Papers by Keyword: AAS

Abstract: This study aimed to determine the characteristics of activated charcoal from mangroves resulting from pyrolysis and activation with 3M KCl using Fourier Transform Infra-Red (FTIR), X-Ray Diffraction (XRD) and ash content analysis and to determine the ratio of Pb, Fe and Cd metal content in river water before and after filtered with activated charcoal. The results of the FTIR test for charcoal from mangroves resulting from pyrolysis and activation with KCl showed the presence of O-H, C=C, C-H, C-N and C-Cl groups as additional groups that appeared after the activation process. The results of XRD analysis show that the lattice parameter (α) can be calculated, namely in pyrolysis mangrove charcoal = 5.79 and charcoal from pyrolysis and activation mangrove wood = 5.88. The results show that there is a change in the distance between the crystal planes after activation, with the known value of, the results of d-spacing 3 strong peaks are 3.39 , 2.94 and 5.88 . The results of the analysis of the ash content are 15.4% and exceed the maximum percentage that has been determined, because there are still impurities attached to the carbon surface. The results of the analysis using Atomic Absorbtion Spectrophotometry (AAS) showed that there were differences in the levels of Pb, Fe and Cd in river water before and after being filtered with activated charcoal. There was a decrease in Pb levels from points 1,2 and 3 as much as 73%, 49% and 55.23%. Meanwhile, Fe metal decreased from points 1, 2 and 3 as much as 58%, 66% and 81%. And on Cd there was a decrease of 44%, 61% and 92%. From these percentage results, activated charcoal from mangroves can be said to be effective because it can absorb metals in river water. Pb metal in river water in East Kombos Manado City has passed the concentration specified in Government Regulation of the Republic of Indonesia No. 22 of 2021, Class II Water Quality Standards.

Abstract: Zeolite Pahae an adsorbent material by activating physical and chemical processes has been synthesized. The methods used are ball milling and coprecipitation methods. Zeolite was ball milling and activated, then sieved using 100 mesh and 200 mesh sieves. To obtain nanozeolite, a ball mill and coprecipitation were carried out to obtain a size of 9.08 nm. The X-Ray Diffraction (XRD) results showed that the zeolite structure is tetragonal. Zeolite is used as a heavy metal adsorbent. Atomic Absorption Spectroscopy (AAS) method can determine how much zeolite can absorb heavy metals. The results of the AAS test showed that the absorption of nanozeolite to heavy metals was Pb of 99.81%; Fe is 99.99% and Mn is 96.87%. The absorption of 200 mesh zeolite is Pb of 99.45%; Fe is 99.99% and Mn is 99.61%. The absorption of 100 mesh zeolite is Pb of 99.66%; Fe is 99.98%, and Mn is 99.68%. From these results obtained zeolite particle size affects the absorption of heavy metals.

Abstract: The heavy metal contain in the industrial wastewater can cause a pollution towards the environment and human due to its toxicity. Therefore extensive studies were conducted for the heavy metal removal. This study was conducted under several conditions by varying pH, biosorbent dosage, initial wastewater concentration and contact time. The results revealed that optimum pH, for high strength synthetic wastewater was 8.0 meanwhile for low strength synthetic wastewater was 7.0. Both high and low strength synthetic wastewater was optimum at 30 minutes of contact time with 1.5g and 0.02g of bisorbent dosage respectively. Meanwhile, the optimum initial metal concentration for high and low strength synthetic wastewater was 400ppm and 1ppm respectively. The results had proven that watermelon rind is able to treat wastewater with high and low concentration of metal.

Abstract: The corrosion tests of Cr, Fe and Ni of Hastelloy C-276 were studied at high temperature and pressure with different aggressive components. The results were investigated by means of graphite furnace atomic absorption spectrophotometer (AAS). The Cr forms stable oxide and NiO is unstable. There is a synergistic effect between salt and oxygen leading to a severe loss of metals. The PO₄^3- can improve the resistance to corrosion for Hastelloy C-276 due to the low-solubility phosphates. The colors of effluences can better support the changed concentrations of metals. The lost metals can reveal the corrosion mechanism of Ni-based alloys.

Abstract: Water pollution by heavy metal is great concern due to its toxicity to nature and environment. Extensive studies were carried out to remove heavy metal through physical, chemical and biological approaches. One of the biological approaches is biosorption. This study was conducted under several conditions namely pH, biosorbent dosage, initial wastewater concentration and contact time. Final concentrations of metals were tested using Atomic Absorption Spectrometry (AAS). The results revealed that optimum removal for Lead and Zinc was 77.3% and 90.30%. Optimum pH, for Lead was 6.0 whereas Zinc was 7.0 respectively. Both metals have showed the same optimum biosorbent dosage of 0.02g and 30 minutes of contact times. Meanwhile, the optimum initial metal concentration for Lead and Zinc were 5 ppm and 1ppm. It is proven that watermelon rind is able to treat wastewater with the present of Lead and Zinc.

Abstract: A new method was introduced for rapid measurement of iron ions in drinking water by automatic discrete spectrophotometry. In the iron concentration range 0-1.5mg/L, the linear relationship was good and the correlation coefficient was 0.9998. The total iron detection of recovery efficiency was 99.94%±1.6% and detection limit was 0.006mg/L and precision of the RSD% was 0.35%. The results show that the method was direct, fast, stable operation and lower iron concentration in water can be accurately detected.There is no significant difference compared with the results of atomic absorption spectrometry methods.

Abstract: The preparation and modelling of single, binary and ternary ion exchanged zeolites that express antimicrobial efficiency is discussed. As experimental material A type zeolite was used and different variations of Ag, Cu and Zn ions were incorporated into the crystal structure. Antimicrobial efficiency is based on the ion concentration and ion release of the zeolite, therefore the maximum cation-exchange capacities (CEC) were determined for each of the single ions. After the determination of CEC the preparation of binary and ternary ion-exchanged zeolite samples were prepared by the mixture of silver, copper and zinc nitrate solutions and the composition of the samples was determined by atomic absorption spectroscopy (AAS). To verify the bioactive effect, the minimum inhibitory concentration (MIC) of single, binary and ternary ion-exchanged zeolite A was determined for bacteria strains.

Abstract: Objectives: This report presents toxicological profile available on a superparamagnetic iron oxide (SPIO) nanoparticle in vivo.