Papers by Author: Takuma Suzuki

Abstract: Silicon carbide double-implanted metal-oxide-semiconductor field-effect transistors (DIMOSFETs) were fabricated on 4H-SiC (000-1) carbon face. The effect of current spread layer (CSL) structure was studied. 1.9 mm × 1.9 mm DIMOSFETs were characterized from room temperature to 200°C. At room temperature, the specific on-resistance of this MOSFET was 14.8 mΩcm² at a gate bias of 20 V and a drain voltage of 0.5 V. The blocking voltage of this MOSFET was 3300 V. At 300 °C, the specific on-resistance increased from 14.8 mΩcm² to 83.9 mΩcm² and the threshold voltage decreased from 5.3 V to 3.4 V.

Abstract: The causes of extrinsic failures in time-dependent dielectric breakdown characteristics of gate oxide on C-face of 4H-SiC are examined by comparing breakdown points of tested gate oxides with the images of X-ray topography and those of differential interference contrast microscopy. We have concluded as follows: (1) surface morphological defects that originate from threading screw dislocations degrade reliability of gate oxides. (2) These surface defects are not necessarily found on every wafer. (3) Crystallographic defects are not killer defects of MOSFET per se.

Abstract: 1.2 mm × 1.2 mm and 2.7 mm × 2.7 mm silicon carbide double-implanted metal-oxide-semiconductor field-effect transistors (DIMOSFETs) were fabricated on 4H-SiC (000-1) carbon face. 1.2 mm × 1.2 mm DIMOSFETs were characterized from room temperature to 150°C. At room temperature, the specific on-resistance of this MOSFET was 5.7 mΩcm2 at a gate bias of 20 V and a drain voltage of 1.0 V. The blocking voltage of this MOSFET was 1450 V based on the avalanche current. At 150 °C, the specific on-resistance increased from 5.7 mΩcm2 to 9.1 mΩcm2 and the threshold voltage decreased from 4.9 V to 4.1 V. The blocking voltage increased from 1450V to 1500V. 2.7 mm × 2.7 mm DIMOSFETs were also characterized at room temperature. They showed a specific on-resistance of 8.0 mΩcm2 at a gate bias of 20 V and a drain voltage of 1 V. The blocking voltage of this device was 1550 V, which was determined by the avalanche current. The time-zero dielectric breakdown (TZDB) and time-dependent dielectric breakdown (TDDB) characteristics of 180 μm × 180 μm MOS capacitor were estimated. At room temperature (RT), TZDB was 9.3 MV/cm and the charge to breakdown value of 63% cumulative failure (Qbd) was 72 C/cm2. The temperature dependence of Qbd measurements showed that it deceased from 72 C/cm2 at RT to 14 C/cm2 at 250 °C. Switching characteristics of 1.2 mm × 1.2 mm DIMOSFETs were obtained by the double-pulse measurements. The turn-on time and the turn-off time were 36 nsec and 53 nsec, respectively.

Abstract: Silicon carbide Double-Implanted Metal-Oxide-Semiconductor Field-Effect Transistors (DIMOSFETs) were fabricated on 4H-SiC (000-1) carbon face. The DIMOSFETs were characterized from room temperature to 250°C. At room temperature, they showed a specific on-resistance of 4.9 mΩcm2 at a gate bias of 20 V and a drain voltage of 1.0 V. The specific on-resistance taken at a drain current (Id) of 260 A/cm2 was 5.0 mΩcm2. The blocking voltage of this device was higher than 1360 V at room temperature. At 250°C, the specific on-resistance increased from 5.0 mΩcm2 to 12.5 mΩcm2 and the threshold voltage determined at Id = 26 mA/cm2 decreased from 5.5 V to 4.3 V.

Abstract: The effect of ammonia (NH3) post-oxidation annealing (POA) technique on the reliability of thermal oxides grown on a n-type 4H-SiC (0001) face by dry oxidation has been investigated. Comparing other POA techniques using hydrogen and nitrous oxide gases, it was indicated that the NH3 POA after dry oxidation remarkably improves the insulating properties of thermal oxides. The mode value of field-to-breakdown for thermal oxides prepared by NH3 POA was 12.1 MV/cm. The charge-to-breakdown (QBD) in the NH3 POA sample was the highest in all samples, and the QBD value at 63% cumulative failure rate was 19.1 C/cm2. In addition, the NH3 POA maintained excellent electron trapping characteristics of thermal oxides against the electron injection.

Abstract: This paper discusses the issues regarding reliability of large-area (up to 25mm2) gate oxide on the C-face of 4H-SiC. We have shown that the TDDB characteristics of large-area gate oxide improved by separating gate oxidation processes into oxide growth by dry-oxidation and successive interface control by anneal in N2O ambient or that by wet-oxidation followed by anneal in H2 ambient. In particular, dry-oxidation followed by anneal in N2O ambient for interface treatment (dry+N2O process) is effective for the suppression of the random failure in TDDB characteristics. The estimated lifetime of gate oxide of less than 9mm2 by the dry+N2O process is six-digits larger than 30 years. In the case of the TDDB characteristics of 25mm2 gate oxide grown by the dry+N2O process, the initial and random failure in TDDB characteristics is dominant. However, even in this case, we have confirmed that the evaluated lifetime of 25mm2 gate oxide is more than 30 years. In order to clarify the mechanism of the degradation of the TDDB characteristics of large-area gate oxide, we examined the effect of the surface defect on the TDDB characteristics by observing the surface of each broken MOS capacitor after the TDDB test. We have found following results. (1) The initial failures in TDDB characteristics are mainly due to surface defects such as “down fall”, “comet”, and “triangular defect”. (2) The footprints of random failure do not correspond to the positions of smaller surface defects such as “bump”. Finally, we have found that the quality of the epitaxial layer affects random failure rate in the TDDB characteristics of large area gate oxide; the random failure in the TDDB characteristics of 25mm2 gate oxide on epitaxial layer grown by a certain epitaxial vendor is almost suppressed. However, the cause of the difference in TDDB characteristics is not identified.

Abstract: The influences of processing and material defects on the electrical characteristics of large-capacity (approximately 100A) SiC-SBDs and SiC-MOSFETs have been investigated. In the case of processing defects, controlled activation annealing is the most important factor. On the other hand for material defects, the number of epitaxial defects must be decreased to zero for both SBDs and MOSFETs. The dislocation defects in SiC wafers are dangerous for the breakdown voltage of MOSFETs. However, they are not killer defects. If the epitaxial defect density is sufficiently low and the dislocation density is in the order of 10000cm-2, the long- term reliability of the gate oxide at the electric field of 3MV/cm can be guaranteed.

Abstract: Condition dependences of defect formation in 4H-SiC epilayer induced by the implantation/annealing process were investigated using synchrotron reflection X-ray topography and transmission electron microscopy. Nitrogen, phosphorus or aluminum ions were implanted in the 4H-SiC epilayers and then activation annealing was performed. To compare the implantation/annealing process, a sample receiving only the annealing treatment without the implantation was also performed. Two different crucibles (conventional and improved) were used in the annealing process. The formation of single layer Shockley-type stacking faults near the surface was found to have no ion-implantation condition or crucible dependence. The formation of BPD half-loops and the glide of pre-existing BPDs showed clear dependence on the crucibles.

Abstract: The oxide reliability of metal-oxide-semiconductor (MOS) capacitors on 4H-SiC(000-1) carbon face was investigated. The gate oxide was fabricated by using N2O nitridation. The effective conduction band offset (Ec) of MOS structure fabricated by N2O nitridation was increased to 2.2 eV compared with Ec = 1.7 eV for pyrogenic oxidation sample of. Furthermore, significant improvements in the oxide reliability were observed by time-dependent dielectric breakdown (TDDB) measurement. It is suggested that the N2O nitridation as a method of gate oxide fabrication satisfies oxide reliability on 4H-SiC(000-1) carbon face MOSFETs.

Abstract: This paper discusses the issues regarding reliability of large-area (up to 9mm2) gate oxide on the C-face of 4H-SiC. We first show that the initial failure in TDDB characteristics of large area gate oxide is strongly correlated with the surface-defect density. Using wafers with low surface-defect density wafers, scaling analysis of the area-dependence of TDDB characteristics has been performed. It has shown that the reliability of a large area gate oxide is dominated by initial and random failures. Further, we have shown that, by optimizing the temperatures of post-oxidation anneal in hydrogen atmosphere, the random failures of TDDB characteristics are substantially reduced.