M under tested conditions was austenite. With a train of 25% by cold working, the grains of alloy 800M became longer, yield strength (YS) and ultimate tensile strength (UTS) increased, elongation (δ ) decreased, residual stress and the susceptibility to SCC increased. With increasing temperature of heat treatment of alloy 800M with cold working, the grains became bigger , residual stress, YS and UTS decreased and δ increased, the susceptibility to SCC of alloy 800M decreased. In boiling caustic solution, SCC cracks on the surfaces of C-ring specimens polarized potentiostatically at –20mV/SCE initiated from pitting and propagated along grain boundaries. AES analysis indicated that the surface films on MA alloy 800M were enriched in nickel and depleted in iron and chromium.
993
Authors: Wu Yang, Guang Fu Li, Hao Guo, Jian Jiang Zhou, Chun Bo Huang, Jiasheng Bai
Abstract: Effects of some environmental factors on stress corrosion cracking (SCC) of pipeline steel X-70 both in near-neutral pH environments, including NS4 solution and several solutions containing main types of soil in the eastern part of China, and in high pH solution were studied by means of electrochemical measurement and slow strain rate testing (SSRT). The anodic polarization curves showed different features in near-neutral pH and high pH solutions in terms of active-passive transition behavior. In near-neutral pH solutions, the cracking mode was transgranular with the feature of quasi-cleavage, the susceptibility to SCC increased with decreasing potential, pH and temperature as well as increasing CO2, indicating a dominant mechanism of hydrogen induced cracking (HIC). In high pH solutions, the cracking behavior was similar to that in near-neutral pH solutions when the specimens were polarized at cathodic potentials, but quite different at anodic potentials. A comparison of the electrochemical behavior with the SCC potential region indicated a dominant SCC mechanism associated with anodic dissolution (AD) of X70 in high pH solution at anodic potentials. A preliminary experimental potential (E)-pH-SCC diagram has been established for X70 in near-neutral pH environments.
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