Papers by Keyword: Langmuir Model

Abstract: This work presents a theoretical study of the anomalous behavior of moisture transient diffusion in vegetable fiber-reinforced composites materials using Langmuir-type model. For obtain the analytical solution was used the Laplace transform technique. Results of the absorption kinetics and concentration distribution of water (free and trapped water molecules) within the material along the process are presented and analyzed. Predicted results compared to experimental data of average moisture content have shown that the model was effective for description of the phenomenon, allowing a better understanding about the effects of moisture migration mechanisms.

Abstract: With respect to the problems existed in the description of the adsorption characteristics of super-low rank and super-high rank coals using the conventional Langmuir adsorption model, in this paper, We first introduces the De Bore adsorption model into the coal seam gas adsorption, and utilizes the results of the ab initio calculation of quantum chemistry result and the isothermal adsorption test statistical results, simplifies the De Bore model equation. The new adsorption model is more suitable for describing the gas adsorption characteristics of the whole coal ranks. This new model has the stronger function and wider suitable scope than the Langmuir adsorption model.

Abstract: The AFPs and water molecules are considered together when they adsorb on the ice surface in this article. Based on Myers and Prausnitz’s ideal adsorbed solution theory(IAST) and Langmuir adsorption model, the coverage rate of HPLC-6 on the ice surface is calculated when considering the adsorption of water, and the thermal hysteresis temperature of HPLC-6 is also given. The results show that the thermal hysteresis temperature increases as the concentration increases, and the theoretical result is agreement with experimental data.

Abstract: A modified peat was prepared by using nitrate and natural peat from Yiyang city in Hunan Province. The adsorption properties of the nitrifying peat for Methylene blue was investigated in aqueous solution. The effect of the adsorbent dosage, time and the initial concentration of methylene blue on the adsorption capability was discussed. The result showed that time and the adsorbent dosage had greater influence on the adsorption of Methylene blue, the adsorption of Methylene blue by Nitrifying peat was a rapid process, and in 20 min in the adsorption rate reached more and 60%, the adsorption amount was approximately proportional to the initial concentration( 20-100 mg /L). Langmuir and Freundlich isotherms were used to fit the equilibrium data, and it was found that the adsorption isotherm followed the Langmuir model.

Abstract: In the present paper, the ability of carboxymethylcellulose sulfate (CMC-S) for Cu(II) removal was studied. The influence of factors, such as the pH value, the initial copper concentrations, and the contact time, were investigated in detail. Atomic absorption spectrophotometer was applied to determined the concentration of Cu(II). The results showed that the adsorption process was strongly dependent on the pH value and the initial copper concentration. The optimum pH value was in the range of 6-7. The theoretical adsorption capacities for Cu(II) was 127.7 mg/g. The equilibrium data was well fitted to the Langmuir isotherm model at 25°C, which can be explained as a monolayer adsorption.