Paper Titles
Order-Disorder Phase Transition in NaBD4
p.287
Kinetics of the Decomposition of Crocidolite Asbestos: A Preliminary Real-Time X-Ray Powder Diffraction Study
p.291
Sorbate Rearrangement and Cation Migration in HFC-134 Loaded NaY Zeolite: a Temperature Dependent Synchrotron Powder Diffraction Study
p.295
Kinetical Investigations on Lamellar CalciumAluminateChromateHydrates with High Speed Detector
p.299
Features of Crystal Structure and Ferroelectric Phase Transitions of KTiOPO4 Doped with Nb and Sb
p.303
Synthesis, Properties and Characterisation of Manganeous Layered Double Hydroxides Using In Situ X-Ray Techniques
p.307
Phase Transformations in Li-Mn-O Spinels Synthesized by Sol-Gel Method
p.311
Influence of the Dehydration on Location of Both Sodium and Calcium Cations in 5A Zeolite – An In Situ X-Ray Diffraction Study
p.315
Calcination of ZSM-5. An In Situ Synchrotron Powder Diffraction Study
p.319

Features of Crystal Structure and Ferroelectric Phase Transitions of KTiOPO4 Doped with Nb and Sb

Article Preview

Abstract:

The evolution of the crystal structures as a function of temperature of the new solid- solution KTiOPO4 (KTP) isomorphs, namely K1-xNbxTi1-xOPO4 and K1-xSbxTi1-xOPO4 have been studied by neutron powder diffraction below and above the ferroelectric phase transition temperatures. On the basis of the experimental data obtained the cation distribution, among the sublattices of this structure, and the distortion of the framework at the phase transition, have been discussed. The possible correlation between the non-linear optical properties and the dominant structural features tailored by compositional variation has also been studied.

You might also be interested in these eBooks
European Powder Diffraction EPDIC 8 View Preview

Info:

Periodical:

Materials Science Forum (Volumes 443-444)

Pages:

303-306

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.443-444.303

Citation:

Cite this paper

Online since:

January 2004

Authors:

S.A. Ivanov, Sergei Yu. Stefanovich, S.-G. Eriksson, V.I. Voronkova, T.Yu. Losevskaya, V.K. Yanovskii, Roland Tellgren, Håkan Rundlöf

Keywords:

KTP-Type Structure, Neutron Powder Diffraction, Phase Transition

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2004 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

References

[1] G.D. Stucky, M.L.F. Phillips, T.E. Gier: Chem. Mater. 1 (1989), p.492.

Google Scholar

[2] V.K. Yanovskii, V.I. Voronkova: Phys. Stat. Solidi(A) 93 (1986), p.665.

Google Scholar

[3] C.L. Cheng, L.K. Cheng, R.L. Harlow et al.: Appl. Phys. Lett. 64 (1994), p.155.

Google Scholar

[4] P.A. Thomas, B.E. Watts: Solid State Commun. 73 (1990), p.97.

Google Scholar

[5] D.Y. Zhang, H.Y. Sten, W Liu et al., J. Cryst. Growth 218 (2000), p.98.

Google Scholar

[6] S.G. Moorthy, F.J. Kumar, C. Subramanian et. al.: Mater. Letters. 36 (1998), p.266.

Google Scholar

[7] T.Y. Losevskaya, O.A. Alekseeva V.K. Yanovsky et. al., Crystal. Reports. 45 (2000), p.809.

Google Scholar

[8] J. Rodriguez-Carvajal: Physica B 192 (1993), p.55.

Google Scholar

[9] T. Balic Zunic, I. Vickovic: J. Appl. Cryst. 29 (1996), p.305.

Google Scholar

[10] I. Tordjman, R. Masse, J. Guitel: Z. Krist. 139 (1974), p.103.

Google Scholar