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Methodology Properties of Materials used.
The specific gravity values of the above materials are listed in Table 1.
Properties of Materials S.
Materials Used Specific Gravity 1.
H. , “Workability, Testing, and Performance of Self-Consolidating Concrete”, Title No. 96-M43, ACI Materials Journal, V. 96, No. 3, May-June 1999 [5] Khayat, K.

Preparation and Thermoelectric Properties of Ca3Co4O9 Ceramics with Parallel Sheet Shaped Pores Huadong Wang1,a, Xudong Sun1,b, Xueyong Ding1,c, Mu Zhang1,d, Xiaodong Li1,e, Ji-Guang Li1,2,f, Di Huo1,g, Shaohong Liu1,h 1 Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education) adn School of Materials and Metallurgy, Northeastern University, Shenyang, Liaoning 110004, China 2Advanced Materials Processing Unit, National Institute for Materials Science, Sengen 1-2-1, Tsukuba, Ibaraki 305-0047, Japan awanghuadonglq@126.com, bxdsun@mail.neu.edu.cn, cDingxy@smm.neu.edu.cn, dacmzhang@gmail.com, elixd@atm.neu.edu.cn, flijg@smm.neu.edu.cn, ghuod@smm.neu.edu.cn, hliush@smm.neu.edu.cn Keywords: Ca3Co4O9, porous, sheet shaped pores, thermoelectric property Abstract.
Thermoelectric (TE) materials were considered as the best at converting waste heat to electricity.
With these regards, Co-based oxide materials with layered structures are possible candidates for TE materials[4-6].
Hence, researchers endeavored to find polycrystalline materials with high ZT value.
[4] Siwen Li, Ryoji Funahashi, Ichiro Matsubara, Kazuo Ueno, Hiroyuki Yamada, High temperature thermoelectric properties of oxide Ca9Co12O28, Journal of Materials Chemistry Communication, 9 (1999), 1659-1660 [5] J.G.

Experimental Materials.
Acknowledgements The work was financially supported by National Nature Science Foundation of China (NSFC: 20874074) and Zhejiang Provincial Natural Science Foundation of China (ZJNSF:Y506016).
[6] K.X.Li, X.F.Song and D.Zhang: Journal of Applied Polymer Science Vol.109(2008), p.1298
[7] X.F.Song,S.Z.Zhang and D.Zhang: Journal of Applied Polymer Science Vol.117(2010), p.3155
[9] Y.S.Ma, Q.H.Tang, D.Zhang: Advanced Materials Research Vols.233-235(2011), p.1073

Vibration Analysis on Ball End Milling Hardened Mould Assembled with Different Hardness Materials Y.Y.
Toh: Journal of Sound and Vibration, Vol.278 (2004), pp. 101-115
Sun et al: Journal of Advanced Manufacture Technology, Vol.46 (2010), pp.69-78
Aslan: Materials and Design, Vol.26 (2005), pp. 21-27
Gan: International Journal of Machine Tools and Manufacture, Vol.29 (1989), pp. 295-303

Materials and Methods Material Preparation: Clay Sample.
Adefila, Immobilization of cassava linamerase on kankara kaolinite clay, Journal of Natural Science Research 41 (2006) 1864-1874
Sayong clay material for biocatalyst immobilization, Material Science Forum, 737 (2013) 145-152
Pajares, Passivation of a montmorillonite by the silica created in acid activation, Journal of Material Chemistry 2 (9) (1992) 907-911
Rigi, Effect of acid activation on structural and bleaching properties of a bentonite, Iranian Journal of Materials Science & Engineering, 8 (4) (2011) 50-56

Rajurkar: Journal of Materials Processing Technology Vol.47 (1-2) (1994), p. 133 [4] J.D.
Muralidhar: Machine Science and Technology Vol.5 (2) (2001), p. 151 [10] A.C.
Weng: Journal of Materials Processing and Technology Vol. 507-509 (2007), p. 123 [11] R.K.
Jain: Journal of Materials Processing Technology Vol.152 (1) (2004), p. 17
Pai: Journal of Mechanical Science and Technology Vol. 21 (2007), p. 1593 [16] A.C.

At present it is obvious the surface sizes, structures, activities and the internal chemical and crystal composition of materials can be modified by a controlled mechanical activation process [16-23] Materials and experimental procedures Nowadays, ceramic items are normally produced with materials having submicron and nanoparticles [24-28].
Lapides: Journal of Materials Synthesis and Processing Vol. 8 (2000), p. 223
Nogrega: Journal of the Brazilian Chemical Society Vol. 16 (2005), p. 108
Valdre: Applied Clay Science Vol. 38 (2005), p. 233
Mondonico: Applied Clay Science Vol. 42 (2009), p. 398

More sustainable production of cement-based materials could enable CO2 emissions to be decreased.
Venkatesh, Effect of Stone Dust on Setting Time and Strength Characteristics of Cement Mortar, International Journal of Earth Sciences and Engineering, 9,3, ISSn:0974-5904, June 2016,1007-1011
[3] ACE Update and EPR, I-Tech media, Micro Fine Materials in Improving Concrete Performance, 2012
Fly Ash for The Sustainable Production of Air-CuredCementitiousMortars,http://www.mdpi.com/journal/materials,14,1208, https://doi.org/10.3390/ma14051208, 2021
Dwaraka, Behavior of Concrete with Granite Polishing Powder on Partial Replacement of Cement, International Journal of Engineering Science Invention Research & Development, V, II, AUGUST 2018, www.ijesird.com, E-ISSN: 2349-6185

The purpose of ice-bathing is to avoid the large sizes of particle formed when TiCl particles (20 to 50nm) were formed using CTAB and precipitation (Lee et al, 2008 dissolving TiCl4 in ethanol at a structure were then evaluated by Materials and Method Titanium tetrachloride TiCl4 (99%) Aldrich, were used as starting materials was cetyltrimethylammonium bromide (CTAB){CH Merck.
(99%), provided by Merck, and absolute ethanol were used as starting materials, without further purification.
Dye-sensitized solar cell: Journal of Photochemistry and Photobiology C, 2003, 4, 145 [5] Jinting Jiu et al.,.
Performance of dye-sensitized solar cell based on nanocrystals TiO2 film prepared with mixed template method: Solar Energy Materials and Solar Cells, 2005, 87, 77 [6] Jinting Jiu et al., Preparation of highly photocatalytic active nano-scale TiO2 by mixed template method: Materials Letters, 2004, 58, 3915 [7] I.Kartini et al., A novel route to the synthesis of mesoporous titania with full anatase nanocrystalline domains: Journal of Sol-Gel and Tech., 2004, 31, 185 [8] Kavan et al.,.
Mesoporous thin film TiO2 electrodes: Microp. and Mesoporous Material, 2001, 44-45, 653 [9] D.U.Lee et al.,.

Wang: Smart Materials and structures, vol.15(2006), p.
Wang: Smart Materials and structures, vol. 19 (2010), p. 065023
Smart materials & Structures, vol. 13(2004), p.1203-1210
Huang: Journal of Intelligent Material Systems and Structures, vol. 17(2006), p. 801-806
Guo: Journal of Intelligent Material Systems and Structures, vol. 17(2006), p. 871-881.