Papers by Keyword: Niobium Silicide

Abstract: This work investigates the evolution of the microstructure of an Nb-23Ti-20Si (at.%) based alloy, from the primary plasma-melted material that is gas-atomized towards the consolidated material (here using SPS). The nature, morphology and size of the solid solution and the various silicides are followed by SEM, EDS and EBSD. Homogenous and fine microstructures are obtained after the SPS step and are improved by a subsequent heat treatment (1500°C, 100 h). However blocky silicides, already present in the powder particles, cannot be eliminated. A better control of the primary material’s microstructure would improve the microstructure of the final material.

Abstract: A comparative study on the microstructure-mechanical property relationships in the molybdenum and niobium silicide based composites has been carried out with emphasis on the role of the ductile and brittle phase constituents at ambient and elevated temperatures. The MoSi2, MoSi2-20 vol.% SiC and -Mo-Mo3Si-Mo5SiB2 composites have been prepared by powder metallurgy processing. Furthermore, the niobium silicide based composites, having a eutectic of Nb solid solution (Nbss) and (Nb,Mo)5Si3, and either Nbss or (Nb,Mo)5Si3 as the primary phase in the hypoeutectic or hypereutectic compositions, respectively, have been processed by arc melting. The increase in fracture toughness with respect to that of MoSi2 is modest in the MoSi2-SiC composites, and more significant in the multiphase Mo-Mo3Si-Mo5SiB2 and Nbss-(Nb,Mo)5Si3 based in-situ composites with ductile reinforcements. The ductile phase, either Mo or Nbss aids in toughening chiefly through crack arrest and bridging, and undergoes plastic yielding under constraint during deformation, leading to a higher energy of fracture. In the MoSi2 and MoSi2-SiC composites, the matrix grain size has a significant role in high temperature strength retention and strain hardening behaviour. In the ductile phase reinforced composites, the hard silicide-based intermetallic phases contribute to elevated temperature strength, while the constrained plastic deformation of the -Mo or Nbss is responsible for much higher rate of strain hardening than in the MoSi2 and MoSi2-SiC composites.

Abstract: The microstructure and mechanical properties including room temperature fracture toughness Kq, tensile strengthσb and elongationδ at 1250°C of the Nb based alloy directionally solidified in an electron beam floating zone melting (EBFZM) furnace have been evaluated. The microstructure is primarily composed of Nb solid solution (Nbss), α-(Nb)5Si3 and (Nb)3Si phases. After directional solidification with the moving rate of electron beam gun R being respectively 2.4, 4.8 and 7.2 mm/min, the primary Nbss dendrites, Nbss + (Nb)5Si3/(Nb)3Si eutectic colonies (lamellar or rod-like) and divorced Nb silicide plates align along the longitudinal axes of the specimens. When R = 2.4 mm/min, the best directional microstructure is obtained. Directional solidification has significantly improved theσb at 1250°C and Kq. The maximumσb occurs for the specimens with R = 2.4 mm/min and is about 85.0 MPa, meanwhile, the Kq is about 19.4 MPam1/2.

Abstract: The directionally solidified specimens of Nb-13.52 Si-22.60 Ti–6.88 Hf–2.54 Cr–2.24 Al alloy were prepared in an electron beam floating zone melting furnace at the withdrawing rate of 0.1, 0.3, 0.6, 1.0, 2.4 and 6.0 mm/min. All the primary Nb solid solution (Nbss) columns, Nbss + (Nb)3Si/(Nb)5Si3 eutectic colonies and divorced (Nb)3Si/(Nb)5Si3 plates or chains align well along the longitudinal axis of the specimens. With increasing of the withdrawing rate, the microstructure is gradually refined, and the amount of Nbss + (Nb)3Si/(Nb)5Si3 eutectic colonies increases. Both the room temperature ultimate tensile strength σb and fracture toughness KQ are improved for the directionally solidified specimens. The tensile fracture occurs in a cleavage way.