Papers by Keyword: Spray Deposition

Abstract: Processes of rolling after wedge pressing and extruding for multi-layer spray deposited Al-Fe-V-Si/SiCP sheet formation were described in this paper, and the effects of the two different processes on the microstructure and mechanical properties of the composite were investigated. The microstructure of the composite prepared by different processes was observed by OM, SEM, and TEM. The experimental results show that the wedge pressing process can obviously eliminate the pores in the as-deposited preforms and improve the formability effectively. And more uniform microstructure and more excellent mechanical properties of the compositesheets were obtained by rolling after wedge pressing than that by extruding. The excellent mechanical properties can be attributed to avoiding of SiC particles lamination and aggregation which are familiar to the composite as-extruded. Stable microstructure, and good bonding between SiC particles and the matrix improve its mechanical properties further.

Abstract: Spray deposition is a novel process which is used to manufacture rapidly solidified bulk and near-net-shape preforms. In this paper, Al-8.6Zn-2.6Mg-2.2Cu alloy was synthesized by the spray atomization and deposition technique. The microstructural development during subsequent hot extrusion, hot rolling and canned forging was investigated by means of scanning electron microscope and X-ray diffraction. The results indicate that the spray-deposited alloy exhibits a uniform microstructure composed of the Al matrix and Mg(ZnCu)2 compounds with various shape. The fragmentation of the Mg(ZnCu)2 phases in the alloy has been regarded as one of the main phenomena during extrusion, rolling and forging. Under T6 temper condition, the hot-extruded Al-Zn-Mg-Cu alloy displays superior strength, and higher than hot-rolled and canned-forged ones.

Abstract: TiC reinforced AZ91 magnesium matrix composites have been fabricated by a melt in-situ reaction spray deposition. The microstructures of spray-deposited alloys were studied by using scanning electron microscopy (SEM) and X-ray diffraction (XRD). The dry sliding wear behavior of the alloys was investigated by using a pin-on-disc machine under five loads, namely 10, 20, 30, 40 and 50 N. It has been found that the wear behavior of the alloys was dependent on the TiC content in the microstructure and the applied load. At a lower load (10 N), with increasing TiC content, the wear rate of the alloy was decreased, and the dominant wear mechanism was an oxidative mechanism. At a higher load (50 N), a spray- deposited AZ91/TiC composites exhibited superior wear resistance to the AZ91 magnesium alloy, the dominant wear mechanism was delamination.

Abstract: The structure and photoluminescence (PL) of ZnO films deposited on Si (111) substrates by chemical spray deposition using aqueous solution of zinc acetate [Zn (CH3 CO2)2 , 2H2O] was investigated. It was found that these properties depend strongly on growth temperature and grain size. The samples grown at the optimum deposition conditions can generate stronger luminescence. It was revealed by X-ray diffraction that the preferred orientation of poly-crystals is along C-axis, with hexagonal wurtzite structure. PL spectroscopy results shows an evident ultra-violet (UV) emission observed near 380 nm with a broad low intensity band centred at 430 nm. The band was reported as being caused by the defects in the grain boundaries of ZnO. Under optimum deposition conditions a low resistivity and a high optical transmittance of the order of 2.8×10−4 Ω cm and 90%, respectively, were obtained.

Abstract: In the present investigation, several novel techniques including sequential motion compaction, ceramic rolling and frame-confined rolling have been developed to improve the formability of spray deposited porous aluminum alloy preforms. The experimental results show that these techniques can greatly improve the workability of the spray deposited performs. Especially, sequential motion compaction can be used to densify the preforms of large dimensions which are difficult to further processing by the traditional techniques to fully dense.

Abstract: In this paper, Al-10.8Zn-2.8Mg-1.9Cu alloy was synthesized by the spray atomization and deposition technique. The microstructure and mechanical properties of the spray deposited alloy at various aging conditions (T6, T73 and RRA treatment) were studied using high-resolution electron microscopy, selected area diffraction, and tensile tests. The results indicate that the two types of GP zones, GPI and GPII zones are major precipitates for the alloy under peak-aged condition. The peak UTS and YS values achieved at an ageing temperature of 120 °C was 818 MPa and 793 MPa. Under two-step aging condition, the GP zones and η’ are major precipitates for the alloy, the discontinuous grain boundary precipitates are favorable to SCC resistance in over-aged condition, which reduces its strength 58 MPa(about 7%) comparing to the peak-aged condition. RRA treatment decreased ultimate tensile strength 25 MPa (about 3%) in values compared with the alloy at T6 condition.

Abstract: Six kinds of Al-Zn-Mg-Cu alloys, modified with nickel and zirconium, have been produced by rapid solidification using spray deposition(the Osprey process). The effect of nickel on the structures, mechanical properties of ultrahigh strength aluminium alloy is studied, and the probable maximum of mechanical properties is predicted. There are three nickel-rich phases, Al3Ni2, Al7Cu4Ni and MgNi2, forming in 1%Ni alloy, its ultimate tensile strength(UTS) increased with increasing extrusion ratios significantly while maintaining high levels of ductility, Futhermore, the extruded bars show enhancing more clearly than extruded plates in UTS and ductility. The content of Ni should decreased with increasing of Zn and Zr, and the highest properties(UTS=832MPa, Elongation=7.5%)are attained in 0.20Zr＋0.30Ni (wt%)alloy. In addition, the size, the shape and the homogeneous distribution of zirconium-rich phase produced in solidification is the key to effecting the mechanical properties of materials when Zr content is 0.2~0.5％.

Abstract: A novel spray deposition technology with characteristic of the movable crucible, has been developed to prepare aluminum alloy and aluminum alloy matrix composite rings with large dimensions. The influences of process parameters on the microstructure and properties of the as-deposited rings were systematically investigated and the process parameters were optimized. Up to now, 7075Al/SiCp and A356/SiCp composite rings with the outer diameter of 1200mm, the inner diameter of 600mm and the thickness of 250mm, and LF6 aluminum alloy ring with the outer diameter of 3500mm, the inner diameter of 3100mm and the thickness of 250mm have been produced respectively. All the as-deposited performs were featured with the grain size about 3~5µm and a homogeneous distribution of ceramic particles the cooling rate up to 104K/s. Moreover, no cracking occurred in the performs because of the lower inner stress. The experimental results indicated that this novel technology was a promising and viable mean for the preparation of metal rings.