Authors: Wei Huang, Jin Chun Tu, Yang Cao, Xiao Hong Wang, Jin Li, Kai Xiao
Abstract: In this paper, mesoporous indium oxide has been synthesized by the hard template route from the SBA-15 silica template. The results characterized from XRD, and N2 adsorption-desorption demonstrated that the synthesis can be controlled successfully in nanometer (meso-structure) scale. The obtained sample was investigated as humidity sensing material by coating on a ceramic plate, and the humidity sensing performance can be enhanced up to more than three orders of magnitude without any doping. Further testing proved that it is a promising humidity sensing material and can be widely used, and a possible mechanism was also provided.
1860
Authors: Ya Wei Hu, Hui Rong He, Yang Min Ma
Abstract: Ultra-thin fibers of indium oxide (In2O3) were prepared by sol-gel processing and the electrospinning technique using polyvinylpyrrolidone (PVP) and indium nitrate as precursors. The fibers were characterized by the thermogravimetric analysis, scanning electron microscopy, X-ray diffraction and room temperature photoluminescence spectra. It was observed that the In2O3 nanofibers exhibited photoluminescence peaks centered at 526 and 590 nm, corresponding to the defeat-related deep-level emission.
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Authors: Alberto F. Pasquevich, Mario Rentería
Abstract: In this chapter Perturbed Angular Correlation (PAC) experiments on binary oxides are described. These experiments provide local-scale fingerprints about the formation, identification, and lattice environment of defect complexes at the PAC probe site. The potential of the PAC observations in conjunction with ab initio calculations is shown. Measurements of the electric-field gradient at impurity sites using 111Cd and 181Ta probes are reviewed. Special attention is paid to oxides with the bixbyite structure. The case of In2O3 is particularly analyzed. Results obtained with HfO2, in form of coarse grain or nano particles, are described. The potential results that can be obtained from Density Functional Theory ab initio calculations in doped systems are shown describing the main results observed in many impurity-host systems.
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Authors: Jin Ho Yoon, Jung Sik Kim
Abstract: In this study, the micro gas sensor for NOx gas was fabricated by using a MEMS technology and sol-gel process. The sensing electrode and micro heater were designed to be a co-planar typed structure in the Pt thin film layer. The fabricated micro platform had a low power consumption of 67 mW at 2.0 V of heater voltage and 300°C of operating temperature. Indium oxide as a sensing material for NOx gas was synthesized by a sol-gel process with indium isopropoxide. The particle size of synthesized In2O3 was identified as about 50 nm. The maximum gas sensitivity as relative resistance (Rs = Rgas / Rair) occurred at 300°C with the value of 8.0 at 1 ppm NO2 gas. The present study shows that a MEMS-based gas sensor is a potential candidate for the automobile AQS (air quality system) gas sensor with many advantages of small dimension, high sensitivity, short response time and low power consumption.
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Authors: Hyoun Woo Kim, Jong Woo Lee, Jeong Whan Han, Hyung Sun Kim, Mok Soon Kim, Byung Don Yoo, Sun Keun Hwang
Abstract: Indium oxide (In2O3) films were successfully grown on LiAlO2 substrates using the
triethylindium (TEI) as a precursor in the presence of oxygen in the metalorganic chemical vapor
deposition process. We have established the correlation between the substrate temperature and the
structural properties. The grain structures were clearly shown on the surface of the films deposited at
350°C. The root mean square (RMS) surface roughness of the In2O3 films increased with increasing
the substrate temperature. A photoluminescence measurement at room temperature exhibited a
yellow-green emission band centered at 585 nm.
625
Authors: Hyoun Woo Kim, Sun Keun Hwang, Won Seung Cho, Tae Gyung Ko, Seung Yong Choi, Wan In Lee, Sang Eon Park, Jung Hoon Joo, Dong Ik Kim, Seong Gyoon Kim, Byung Hak Choe, Seok Hong Min, Jae Ho Choi
Abstract: This paper reports the fabrication of indium oxide (In2O3) films using a triethylindium and
oxygen mixture. The deposition has been carried out on TiAlN substrates (200-350°C). We have
established the correlation between the substrate temperature and the structural properties. The films
deposited at 300-350°C were polycrystalline, whereas those deposited at 200°C was close to
amorphous. XRD analysis and SEM images indicated that the films grown at 350°C had grained
structures with the (222) preferred orientation. The room-temperature photoluminescence spectra of
the In2O3 films exhibited a visible light emission.
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Authors: Hyoun Woo Kim, Ju Hyun Myung
Abstract: Indium oxide (In2O3) films was deposited on TiN substrates by the metal organic chemical
vapor deposition technique using a triethylindium and oxygen mixture. The films deposited at 250-350°C
were polycrystalline, while that deposited at 200°C was close to amorphous. XRD and SEM analyses
indicated that the films grown at 350°C had grained structures with the (222) preferred orientation.
760
Authors: Sung En Lin, Wen Cheng J. Wei
Abstract: Monodispersive and uniform particles have many potential applications. The objectives of this study are trying to synthesize and control the morphology of monodispersive indium oxide (In2O3)particles through hydrothermal process with the help of PVP (polyvinylpyrrolidone) and urea additions. Various cubic, ellipse, or shuttle-like In2O3 particles were synthesized by using hydrothermal conditions
(65-85oC). The effects of Sr nitrate were studied. Spherical particles could not be synthesized. The aspect ratio of the In2O3 particle reduced as the concentration of Sr nitrate increased. Crystalline In2O3 phase appeared above 300oC.
499
Authors: E.C.C. Souza, E.N.S. Muccillo
Abstract: Indium oxide, a wide band gap transparent conductor, is of great interest for many
device applications due to its unusual combination of high transparency in the visible region
and high electrical conductivity. Several methods, comprising all three phases, namely, the
solid phase, the solution phase, as well as the vapor phase, have been used for the preparation
of In2O3 powders and thin films. In this work, indium oxide nanoparticles were synthesized
by homogeneous precipitation using hexamethylenetetramine as ligand and indium nitrate or
indium chloride as precursor materials. Thermogravimetry and differential thermal analysis
results evidenced the relatively low temperature for crystallization of indium oxide. Spherical
clusters consisting of about 8 nm of diameter indium oxide nanoparticles were obtained after
thermal decomposition at 400 °C for 2 h, as revealed by X-ray diffraction experiments and
nitrogen adsorption measurements. Transmission electron microscopy observations confirm
the single-crystalline nature of the prepared nanoparticles. This material exhibits
photoluminescence emission at room temperature with peak onset at 315 nm as a
consequence of the small size of the particles.
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Authors: Hyoun Woo Kim, Ju Hyun Myung, S.H. Shim, Woon Suk Hwang
Abstract: In2O3 materials consisting of dense arrays of vertically aligned rod-like structures were
deposited on sapphire substrates by thermal chemical vapor deposition (CVD) using triethylindium
(TEI) and oxygen as precursors at a substrate temperature of 350 oC. The rod-like structure with a
triangular cross section had a cubic structure, exhibiting preferred crystallographic orientation in the
[111] direction. The photoluminescence spectra of In2O3 structures under excitation at 325 nm
revealed a visible emission.
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