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Online since: April 2011
Authors: Shi Qiang Cui, Shou Zhi Pu, Ming Liu, Gang Liu, Wei Li
Synthesis, Properties and Application in Optical Memory of A new Photochromic Diarylethene
Ming Liu, Wei Li, Shouzhi Pu*, Gang Liu, Shiqiang Cui
Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University
Nanchang 330013, P.
The structure of 1a was characterized by 1H NMR.
The structure of 1a was characterized by 1H NMR. 1H NMR (400 MHz, CDCl3, ppm): δ 1.93 (s, 3H, -CH3), 2.29 (s, 3H, -CH3), 7.17 (s, 1H, thiophene-H), 7.23 (d, 1H, benzene-H), 7.26 (t, 1H, benzene-H), 7.28-7.30(t, 2H, benzothiophene-H), 7.33 (d, 1H, benzene-H), 7.35 (s, 1H, benzene-H), 7.57-7.59(d, 1H, benzothiophene-H), 7.67-7.68(d, 1H, benzothiophene-H) Scheme 2.
The structure of 1a was characterized by 1H NMR.
The structure of 1a was characterized by 1H NMR. 1H NMR (400 MHz, CDCl3, ppm): δ 1.93 (s, 3H, -CH3), 2.29 (s, 3H, -CH3), 7.17 (s, 1H, thiophene-H), 7.23 (d, 1H, benzene-H), 7.26 (t, 1H, benzene-H), 7.28-7.30(t, 2H, benzothiophene-H), 7.33 (d, 1H, benzene-H), 7.35 (s, 1H, benzene-H), 7.57-7.59(d, 1H, benzothiophene-H), 7.67-7.68(d, 1H, benzothiophene-H) Scheme 2.
Online since: December 2012
Authors: Gang Liu, Shi Qiang Cui, Min Deng, Ren Jie Wang
Synthesize, Photochromic and Application for Optical Recording of Diarylthene Bearing Naphthyl Unit
Shiqiang Cui, Min Deng, Renjie Wang and Gang Liu*
Jiangxi Key Laboratory of Organic Chemistry,Jiangxi Science & Technology Normal University, Nanchang 330013, P.
The diarylethene bearing naphthyl rings possesses excellent thermal stability, where the absorption intensity of its closed-ring isomer remains relatively constant for more than 500 h even at 343 K [12] However, photochromic diarylethene derivatives based on a hybrid structure of condensed aromatics and five-membered heteroaryl moieties have rare reported except for us.
The structures of diarylethenes 1o were confirmed 1H NMR spectroscopy. 1H NMR (400 MHz, CDCl3, TMS): 2.22 (s, 3H, –CH3), 2.34 (s, 3H, –CH3), 6.95 (s, 1H, thiophene–H), 7.26 (d, 1H, benzene–H), 7.33 (d, 1H, benzene–H, J = 8.0 Hz), 7.49 (t, 2H, benzene–H, J = 8.0 Hz), 7.54 (t, 3H, naphthalene–H, J = 8.0 Hz), 7.68 (d, 1H, naphthalene–H, J = 8.0 Hz), 7.82 (d, 2H, naphthalene–H, J = 8.0 Hz).
The diarylethene bearing naphthyl rings possesses excellent thermal stability, where the absorption intensity of its closed-ring isomer remains relatively constant for more than 500 h even at 343 K [12] However, photochromic diarylethene derivatives based on a hybrid structure of condensed aromatics and five-membered heteroaryl moieties have rare reported except for us.
The structures of diarylethenes 1o were confirmed 1H NMR spectroscopy. 1H NMR (400 MHz, CDCl3, TMS): 2.22 (s, 3H, –CH3), 2.34 (s, 3H, –CH3), 6.95 (s, 1H, thiophene–H), 7.26 (d, 1H, benzene–H), 7.33 (d, 1H, benzene–H, J = 8.0 Hz), 7.49 (t, 2H, benzene–H, J = 8.0 Hz), 7.54 (t, 3H, naphthalene–H, J = 8.0 Hz), 7.68 (d, 1H, naphthalene–H, J = 8.0 Hz), 7.82 (d, 2H, naphthalene–H, J = 8.0 Hz).
Online since: June 2013
Authors: Zhi Wei Li, Xing Jia, Chun Mei Xu, Lei Liu, De Cai Fu
Chiral separation of amlodipine and its enantiomer on a molecularly imprinted polymer-based stationary phase
Zhiwei Li1,2,a, Xing Jia1,b , Chunmei Xu3,c, Lei Liu1,2,d, Decai Fu1,2,e
1 College of Chemical &Pharmaceutical Enginering, Hebei University of Science and Technology, Shijiazhuang 050018, China
2 State Key Laboratory Breeding Base—Hebei Province Key Laboratory of Molecular Chemistry for Drug, Hebei University of Science and Technology,, Shijiazhuang 050018, China
3 Hebei Huaxu Pharmaceutical CO.
Introduction Molecularly imprinted polymer (MIP) materials are nowadays commonly used for separation of organic materials of similar structures, even enantiomers, as custom made chromatographic supports [1-3].
Structure of amlodipine.
Introduction Molecularly imprinted polymer (MIP) materials are nowadays commonly used for separation of organic materials of similar structures, even enantiomers, as custom made chromatographic supports [1-3].
Structure of amlodipine.
Online since: November 2017
Authors: Yuan Hu, Lei Song, Ying Pan
PEI was kindly provided by Aladdin Chemistry Co., Ltd.
In Fig. 5b and d, the polyester fibers were melted together and the fiber structure is hard to observe.
The fiber structures can be still seen in the Fig. 5c, which indicates that the calcium ion crosslinked coating has better ability to resist the shrinkage during combustion.
In Fig. 5b and d, the polyester fibers were melted together and the fiber structure is hard to observe.
The fiber structures can be still seen in the Fig. 5c, which indicates that the calcium ion crosslinked coating has better ability to resist the shrinkage during combustion.
Online since: August 2018
Authors: Kun Yan Wang
Morphology and Crystallization Behavior of PTT Blends with PTW
Kunyan Wang *
Department of Materials Chemistry, Huzhou University, Huzhou, 313000, China
wkyan01@163.com
Keywords: poly(trimethylene terephthalate), morphology, crystallization behavior
Abstract.
The crystalline structure of the blends was studied by X-ray diffraction.
Shih, Crystallization kinetics and structure of poly(trimethylene terepthalate)/monolayer nano-mica nanocomposites, Mater.
The crystalline structure of the blends was studied by X-ray diffraction.
Shih, Crystallization kinetics and structure of poly(trimethylene terepthalate)/monolayer nano-mica nanocomposites, Mater.
Online since: June 2012
Authors: Yong Xiang Zhao, B. Zhang
Zhang2,b
1Institute of Engineering Reliability and Safety, Traction Power State Key Laboratory, Southwest Jiaotong University, Chengdu 610031, China
2Metals and Chemistry Research Institute, China Academy of Railway Sciences, Beijing 100081, China
ayxzhao@home.swjtu.edu.cn; brailzhang@yahoo.com.cn
Keywords: Railway; Freight car; Roller bearing; Failure.
Checks verify that surface and core of the outer ring have lower hardness values than requirements; seldom micro-structures, i.e. black-white bands with thickness of around 0.6 to 1.3 mm, appear in the carburized layer of the bearing outer ring; the white part is needle like martensites with higher hardness values, while the black part is pearlites with lower hardness values; and more contingently, crack like manufacturing flaws may appear in the carburized layer with equiaxed grains of ferrites having lower hardness values are around the flaws.
Black-white band structure in carburized layer (×450) e.
However, in the metallurgical photograph checks, surface graph of outer ring raceway seems normally (Fig. 5a) but in the carburized layer, seldom micro-structures, i.e. black-white band with a thickness of around 0.6 to 1.3 mm, which were formed in manufacturing process, were exhibited (Fig. 5b-d).
Factors are that surface and core of the outer ring have lower values than the requirements; seldom micro-structures of black-white bands with thickness of around 0.6 to 1.3 mm appear in carburized layer of the bearing outer ring; the white part is needle like martensites with higher hardness values, while the black part is pearlites with lower hardness values; and more contingently, crack like manufacturing flaws may appear in the carburized layer in which equiaxed grains of ferrites with lower hardness values are around the flaws.
Checks verify that surface and core of the outer ring have lower hardness values than requirements; seldom micro-structures, i.e. black-white bands with thickness of around 0.6 to 1.3 mm, appear in the carburized layer of the bearing outer ring; the white part is needle like martensites with higher hardness values, while the black part is pearlites with lower hardness values; and more contingently, crack like manufacturing flaws may appear in the carburized layer with equiaxed grains of ferrites having lower hardness values are around the flaws.
Black-white band structure in carburized layer (×450) e.
However, in the metallurgical photograph checks, surface graph of outer ring raceway seems normally (Fig. 5a) but in the carburized layer, seldom micro-structures, i.e. black-white band with a thickness of around 0.6 to 1.3 mm, which were formed in manufacturing process, were exhibited (Fig. 5b-d).
Factors are that surface and core of the outer ring have lower values than the requirements; seldom micro-structures of black-white bands with thickness of around 0.6 to 1.3 mm appear in carburized layer of the bearing outer ring; the white part is needle like martensites with higher hardness values, while the black part is pearlites with lower hardness values; and more contingently, crack like manufacturing flaws may appear in the carburized layer in which equiaxed grains of ferrites with lower hardness values are around the flaws.
Online since: November 2011
Authors: Bin Yang, Neng Huang
In our study, a new type of Pt/C membrane electrodes, PtCuLaOx/C heterogeneous structure, in which with developing different flow of O2, on the surface of carbonaceous substrates were manufactured by Ion Beam Sputtering (IBS) technology.
In our study, we raised PtCuLaOx/C heterogeneous structure membrane electrodes, in which with developing different flow of O2, were manufactured by IBS.
(a) (b) Fig. 2 Cathodic LSV of PtCuLaOx/C heterogeneous structure membrane electrodes.
Conclusions By IBS technology, in which with different flow of O2, PtCuLaOx/C heterogeneous structure membrane catalytic electrodes could be manufactured.
Anniyev, et al.: Nature Chemistry. 2 (2010), p. 454
In our study, we raised PtCuLaOx/C heterogeneous structure membrane electrodes, in which with developing different flow of O2, were manufactured by IBS.
(a) (b) Fig. 2 Cathodic LSV of PtCuLaOx/C heterogeneous structure membrane electrodes.
Conclusions By IBS technology, in which with different flow of O2, PtCuLaOx/C heterogeneous structure membrane catalytic electrodes could be manufactured.
Anniyev, et al.: Nature Chemistry. 2 (2010), p. 454
Online since: August 2016
Authors: Sha Ren, Li Na Guo
Preparation and Luminescent Properties of Tb3+ Doped
Bi2WO6 Phosphor
Lina Guo1, a *, Sha Ren1, b
1College of Chemistry and Environmental Science, Inner Mongolia Normal University,
Hohhot 010022, China
a775735220@qq.com, bsr@imnu.edu.cn
Keywords: Bi2WO6: Tb3+, Green phosphor, Luminescence properties
Abstract.
The structure and composition of the samples were characterized by DTA-TG and XRD.
While the Tb3+ doped Bi2WO6 materials has not been reported, which can be effectively excited by visible light and has the stable crystal structure.
The structure and composition of the samples were characterized by DTA-TG, powder X-ray diffraction.
When the annealing temperature was higher than 550°C, the weight of the sample almost unchanged, which showed that the crystal structure of samples has been basically stable.
The structure and composition of the samples were characterized by DTA-TG and XRD.
While the Tb3+ doped Bi2WO6 materials has not been reported, which can be effectively excited by visible light and has the stable crystal structure.
The structure and composition of the samples were characterized by DTA-TG, powder X-ray diffraction.
When the annealing temperature was higher than 550°C, the weight of the sample almost unchanged, which showed that the crystal structure of samples has been basically stable.
Online since: October 2013
Authors: Zhou Xiang Yu, He Cheng, Dong Feng Chen, Yun Tao Liu, Li Zhang
Study on Calibrating Neutron Velocity Selector of Small Angle Neutron Scattering Instrument
Zhouxiang Yu1, a, Yuntao Liu1, b, He Cheng2, c, Li Zhang1, d, Dongfeng Chen1, e
1China Institute of Atomic Energy, P.O.Box 275-30, Beijing 102413, China
2Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
ayzx80@ciae.ac.cn, bytliu@ciae.ac.cn (corresponding author), cchenghe@iccas.ac.cn, dlzhang@ciae.ac.cn, edongfeng@ciae.ac.cn
Keywords: neutron velocity selector; small angle neutron scattering instrument; count loss rate; neutron time of flight
Abstract.
Based on small angle neutron scattering instrument (SANS) at China Advanced Research Reactor (CARR), instrument structure was designed and instrument parameters were determined.
Instrument structure and parameter setting For neutron velocity selector of SANS at CARR, wavelength range is 2.7 ~45Å and resolution rate range is 8 ~25% which satisfy the SANS demands for selectable wavelength range 2.7 ~20Å and selectable resolution rate range 10 ~22% [11].
Figure 1 (a) Calibration instrument structure (b) Front view of chopper Figure 2 Hardware flow chart of data acquisition system The desired time-of-flight spectrum is shown in Fig. 3.
Probing nanoscale structures-the sans toolbox [M].
Based on small angle neutron scattering instrument (SANS) at China Advanced Research Reactor (CARR), instrument structure was designed and instrument parameters were determined.
Instrument structure and parameter setting For neutron velocity selector of SANS at CARR, wavelength range is 2.7 ~45Å and resolution rate range is 8 ~25% which satisfy the SANS demands for selectable wavelength range 2.7 ~20Å and selectable resolution rate range 10 ~22% [11].
Figure 1 (a) Calibration instrument structure (b) Front view of chopper Figure 2 Hardware flow chart of data acquisition system The desired time-of-flight spectrum is shown in Fig. 3.
Probing nanoscale structures-the sans toolbox [M].
Online since: April 2007
Authors: Jeong Hwan Park, Ji Hwan Park, Gun Dae Lee, Seong Soo Park, Seong Soo Hong, Hong Chae Park
The samples prepared by conventional thermal
heating method mainly consist of irregular and small particles, whereas the samples prepared by micro-
wave heating method have elongated rope-like structure and their length extends longer than 10 µm.
Recently, microwave synthesis has been applied successfully for the synthesis of MCM-41 which is known as a promising material for applications like guest-host chemistry and organic/inorganic composite materials [2].
The technique to tailor the structure and morphology of ordered mesostructured inorganic materials is a vital factor in their use.
The XRD patterns of MCM-41 samples clearly show that a typical MCM-41 material with a relatively well ordered structure is synthesized by both the heating methods.
However, it is demonstrated in this work that the microwave heating induced the formation of fibrous MCM-41 structure only after 3 h of crystallization time.
Recently, microwave synthesis has been applied successfully for the synthesis of MCM-41 which is known as a promising material for applications like guest-host chemistry and organic/inorganic composite materials [2].
The technique to tailor the structure and morphology of ordered mesostructured inorganic materials is a vital factor in their use.
The XRD patterns of MCM-41 samples clearly show that a typical MCM-41 material with a relatively well ordered structure is synthesized by both the heating methods.
However, it is demonstrated in this work that the microwave heating induced the formation of fibrous MCM-41 structure only after 3 h of crystallization time.