Papers by Keyword: Crystallography

Abstract: The influence of prior austenite grain size on the crystallography of allotriomorphic ferrite is investigated in a low carbon steel. The results show that as the prior austenite grain size decreasing, the fraction of allotriomorphic ferrites that do not keep K-S orientation relationship with any surrounding prior austenite grains is increased. It is observed that such ferrites usually form at the grain edges or grain corners. It is known that with the grain size decreasing, the fraction of grain edges and corners increases. It is suggested that the free energy of the defects at such nucleation sites is higher than that at grain faces, and the nucleation barrier of ferrite is lower. As a result, the possibility for the ferrite to form that does not have orientation relationship with all surrounding austenite grains is increased at such sites.

Abstract: Nanoindentation is considered to be a very promising experimental approach to measuring the ideal shear strength since the stressed volume beneath the sharp indenter may be defect-free. The local shear component of the stress reaches its maximum value at some close distance from the indenter in the bulk. The value of the stress can reach the ideal shear strength and, consequently become high enough to nucleate dislocations. This process might be detected as a pop-in on the nanoindentation load-displacement curve. To model the nanoindentation test for that purpose, three different approaches have been used in this works. The first approach is based on the analytical Hertzian solution of the stress field beneath the nanoindenter where only a continuum mechanics is taken into account. The second concept is based on the numerical solution without crystallographic considerations and the third one respects the fact that the dislocation generation in the substrate is subjected to crystallographic rules. The aim of this article is to compare all these concepts by their application to the nanoindentation process performed on selected bcc and fcc metallic substrates.

Abstract: A minor, but crucial, modification to the original version of the TM was recently proposed in order to ensure that the model predictions were entirely consistent with those of the phenomenological theory of martensite crystallography (PTMC). In the present paper an analysis based on the principles of the Frank-Bilby equation is used to derive this modified version of the two-dimensional TM equation for the habit plane orientation from first principles. A considerably simpler and more accurate expression for the tilt rotation is also presented. Finally, a simple method for using the TM approach to calculate the shape strain, its magnitude and direction is described. The results of the predictions made with this improved version of the TM are compared with those of the original TM and with the corresponding PTMC predictions.

Abstract: Effects of transformation temperature on variant grouping tendency of bainitic ferrite in a low carbon low alloy steel transformed isothermally are investigated by means of electron backscatter diffraction analysis. Baintic variants of Kurdjumov-Sachs (K-S) orientation relationship belonging to the same Bain correspondence tend to form adjacently in the bainite structure formed at 823K, while the K-S variants sharing the same close-packed plane parallel relation form adjacently in the bainite structure formed at 723K and lath martensite formed by quenching.

Abstract: Low dimensional nanostructures, e.g. nanowires, self-assembled through heteroepitaxy, present a variety of crystallographic features that do not always follow conventional V-W or S-K growth mode. Applying Δg parallelism rules and edge-to-edge matching (E2EM) model in β-DySi₂/Si and CoSi₂/Si systems provides a better understanding of the natural preference of the interface orientation and the orientation relationship (OR) during heteroepitaxial growth. This may help improving the quality of nanowires through optimizing the substrate orientation.

Abstract: The partitioning of alloying elements between a and b phases was measured at different steps of the isothermal transformation at 710 and 610°C in Ti 17 alloy using EDX analyzer in the TEM. In addition, the transformation crystallography was determined. No differences in substitution elements were observed for a same transformation temperature in the a phase, however the composition varied with the transformation temperature. For the partial transformed specimens, gradient in composition were obtained. Results are compared to calculated compositions using ThermoCalc software and Saunders database.

Abstract: There is now a great deal known about the atomic mechanisms of solid–state phasetransformations, and this knowledge can be exploited to determine the distribution of crystalorientations. It is possible to estimate accurately, the crystallographic texture, transformationstrains and details of the microstructure, particularly in the context of steels. The concepts havenow been applied to design metallic alloys which compensate automatically for the residualstresses which develop in engineering components when they are cooled heterogeneously fromelevated temperatures. Such materials are now in commercial use and represent an innovationresulting directly from phase transformation theory.

Abstract: Pyrrhotite [1] is a common ferrimagnetic mineral in terrestrial rocks and has been identified recently as the major remanence carrier in Martian rocks, as in SNC (Shergotty-Nakhla-Chassigny) type meteorites. This compound undergoes a low temperature magnetic transition around 32 K with a change in the natural magnetic remanence [2]. This transition is going to be of growing importance in paleomagnetism and rock magnetism. To determine the structure change at 32K neutron diffraction was performed on two crystal samples at 50K and 20K (D10-ILL). Based on the magnetic torque measurements, performed on the same samples, a model of low-temperature triclinic structure was build. This model, explains previous Mössbauer experiments [4], the torque measurements, the magneto-crystalline anisotropy decreasing.

Abstract: Single crystal nickel base superalloys, such as Chinese material DD6 have been used in gas turbine blade in China more and more widely. In order to make better use of single crystal superalloys with many excellencies, constitutive models have been developed. In this paper, general method of crystallographic constitutive modeling was summarizes and a new constitutive model, based on crystallographic theory was proposed with phenomenological models' advantages. Based on crystallographic slip system principle, the basic slip-based viscoplasticity theory equations were set up on 12 octahedral slip systems and 6 cubic slip systems, total 18 slip systems. In micro-level slip system, the general unified constitutive formulations were used as the flow equations and hardening law. In the model, scalar forms were applied for constitutive equations on slip systems and the number and types of active slip systems were used to describe the material anisotropy, which was satisfied automatically by slip systems not anisotropic tensors and. The experimental and calculation results of two kind single crystal superalloys PWA1480 and DD6 were compared. The model had the capability to predict many mechanical response and analyze structure of single crystal superalloys. The modeling procedures and results showed that this crystallographic model had more clear physical meaning and was exact.

Abstract: Nanoparticle research disciplines—chemical synthesis, applied physics and devices based on their physical-chemical properties, and computational physics—have been very active fields for the last 15 years or so, because of the potential and current applications in medicine, catalysis, energy storage, environment and electronics applications. This wide spectrum of disciplines and their applications keep metallic nanoparticles as one of the most promising nanostructures and their research as one of the cornerstones of nanotechnology. In this contribution we present a comprehensive and extended geometrical description for the most common shapes and structures for metallic nanoparticles, as well as experimental results for these geometries with some variations given by truncations.