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Online since: September 2011
Authors: Guo Ping Yao, Jin Huan Zheng, Hui Fen Chen
The nature of VE is very unstable, when exposed to the air, the phenolic hydroxyl group of VE structure is oxidized susceptibly and has no longer biological activity.
The effective way is to wrap up the sensitive part of VE molecule so as to keep it from contacting with air, for example, microencapsulation [2], transforming it into its derivatives by modifying its structure such as VE acetate [3] and VE linoleate [4].
Prepolymerization of Polyurethane Influence of isocyanate structure on reaction activity is reflected in two aspects: inductive effect and steric effect. 2,4-TDI is an aromatic diisocyanate that includes two NCO groups, ortho- and para-NCO, which have an inducement with each other to make reaction activity of the isocyanate increase.
References [1] Block G, Langseth L: Food Technology, No.7 (1994), p. 80-84 [2] H G Tang, W S Xia, in Chinese: Journal of Cereals and Oils, No.3 (2005), p. 7-9 [3] Bulychev E Y: Pharmaceutical Chemistry Journal, Vol. 32, No. 6 (1998), p. 331-332 [4] Horie M, Vitamin E Linoleate, JP 57,193,473. (1982) [5] Aneja A, Wilkes GL, Rightor EG: J.
The effective way is to wrap up the sensitive part of VE molecule so as to keep it from contacting with air, for example, microencapsulation [2], transforming it into its derivatives by modifying its structure such as VE acetate [3] and VE linoleate [4].
Prepolymerization of Polyurethane Influence of isocyanate structure on reaction activity is reflected in two aspects: inductive effect and steric effect. 2,4-TDI is an aromatic diisocyanate that includes two NCO groups, ortho- and para-NCO, which have an inducement with each other to make reaction activity of the isocyanate increase.
References [1] Block G, Langseth L: Food Technology, No.7 (1994), p. 80-84 [2] H G Tang, W S Xia, in Chinese: Journal of Cereals and Oils, No.3 (2005), p. 7-9 [3] Bulychev E Y: Pharmaceutical Chemistry Journal, Vol. 32, No. 6 (1998), p. 331-332 [4] Horie M, Vitamin E Linoleate, JP 57,193,473. (1982) [5] Aneja A, Wilkes GL, Rightor EG: J.
Online since: November 2011
Authors: Jing Bo Zhu, Jian Hua Li, Zong Jian Zheng, Shao Ping Fu
Preparation and Characterization of Paclitaxel Imprinted Silica Nanoparticles
Jianhua Li1 a, Zongjian Zheng2 b, Shaoping Fu1,2 c*, Jingbo Zhu1,2 d*
1School of Food Science and Technology, Dalian Polytechnic University, Dalian 116034, China
2Insitute of Chemistry and Applications of Plant Resourced, Dalian Polytechnic University, Dalian 116034, China
d*zhujingb@sina.com, c*shaopingfu@gmail.com, alijianhua_2009@163.com, bzhengzongjian.cn@163.com
Key words: molecular imprinting technique, a sol–gel process, silica nanoparticles, paclitaxel.
The structures of paclitaxel and 10-DAB III are shown in Fig. 1.
The structures of paxlitaxel and 10-DAB III Experimental Synthesis of the molecularly imprinted layer-coated silica nanoparticles.
The polymerization reaction was carried out at room temperature under stirring for 20 h to obtain particles with a high cross-linking structure.
The structures of paclitaxel and 10-DAB III are shown in Fig. 1.
The structures of paxlitaxel and 10-DAB III Experimental Synthesis of the molecularly imprinted layer-coated silica nanoparticles.
The polymerization reaction was carried out at room temperature under stirring for 20 h to obtain particles with a high cross-linking structure.
Online since: November 2011
Authors: Deng Liang He, Lai Bao Liu, Dong Mei Zhao
Study on Photocatalysis Degradation of Phenol by Using Tourmaline/ TiO2 System as Catalyst
Liu Laibao1, 2, a He Dengliang3 Zhao Dongmei1
(1State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology, Mianyang 621010, China;
2School of Materials Science and Engineering, Southeast University, Nanjing 211189, China;
3Department of Chemistry, Mianyang Nomal Uiversity, Mianyang 621000, China;)
aemail: liulaibao@swust.edu.cn
Key words: Tourmaline; Titanium dioxide; Photoelectrocatalysis
Abstract :The authors use the method of titanium salts on the surface of tourmaline particles hydrolyzing and coating TiO2 to construct Tourmaline/ TiO2 system in different conditions and characterize the catalyst system by TEM and SEM and Raman Spectra Pattern.
As the vertex angles of silicon-oxygen tetrahedron of six-membered ring in tourmaline structure point to the same direction, it would make tourmaline have great hetero-grade symmetrical structure and so produce spontaneous polarization similar to that of magnet pole, which apparently appears as piezoelectricity and thermoelectricity.
Fig. 1 Zeta potential test result of tourmaline powder Fig. 2 Raman Spectra pattern of catalysis system A TEM picture of tourmaline raw mineral B SEM picture of tourmaline surface encapsulation status in catalyst system Fig.3 Microscope structure picture of catalyst system 3.2 Photo-catalysis Performance Test 3.2.1 The Photo-catalysis Activity of Tourmaline/TiO2 Catalysis System In this experiment tourmaline and TiO2 were added in a rate of 0.2, 0.4, 0.6, 0.8 and 1.0.
As the vertex angles of silicon-oxygen tetrahedron of six-membered ring in tourmaline structure point to the same direction, it would make tourmaline have great hetero-grade symmetrical structure and so produce spontaneous polarization similar to that of magnet pole, which apparently appears as piezoelectricity and thermoelectricity.
Fig. 1 Zeta potential test result of tourmaline powder Fig. 2 Raman Spectra pattern of catalysis system A TEM picture of tourmaline raw mineral B SEM picture of tourmaline surface encapsulation status in catalyst system Fig.3 Microscope structure picture of catalyst system 3.2 Photo-catalysis Performance Test 3.2.1 The Photo-catalysis Activity of Tourmaline/TiO2 Catalysis System In this experiment tourmaline and TiO2 were added in a rate of 0.2, 0.4, 0.6, 0.8 and 1.0.
Online since: May 2014
Authors: Kai Yan, Xiao Xu Liu
It was established that the morphology of the PI/titania hybrid can be controlled by introducing titania structure onto main and side chain of PI molecule,[5-6]The adding coupling agents KH550 were concentrated on improving the interfacial interaction between organic and inorganic components to make titania inorganic particles disperse in PI matrix.
The diffuse interface layer could probably be fitted with the following equation: E=(2π)0.5s , where s is negative slope of hybrid films, E is the average thickness of the interface layer which is a characteristic structure parameter in relation to the physical and chemical properties of materials.
The micro morphology, structure, and electrical and mechanical properties of PI/TiO2 nanocomposite films were studied.
Tsai, Highly fl{TTP}-1278 exible and optical transparent 6F-PI/TiO2 optical hybrid fi{TTP}-1279 lms with tunable refractive index and excellent thermal stability Journal of Materials Chemistry,Vol.20,pp. 531-536,2010 [4]L.Y.
The diffuse interface layer could probably be fitted with the following equation: E=(2π)0.5s , where s is negative slope of hybrid films, E is the average thickness of the interface layer which is a characteristic structure parameter in relation to the physical and chemical properties of materials.
The micro morphology, structure, and electrical and mechanical properties of PI/TiO2 nanocomposite films were studied.
Tsai, Highly fl{TTP}-1278 exible and optical transparent 6F-PI/TiO2 optical hybrid fi{TTP}-1279 lms with tunable refractive index and excellent thermal stability Journal of Materials Chemistry,Vol.20,pp. 531-536,2010 [4]L.Y.
Online since: December 2014
Authors: Marcos Flavio de Campos, José Adilson de Castro
Model description
The microstructure of the phases was modeled using a hexagonal cell structure representing the grains and contour phases.
(1) where the diffusion coefficient is given, according to the grains and inter granular phases, as follows: (2) (3) (4) Dy = 100% Fig. 1 Grain structure and applied boundary conditions for Dy diffusion.
Figure 1 shows the grain structure and the boundary conditions applied for the simulations of the Dy diffusions within the intergranular phase.
In: Handbook on the Physics and Chemistry of Rare Earths, Edited by K.
(1) where the diffusion coefficient is given, according to the grains and inter granular phases, as follows: (2) (3) (4) Dy = 100% Fig. 1 Grain structure and applied boundary conditions for Dy diffusion.
Figure 1 shows the grain structure and the boundary conditions applied for the simulations of the Dy diffusions within the intergranular phase.
In: Handbook on the Physics and Chemistry of Rare Earths, Edited by K.
Online since: May 2013
Authors: Yi Gang Luan, Zheng Heng Zhao, Peng Fei Liu
Basing on souders-brown equation [1] and relative theory, referring to the structure which is mentioned in the reference [2], a new style of gas-liquid separating scrubber is designed and its fluid flow is simulated.
Its structure is shown in Fig 1.
body Vane-inlet Lower cover Mist-mat Drain pipe Cyclone deck Upper cover Cyclone tube Upper panel Lower panel Separation hole Helical blade liquid gas Lower panel Guide vane Upper panel Fig.1 Structure of the scrubber 1.
Entrainment and Capacity, Industrial & Engineering Chemistry, 2, 98-103, (1934) [2] Trond Austrheim, Lars H.Gjertsen and Alex C.
Its structure is shown in Fig 1.
body Vane-inlet Lower cover Mist-mat Drain pipe Cyclone deck Upper cover Cyclone tube Upper panel Lower panel Separation hole Helical blade liquid gas Lower panel Guide vane Upper panel Fig.1 Structure of the scrubber 1.
Entrainment and Capacity, Industrial & Engineering Chemistry, 2, 98-103, (1934) [2] Trond Austrheim, Lars H.Gjertsen and Alex C.
Online since: November 2007
Authors: Besim Ben-Nissan, Kanthi Lewis, S.M. Valenzuela
Ben-Nissan
1
1 Department of Chemistry Materials and Forensic Science, 2
Department of Medical and Molecular
Biosciences, University of Technology Sydney, PO Box 123 Broadway NSW 2007 Australia
a
Kanthi.Lewis@uts.edu.au
Keywords: bone, sol-gel, hyroxyapatite, zirconia, nanocoatings, osteoblast
Abstract.
Introduction Implant materials are being increasingly designed to provide optimal pore structure for osteointegration, and a subsequent increase in the bone to implant bond [1].
It results in a stoichiometric, homogeneous and pure coating due to mixing on the molecular scale; reduced firing temperatures due to small particle sizes with high surface areas; it has the ability to produce uniform fine-grained structures; the use of different chemical routes (alkoxide or aqueousbased); and their ease of application to complex shapes with a range of coating techniques: dip, spin, and spray coating.
Results and Discussion FTIR studies showed that HAp coatings were pure carbonated hydroxyapatite with a nanocrystalline structure.
Introduction Implant materials are being increasingly designed to provide optimal pore structure for osteointegration, and a subsequent increase in the bone to implant bond [1].
It results in a stoichiometric, homogeneous and pure coating due to mixing on the molecular scale; reduced firing temperatures due to small particle sizes with high surface areas; it has the ability to produce uniform fine-grained structures; the use of different chemical routes (alkoxide or aqueousbased); and their ease of application to complex shapes with a range of coating techniques: dip, spin, and spray coating.
Results and Discussion FTIR studies showed that HAp coatings were pure carbonated hydroxyapatite with a nanocrystalline structure.
Online since: January 2021
Authors: Toshihide Takenaka, Taiki Morishige, Hayato Ikoma
The Influence of Introduced Strains on the Exfoliation Corrosion Behavior of Mg-14mass%Li-1mass%Al Alloy
Hayato IKOMA1,a*, Taiki MORISHIGE2,b, Toshihide TAKENAKA2,c
1Graduate School of Science and Engineering, Kansai University, 3-3-35, Yamate-cho,
Suita 564-8680, Japan
2Dept. of Chemistry and Material Engineering, Kansai University, 3-3-35, Yamate-cho,
Suita 564-8680, Japan
ak823003@kansai-u.ac.jp, btmorishi@kansai-u.ac.jp, cttakenak@kansai-u.ac.jp
Keywords: Mg-Li alloy, exfoliation corrosion, microstructure, cold-worked
Abstract.
However, Mg alloys have difficulty in cold-workability because of their crystal structure.
In order to improve the workability of Mg alloys, bcc-structured Mg-Li alloys were developed.
In addition to its lightweight, Mg-Li alloys are more susceptible to corrosion than hcp-structured Mg alloys.
However, Mg alloys have difficulty in cold-workability because of their crystal structure.
In order to improve the workability of Mg alloys, bcc-structured Mg-Li alloys were developed.
In addition to its lightweight, Mg-Li alloys are more susceptible to corrosion than hcp-structured Mg alloys.
Online since: November 2010
Authors: Cui Jin Pei, Guo Guang Yao, Xiu Lao Tian, Hong Ma
Effect of Li2CO3-V2O5 on the sintering and microwave dielectric properties of 0.6Mg4Nb2O9-0.4SrTiO3 composite ceramics
Cui Jin Pei1, Guo Guang Yao2,a, Xiu Lao Tian2 and Hong Ma2
1Department of Applied Chemistry, Yun Cheng University, Yun Cheng, Shanxi 04000, China
2School of Science, Xi’an University of Posts and Telecommunications, Xi’an 710121, China
ayaoguoguang@xupt.edu.cn
Keywords: Composite ceramics; Dielectric properties; Sintering aids; 0.6Mg4Nb2O9-0.4SrTiO3.
The crystal structures were analyzed by X-ray diffraction (XRD, Rigaku D/MAX2550, Japan).
For the calcined powders, two phases, corresponding to corundum-type structure Mg4Nb2O9 (ICDD #38-1459) and perovskite structure SrTiO3 (ICDD #35-0734), can be indentified from the XRD patterns.
The crystal structures were analyzed by X-ray diffraction (XRD, Rigaku D/MAX2550, Japan).
For the calcined powders, two phases, corresponding to corundum-type structure Mg4Nb2O9 (ICDD #38-1459) and perovskite structure SrTiO3 (ICDD #35-0734), can be indentified from the XRD patterns.
Online since: January 2015
Authors: Hui Ping Shao, Hang Zheng, Zi Fen Zhao
When γ-Fe2O3 grain comes into nano-size, it gets more excellent magnetic properties than the usual structure, the coercive force also greatly improves, and the magnetic recording materials made by can significantly improve the signal-to-noise ratio and image quality, and can achieve high-density information re-cording.
Fig.4 Hysteresis loop of magnetic particles and magnetic fluid pre-pared (①.Magnetic particles(a.Fe3O4;b.γ-Fe2O3); ②.Magnetic fluid prepared(a.Fe3O4;b.γ-Fe2O3)) Conclusion The structure of Fe3O4 surrounded by oleic acid was not damaged during the thermal oxidizing.
Journal of Organ metallic Chemistry, 2013, 740(3): 50-55
The Iron Oxides: Structure, Properties, Reactions, Occurrence and Uses[M].
Fig.4 Hysteresis loop of magnetic particles and magnetic fluid pre-pared (①.Magnetic particles(a.Fe3O4;b.γ-Fe2O3); ②.Magnetic fluid prepared(a.Fe3O4;b.γ-Fe2O3)) Conclusion The structure of Fe3O4 surrounded by oleic acid was not damaged during the thermal oxidizing.
Journal of Organ metallic Chemistry, 2013, 740(3): 50-55
The Iron Oxides: Structure, Properties, Reactions, Occurrence and Uses[M].