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Online since: April 2009
Authors: Tae Whan Hong, Ji Hee Park, Mie Won Jung
Evaluations of Hydrogen Permeation on γ-Al2O3 Synthesized by
Sol-Gel Process
Jihee Park1,a
, Miewon Jung1,b and Taewhan Hong2,c
1
Department of Chemistry, Sungshin Women's University, 136-742 Seoul, Korea
2
Department of Materials Science and Engineering/Research Center for Sustainable Eco-Devices
and materials(ReSEM), Chungju National University, Chungju 380-702, Korea
a
chung520@sungshin.ac.kr,
b
mwjung@sungshin.ac.kr, ctwhong@cjnu.ac.kr
Keywords: γ-Al2O3, Sol-gel process, Hydrogen permeation
Abstract.
The structure of the phase transformation of Al2O3 was determined by powder X-ray diffraction(XRD) using CuKα radiation (λ=1.5406Å), Bruker D8 Focus instrument.
The α-Al2O3 crystalline structure is hexagonal close packing of oxygen while the structure of the other phases except for α phase is tetragonal distorted spinel [7].
This structure has an effect on XRD patterns with differences of intensity result from phase transformation.
Also, this crystalline structure was caused γAl2O3 has many vacancies on surface so it used to catalyst of catalyst support widely to have unique specific surface area.
The structure of the phase transformation of Al2O3 was determined by powder X-ray diffraction(XRD) using CuKα radiation (λ=1.5406Å), Bruker D8 Focus instrument.
The α-Al2O3 crystalline structure is hexagonal close packing of oxygen while the structure of the other phases except for α phase is tetragonal distorted spinel [7].
This structure has an effect on XRD patterns with differences of intensity result from phase transformation.
Also, this crystalline structure was caused γAl2O3 has many vacancies on surface so it used to catalyst of catalyst support widely to have unique specific surface area.
Online since: December 2012
Authors: Han Yang, Xiang Hong Zhang, Xian Da Xie, Ying Ze Wang
Picture 1 Sectional structure and surface structure of PVC hollow fiber big pore ultra filtration membrane
Powdered Activated Carbon.
Principle and Structure of Water Purifier Operating Principle of Water Purifier.
Structure of Water Purifying Plant.
The shell is made of stainless steel 304, and plug-in replaceable filter element is adopted as membrane filter element and activated carbon filter element, end cover on top of shell adopts clamp spring structure, which is easily to be dismantled and maintained as well as to replace filter element, the aeration outlet is set at the bottom of shell of front-mounted pressure shell-type external pressure membrane filter, and cross flow discharge outlet and water-producing nozzle are installed at the upper end, water distributor is installed inside the activated carbon filter, and automatic air valve is mounted in the upper part of rear-mounted pressure shell-type external membrane filter.
Tengteng; Influence of dosing powdered activated carbon in front-end filter on effluent turbidity;Water Technology 2011.02 [3] Zhang Pengfeng1,Yang Yingjie,Zhang Wenchao,Chang Jiang;Study on the Influence of Reclaimed Wastewater UV disinfection by GAC Enhanced sand Filtration; Water & Wastewater Engineering, 2011.02 [4] Zhibin Qian,Wei Shen,Ye Jiang;Study on Micro-wave ultraviolet disinfection technology Water Prospect; Automation & Instrumentation, 2011.01 [5] Fei Yuan, Modified Ultrafiltration Research Progress in China and Abroad, Guangzhou Chemical Industry,2011.12 [6] Hester JF, Mayes AM.Design and performance of foul-resistant acrylonitrile and polysulphone Journal of Membrane Science,1996,111poly (vinylidene fluoride)membranes prepared in a single-step by (2):193-215; [7] Thoml V,Jankoval K,Ulbricht M.Synthesis of photoreactive a-4 azidobenzoyl x methoxypoly( ethylene glycol) s and their end - on photo - grafting onto polysulfone ultrafiltration membranes, Macromo-lecular Chemistry
Principle and Structure of Water Purifier Operating Principle of Water Purifier.
Structure of Water Purifying Plant.
The shell is made of stainless steel 304, and plug-in replaceable filter element is adopted as membrane filter element and activated carbon filter element, end cover on top of shell adopts clamp spring structure, which is easily to be dismantled and maintained as well as to replace filter element, the aeration outlet is set at the bottom of shell of front-mounted pressure shell-type external pressure membrane filter, and cross flow discharge outlet and water-producing nozzle are installed at the upper end, water distributor is installed inside the activated carbon filter, and automatic air valve is mounted in the upper part of rear-mounted pressure shell-type external membrane filter.
Tengteng; Influence of dosing powdered activated carbon in front-end filter on effluent turbidity;Water Technology 2011.02 [3] Zhang Pengfeng1,Yang Yingjie,Zhang Wenchao,Chang Jiang;Study on the Influence of Reclaimed Wastewater UV disinfection by GAC Enhanced sand Filtration; Water & Wastewater Engineering, 2011.02 [4] Zhibin Qian,Wei Shen,Ye Jiang;Study on Micro-wave ultraviolet disinfection technology Water Prospect; Automation & Instrumentation, 2011.01 [5] Fei Yuan, Modified Ultrafiltration Research Progress in China and Abroad, Guangzhou Chemical Industry,2011.12 [6] Hester JF, Mayes AM.Design and performance of foul-resistant acrylonitrile and polysulphone Journal of Membrane Science,1996,111poly (vinylidene fluoride)membranes prepared in a single-step by (2):193-215; [7] Thoml V,Jankoval K,Ulbricht M.Synthesis of photoreactive a-4 azidobenzoyl x methoxypoly( ethylene glycol) s and their end - on photo - grafting onto polysulfone ultrafiltration membranes, Macromo-lecular Chemistry
Online since: January 2011
Authors: Min Zhu, Wen Song Hu, Wei Dong Liu
Initially the neural network applications in data mining has not got good views, mainly because the neural network has its defects such as complex structure, poor interpretability and long training time.
The principle structure of fuzzy neural network system is shown as figure 2.
Structure principle of FNN Algorithm of FNN Structure of FNN.
Figure 3 shows the structure of fuzzy neural system model.
[2] L.qiongzhi, “knowledge discovery and data mining based fuzzy neural network,” Berjing chemistry university master paper, pp. 31-42, Mar 2003
The principle structure of fuzzy neural network system is shown as figure 2.
Structure principle of FNN Algorithm of FNN Structure of FNN.
Figure 3 shows the structure of fuzzy neural system model.
[2] L.qiongzhi, “knowledge discovery and data mining based fuzzy neural network,” Berjing chemistry university master paper, pp. 31-42, Mar 2003
Online since: January 2013
Authors: Yan Zhi Xia, Zong Hua Wang, Fei Fei Zhang, Jian Fei Xia, Lin Hua Xia, Zheng Xiao Liu
As an attractive electrode material, graphene has special structures that make it own the corresponding property which shows great potential to prepare biosensors and apply in energy storage.
Due to its unique circular tube structure, CNTs are often seen as an ideal material to polymerize or composite with other materials, such as metal oxide, nano particles and other carbon materials, which leads to new materials applied in scientific research.
That is because graphene can easily twist during the process of dispersion, which could block the advantages of its unique structures.
It is found that the peak current of UA on G/GCE is higher than that of CNTs/GCE, that is because the graphene which is two dimensionality structure have larger specific surface area and better electrical conductivity than that of CNTs which is one dimensionality structure, so catalytic action for uric acid oxidation is stronger on G/GCE.
Acknowledgements This work was financially supported by National Natural Science Foundation of China (authorized number: 20975056, 21275082 and 81102411), Natural Science Foundation of Shandong (ZR2011BZ004, ZR2011BQ005), JSPS and NSFC under the Japan-China Scientific Cooperation Program (21111140014), State Key Laboratory of Analytical Chemistry for Life Science (SKLACLS1110) and the National Key Basic Research Development Program of China (973 special preliminary study plan, Grant no.: 2012CB722705).
Due to its unique circular tube structure, CNTs are often seen as an ideal material to polymerize or composite with other materials, such as metal oxide, nano particles and other carbon materials, which leads to new materials applied in scientific research.
That is because graphene can easily twist during the process of dispersion, which could block the advantages of its unique structures.
It is found that the peak current of UA on G/GCE is higher than that of CNTs/GCE, that is because the graphene which is two dimensionality structure have larger specific surface area and better electrical conductivity than that of CNTs which is one dimensionality structure, so catalytic action for uric acid oxidation is stronger on G/GCE.
Acknowledgements This work was financially supported by National Natural Science Foundation of China (authorized number: 20975056, 21275082 and 81102411), Natural Science Foundation of Shandong (ZR2011BZ004, ZR2011BQ005), JSPS and NSFC under the Japan-China Scientific Cooperation Program (21111140014), State Key Laboratory of Analytical Chemistry for Life Science (SKLACLS1110) and the National Key Basic Research Development Program of China (973 special preliminary study plan, Grant no.: 2012CB722705).
Online since: November 2020
Authors: Dmitry V. Mashtalyar, Sergey V. Gnedenkov, Sergey L. Sinebryukhov, Igor M. Imshinetsky, Vladimir S. Egorkin, Konstantine V. Nadaraia, Igor E. Vyaliy, Alexander N. Minaev, Valeriia S. Filonina, Andrey S. Gnedenkov, Andrey P. German
Gnedenkov1,k
1 Institute of Chemistry FEB RAS, 159 pr. 100-letiya Vladivostoka, Vladivostok 690022,
2 Far Eastern Federal University, 8 Sukhanova St., Vladivostok 690950, Russia
a*filonina.vs@gmail.com, bnadaraiakv@mail.ru, cmadiva@inbox.ru, dasg17@mail.com, eigorimshin@gmail.com, fgerman.ap@dvfu.ru, gigorvyal@gmail.com, hegorkin@ich.dvo.ru, iaminaev@mail.ru, jsls@ich.dvo.ru, ksvg21@hotmail.com
Keywords: Aluminum alloys, protective coatings, plasma electrolytic oxidation, superdispersed polytetrafluoroethylene, superhydrophobicity, wear, adhesion.
The prospects are explained by material`s structure and properties.
Aluminium structures - a guide to their specifications and design.
Engineering Structures, 18 (1), 90 (1996). https://doi.org/10.1016/s0141-0296(96)90020-6
Functional Plasma Electrolytic Oxidation Coatings for Offshore Structures.
The prospects are explained by material`s structure and properties.
Aluminium structures - a guide to their specifications and design.
Engineering Structures, 18 (1), 90 (1996). https://doi.org/10.1016/s0141-0296(96)90020-6
Functional Plasma Electrolytic Oxidation Coatings for Offshore Structures.
Online since: September 2013
Authors: Lian Ying Wu, Ran Ran Zhao
Dynamic simulation of Petlyuk column for separation of ternary mixtures
Lianying Wu1a, Ranran Zhao1b
College of chemistry and chemical engineering, Ocean University of China. 266100, Qingdao,CHINA
awulianying@ouc.edu.cn , bunionpayatm@163.com
Key words: Dynamic simulating; Petlyuk column; control scheme; RGA
Abstract: The Petlyuk distillation configuration has received considerable attention because of its efficiency to reduce the energy required for the separation of ternary mixtures.
A thermally coupled structure shows an interconnection between two columns with a liquid or vapor extraction from the first column and a recycle stream from the other column in the other phase; such interconnection can be implemented in place of a reboiler or a condenser of one of the columns.
Wolff and Skogestad[2] carried out a control analysis of the Petlyuk system and found the system to be controllable when a three-point control structure was implemented.
The control performance of several alternative structures to the Petlyuk column has been recently reported[6] and the results showed that the control behavior of the Petlyuk system is not necessarily improved by lowering the number of thermal couplings.
Conclusion The structure of the Petlyuk system offers some control challenges arising from the transfer of vapor streams back and forth between the columns.
A thermally coupled structure shows an interconnection between two columns with a liquid or vapor extraction from the first column and a recycle stream from the other column in the other phase; such interconnection can be implemented in place of a reboiler or a condenser of one of the columns.
Wolff and Skogestad[2] carried out a control analysis of the Petlyuk system and found the system to be controllable when a three-point control structure was implemented.
The control performance of several alternative structures to the Petlyuk column has been recently reported[6] and the results showed that the control behavior of the Petlyuk system is not necessarily improved by lowering the number of thermal couplings.
Conclusion The structure of the Petlyuk system offers some control challenges arising from the transfer of vapor streams back and forth between the columns.
Online since: July 2013
Authors: Gang Yang, Yuan Zheng Tang, Yan He, Lian Xiang Ma
Introduction
As is well known, EPDM and its composites have been widely used in industry and household fields due to the excellent mechanical properties and the excellent chemistry stability.
In order to understanding thermal transport in EPDM and its composites, microscopic research on structure-property relationships is necessary.
Physical Model and Simulation Procedure Potential and Molecular Structure for EPDM.
The molecular structure of EPDM is built by Materials Studio® software [12].
Then after, an initial constant energy (NVE) simulation is performed to get the equilibrated structure in micro-canonical ensemble.
In order to understanding thermal transport in EPDM and its composites, microscopic research on structure-property relationships is necessary.
Physical Model and Simulation Procedure Potential and Molecular Structure for EPDM.
The molecular structure of EPDM is built by Materials Studio® software [12].
Then after, an initial constant energy (NVE) simulation is performed to get the equilibrated structure in micro-canonical ensemble.
Online since: January 2016
Authors: Amporn Wiengmoon, Torranin Chairuangsri, Jeerapat Nakpratum, John T.H. Pearce
Pearce3,c
1Department of Physics, Faculty of Science, Naresuan University, Phitsanulok, 65000, Thailand.
2Department of Industrial Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai, 50200, Thailand.
3Panyapiwat Institute of Management, Nonthaburi, 11120, Thailand.
%Cr irons with stable ferritic matrix structures can provide superior heat resistance compared to the austenitic matrix 2.5-3.2wt.
The structure and chemical composition of the oxide layer were analyzed by X-ray diffraction (XRD) and energy dispersive spectroscopy (EDS).
The XRD diffraction pattern of the iron exposed for 24 h (Fig. 3) indicated that V and Fe can accompany in the chromium-rich oxide structure so that the outer oxide layer comprises of chromia (Cr2O3) and (Cr,Fe,V)2O3.
The incorporation of vanadium in the chromium-rich oxide structure can be beneficial in retarding oxidation rate.
%Cr irons with stable ferritic matrix structures can provide superior heat resistance compared to the austenitic matrix 2.5-3.2wt.
The structure and chemical composition of the oxide layer were analyzed by X-ray diffraction (XRD) and energy dispersive spectroscopy (EDS).
The XRD diffraction pattern of the iron exposed for 24 h (Fig. 3) indicated that V and Fe can accompany in the chromium-rich oxide structure so that the outer oxide layer comprises of chromia (Cr2O3) and (Cr,Fe,V)2O3.
The incorporation of vanadium in the chromium-rich oxide structure can be beneficial in retarding oxidation rate.
Online since: January 2016
Authors: Eva Vejmelková, Martin Keppert, Robert Černý, Monika Čáchová, Dana Koňáková, Pavel Reiterman, Kateřina Šestáková
Measurement methods, such basic physical properties (water vacuum saturation and helium pycnometry), pore structure characterization (mercury porosimetry) and mechanical properties (compressive and bending strengths) and experimental results are described and discussed.
The pore structure characteristics were measured by mercury intrusion porosimetry.
Although the utilization of the building material is restricted for non-loading structures, its advantages (mainly thermal resistance) do its utilization suitable and appropriate.
However the pore structures of all studied composites were really different.
Basic physical properties and mainly the pore structure influenced all other properties.
The pore structure characteristics were measured by mercury intrusion porosimetry.
Although the utilization of the building material is restricted for non-loading structures, its advantages (mainly thermal resistance) do its utilization suitable and appropriate.
However the pore structures of all studied composites were really different.
Basic physical properties and mainly the pore structure influenced all other properties.
Online since: December 2011
Authors: Qing Chi Sun, Feng Kuo Zhao, Wei Bing Ma, Hai Quan Liu, Yong Zhang
In the perovskite structure, the Pb2+ vacancy concentration in grains can reduce the mechanical tension on the grain boundaries.
The phase structures of the samples were analyzed using X-ray diffractometry with a 2θ range from 100 to 900.
It was apparent that when the Pb content was higher than 0.96, the specimens exhibited a pure perovskite structure, while there were no detectable traces of the ZrO2 or other impurities observed.
The existence of ZrO2 changes the Zr/Ti ratio in the proverskite structure, and the main phase translates to tetragonal phase.
Thakur: Materials Letters 57 (2003) 2310–2314 [4] Moo-Chin Wang, Mao-Sung Huang, Nan-Chung Wu: Materials Chemistry and Physics 77 (2002) 103–109 [5] Ajai Garg, D.C.
The phase structures of the samples were analyzed using X-ray diffractometry with a 2θ range from 100 to 900.
It was apparent that when the Pb content was higher than 0.96, the specimens exhibited a pure perovskite structure, while there were no detectable traces of the ZrO2 or other impurities observed.
The existence of ZrO2 changes the Zr/Ti ratio in the proverskite structure, and the main phase translates to tetragonal phase.
Thakur: Materials Letters 57 (2003) 2310–2314 [4] Moo-Chin Wang, Mao-Sung Huang, Nan-Chung Wu: Materials Chemistry and Physics 77 (2002) 103–109 [5] Ajai Garg, D.C.