Papers by Keyword: Porosimetry

Abstract: Investigation of the effect of low-pressure NLTP in nitrogen, argon, propane-butane and air on the properties of a multilayer medical-purpose material based on polypropylene used for the manufacture of sanitary-hygienic and medical products. It is shown that after plasma treatment of argon, nitrogen, propane-butane, the surface polarity of the CMC material changes significantly, as evidenced by a decrease in the wettability angle and an increase in capillarity. The most significant changes in indicators are observed in the case of plasma treatment in argon and nitrogen. However, in the case of argon, less processing time is required to achieve the effect. Plasma treatment leads to a slight decrease in tensile strength, no more than 10-15%. It is also shown that when plasma is treated in an argon atmosphere, such characteristics of a nonwoven material as air permeability, hygroscopicity increase, and a decrease in rigidity is observed. The study of the structure of the material (pore size) showed that the treatment with NLTP leads to a significant decrease in the size of large pores and an increase in the size of medium and small pores

Abstract: About 6% of global CO₂ emissions are due to cement production. Blending of Portland cement with a significant fraction of mineral admixture could therefore be instrumental in reducing such emissions. Use of an admixture of vegetable origin such as rice husk as will additionally contribute to waste management and its incineration produces energy. This paper will stress the importance of properly designing such blends. Preferably gap-graded concepts should be employed, since blending efficiency in terms of strength development is promoted as shown in earlier publications. The paper therefore only briefly covers these aspects. Assessment of this blending concept on durability of cementitious materials constitutes a far more complicated problem. This requires careful porosimetry. Mostly, this problem is approached by MIP or by quantitative image analysis. Both can provide 3D information, although that of MIP is generally significantly biased. Quantitative image analysis is however time-consuming and laborious, and thus expensive. Moreover, it does not provide information on continuity of pores. Present day computer facilities offer therefore a better alternative. When using a proper DEM system, the concrete can be simulated in a realistic way. The paper describes new methods for investigating the pore structure in virtual concrete and presents some data on pure cement and blended cement. Differences will have impact on durability risks.

Abstract: This paper discusses the particle packing background of cementitious materials. On micro-level the Portland cement and eventually the mineral admixture grains can be considered packed in the watery environment. Particularly for (super) high performance materials, the packing density can be quite significant. An economic and due to fast computer developments reliable way to study packing of the binder, is by modern discrete element modeling (DEM) approach. In this paper use is made of a concurrent algorithm-based dynamic system, HADES. Hydration is simulated based on spherical grains. Thereupon strength can be studied on the basis of packing density. For durability issues, the complex and tortuous 3D pore structure has to be investigated. This paper uses for the assessment of pore characteristics the robotics-inspired DraMuTS system. Hydrated Portland cement is compared with gap-graded rice husk ash-(RHA)-blended (green) Portland cement. Experiments on gap-graded RHA-blended PC concrete are used as reference. Packing density is shown improved by gap-graded packing. What is more spectacular are the effects of gap-grading with RHA on the pore characteristics obtained on the DEM-produced virtual materials. This paper discusses the expected positive effects on transport-based durability issues due to gap-graded packing-induced changes in the pore system

Abstract: A new method of analysis of PALS spectra of porous materials is proposed. The model considers both the thermalization process of positronium inside the pores and the pore size distribution. The new model is fitted to spectra of mesoporous silica MCM-41 and MSF. The resulting parameters are compared with parameters obtained from fitting the “conventional” models, i.e. a sum of exponential components with discrete or/and distributed lifetimes.