Papers by Keyword: Texture

Abstract: In recent years, nanostructured coatings by Plasma Thermal Spraying (PTS) attracted intense interest due to their enhanced mechanical properties as hardness, strength and ductility. The aim of this study was to evaluate the influence of coating the implant by nanohydroxyaptite, n-HAp, Ca10 (PO4)6(OH)2. The results obtained with n-HAp will also compared with the implant coated with HAp. Bone is a composite material in which are associated a mineral phase in the form of crystals of HAp and an organic matrix constituted by collagen. The c-axes of HAp and the collagen fibers are preferentially oriented in the direction of the stresses that the bones need to withstand. At the interface implant-bone, the new bone reconstituted after implantation must have the same proprieties of the original bone in order to have good fixation with the implant. Therefore, it is necessary to study the mechanical properties of this new bone crystals reconstituted at the interface with the implants coated with n-HAp and HAp by neutrons diffraction on D20 at ILL.

Abstract: This paper reports results of an in-situ compression experiment carried out on a hot rolled Zircaloy-4 plate at ENGIN-X, ISIS. The experiment was aimed at characterizing the plastic anisotropy of the alloy, which can give rise to high intergranular stresses in the polycrystal. As expected from the crystal anisotropy, the various lattice reflections had very different behaviours. In the compression directions, the basal <0002> reflections appeared to bear much more load than the other planes. The resulting intergranular elastic strains could therefore reach up to 5000 microstrain after 10% total deformation, and were responsible for high type II residual stresses after unloading. Considering the macroscopic behaviour, the normal direction had higher mechanical properties than the other two processing directions. The strong texture measured from EBSD measurements suggest that the crystal anisotropy has been brought to a macroscopic level. The experiment also evidenced a significant change in texture for compression along the rolling direction which indicates twinning activation.

Abstract: Hexagonal close-packed and lower symmetry metals often exhibit anisotropic mechanical properties because the dominant slip system forbids slip in certain lattice directions. Rod-textured Zircaloy-2 is a model system which can act as a road map for understanding more complex cases. In this case prism slip is dominant and pyramidal slip is only initiated at higher applied stresses. Tensile twinning does not always play a role since its initiation depends on the starting texture. Along the rod axis, Zircaloy-2 exhibits a very strong weighting of poles lying within the basal plane of the structure such as <10 1 0>, <11 2 0> etc. However, perpendicular to the rod axis, all poles are present. The coefficients of thermal expansion are unequal along the a- and c-axes of the crystal structure, so there are always large intrinsic thermal strains. Likewise, the mechanical properties perpendicular to the rod axis are dominated by the interaction of grains with hard and soft plastic response. Over two decades, the residual strains and the in-situ strain response parallel and perpendicular to the rod axis have been measured by neutron diffraction for both tensile and compressive applied stress. The paper reviews our understanding of the strain development for tensile and compressive applied stress in Zircaloy-2 in terms of slip and tensile twinning, the crucial part played by the thermal strains and the simplifying role of the strong texture.

Abstract: This paper reports the texture development in Si3N4 by strong magnetic field alignment (SMFA), using slip casting of α-Si3N4 raw powder (SN-E10) and pressureless sintering. The texture of β-Si3N4 in the green and sintered bodies was characterized by X-ray diffraction analysis (XRD) and scanning electron microscopy (SEM). The a, b-axis and c-axis aligned β-Si3N4 has been obtained by the static and rotating magnetic field of 12 T, respectively. The β-seed addition and prolonged sintering both enhance the texture, but the former is more efficient. This work suggests an efficient SMFA strategy of producing highly textured β-Si3N4, particularly the unidirectionally c-axis aligned β-Si3N4 by seeding the α-raw powder using the less-agglomerated β-phase particles.

Abstract: Spark plasma sintering was used to fabricate the LaPO4 ceramics and the effect of SPS holding time and sintering temperature on the densification and texture of LaPO4 ceramics were studied. The results revealed that holding time had no obvious influence on the densification of LaPO4 ceramics under the present process. The density increases with the increase of sintering temperature, when it reached 1350°C, the relative density kept nearly constant of 98.6 %. The preferred orientation of LaPO4 ceramics approximately increases with the increase of sintering temperature, but contrary impact in holding time.

Abstract: In the course of the increasing discussions about a reduction of the CO2 emissions magnesium has gained importance since it is the lightest metal for structural applications. Currently magnesium alloys are almost exclusively used as cast parts in the automotive industry because due to their microstructure extruded magnesium profiles exhibit a strong asymmetry in the mechanical properties under tensile and compressive loading (strength differential effect). In order to improve the mechanical properties a detailed knowledge about the influence of the different extrusion parameters on the microstructure of the extrudates is necessary. Therefore, the parameters extrusion method, billet temperature, product speed, extrusion ratio and cooling condition were varied for the extrusion of the magnesium alloys AZ31, AZ61 and AZ80. Subsequently the microstructure was analyzed and the mechanical properties determined. With an additional analysis of the deformation modes of the extruded and cold deformed products it could be discovered that an improvement of the mechanical properties can be achieved by a modification of the extrusion process. Since the strength differential effect in caused by twinning which due to the texture of the extrudates is only active under a compressive loading along the extrusion direction the modification of the extrusion process aims at a suppression of this twinning. Because on the one hand compared to that for dislocation glide the Hall-Petch-Constant for twinning is bigger a grain refinement of the extruded products could be achieved by a predeformation using ECAE similar processes. On the other hand a process has been developed where the profiles are extruded into a hydrostatic counter pressure in order to alter the texture during the extrusion. Thereby the twinning is already activated during the extrusion. Both modifications of the extrusion process result in an increase of the critical resolved shear stress for twinning during the subsequent cold deformation and thus in improved mechanical properties.

Abstract: Polycrystalline Cu has been deformed at room temperature by oscillatory compression method to true reduction εh = 0.6 and 1. Microstructure by using transmission electron microscopy (TEM) and texture evolution after deformations was investigated. Oscillatory compressed microareas contains two distinctive regions: fine grains inside banded microstructure with large misorientation and surrounding matrix with submicrometer subgrains with a fraction of both low and high angle boundaries. Moreover nucleation of new grains under recrystallization takes place at the local-regions. The study of the crystal orientation distribution during applied deformation showed that the pole figure registered for the sample after compression shows ring of pole density, which concentrates around projection of <011>. Oscillatory compression causes formation of two axial texture components: <001> and <011>.

Abstract: Accounting for secondary extinction (SE) of the intensities measured from a textured film by means of conventional X-ray diffractometer, a new X-ray diffraction method is described for determination of film thickness. Physically, the problem is restricted to using a reflection pair corresponding to the main component of the texture. As model sample a vacuum-deposited silver thin film is used.

Abstract: We have used synchrotron x-ray diffraction to study the crystal orientation in human dental enamel as a function of position within intact tooth sections. Keeping tooth sections intact has allowed us to construct 2D and 3D spatial distribution maps of the magnitude and orientation of texture in dental enamel. We have found that the enamel crystallites are most highly aligned at the expected occlusal points for a maxillary first premolar, and that the texture direction varies spatially in a three dimensional curling arrangement. Our results provide a model for texture in enamel which can aid researchers in developing dental composite materials for fillings and crowns with optimal characteristics for longevity, and will guide clinicians to the best method for drilling into enamel, in order to minimize weakening of remaining tooth structure, during dental restoration procedures.

Abstract: Controlling texture and microstructure evolution during annealing processes is very important for optimizing properties of steels. Theories used to explain annealing processes are complicated and always case dependent. An recently developed Monte Carlo simulation based model offers an effective tool for studying annealing process and can be used to verify the arbitrarily defined theories that govern such processes. The computer model takes Orientation Image Microscope (OIM) measurements as an input. The abundant information contained in OIM measurement allows the computer model to incorporate many structural characteristics of polycrystalline materials such as, texture, grain boundary character, grain shape and size, phase composition, chemical composition, stored elastic energy, and the residual stress. The outputs include various texture functions, grain boundary and grain size statistics that can be verified by experimental results. Graphical representation allows us to perform virtual experiments to monitor each step of the structural transformation. An example of applying this simulation to Si steel is given.