Modification of Epoxy Resin Using Liquid Natural Rubber

Article Preview

Abstract:

The cure process and the mechanical properties of liquid polymethylmethacrylate grafted natural rubber (LMG30) modified epoxy have been studied. Addition of LMG30 significantly increased the fracture toughness and the impact strength of the epoxy resin. The fracture toughness increased up to 22 fold (17.3 MNm-3/2) when modified with 5 phr LMG30. The glass transition temperature however, decreases as the rubber content increases. The SEM analysis shows uniform dispersion of rubber particles within the epoxy matrix with average particle size between 0.4 to 0.8 0m in diameter.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

272-274

Citation:

Online since:

June 2006

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2006 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] J. N. Sultan and F. J. McGarry: Polym. Eng. Sci., 13(1), (1973). p.29.

Google Scholar

[2] C.B. Bucknall and T. Yoshii: Br. Polym. J. 10 (1978), p.53.

Google Scholar

[3] Z. N. Sanjana and L. Kupchella: Polym. Eng. Sci., 25, 18, (1985).

Google Scholar

[4] R. A Pearson and A. F. Yee: J. Mat. Sci., 21 (1986), p.2475.

Google Scholar

[5] L. T. Manzione, J. K. Gillham and C. A. McPherson, J. App. Polym. Sci. Vol. 26, (1981), p.907 A. Ibrahim , Malaysian Patent 108852.

Google Scholar

[6] L. C. Chan, J. K. Gillham, A. J. Kinloch and S. J. Shaw, Advances in Chemistry Series 208, American Chemical Society, Washington DC, (1984), p.263.

Google Scholar

[7] I. Zainol, 10 th International Seminar on Elastomer 2005, Organised by Instituto de Quimica/UERJ Rio de Janeiro Brazil, April 2005. Extended Abstracts on CD. Fig. 3. Impact strength of modified epoxy resin at different rubber content 0 20 40 60 80 100 0 3 6 9 12 Rubber Cont. (phr) Impact Strength (J/m) Fig. 4. Scanning electron micrographs of fracture surface of various rubber content (a) 0 phr rubber, (b) 1 phr rubber, (c ) 3 phr rubber, (d) 5 phr rubber (e) 7 phr rubber (f) 10 phr rubber.

DOI: 10.1201/9780203499337.ch6

Google Scholar