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Online since: June 2013
Authors: Gang Ren, Yao Ming Du, Yan Yu
Pore structure parameters of zeolite before and after modification
SBET
Smi
Se
SBJH
Vt
Vmi
V BJH
Wp
(m2.g-1)
(m2.g-1)
(m2.g-1)
(m2.g-1)
(mL.g-1)
(mL.g-1)
(mL.g-1)
(Å)
t-Plot
t-Plot
BJH
t-Plot
BJH
BET(4V/A)
natural zeolite
21.3252
2.3490
18.9762
23.1651
0.05435
0.000911
0.06755
101.9453
modified zeolite
21.9072
3.8559
18.0513
22.8694
0.09426
0.001607
0.10979
172.0987
BET model was adopted to describe the specific area(SBET), average pore size(Wp), total pore volume(Vt ).
As shown in Figure 3, chitosan was combined with zeolite and surface structure of graticule mesh was formed.
This organic-inorganic structure could provide weak polar circumstance and was favor to absorb bisphenol A which possesses weak polar too.
Mark Jr., Activated carbon: surface chemistry and Adsorption from Solution, Marcel Dekker, New York, 1971
As shown in Figure 3, chitosan was combined with zeolite and surface structure of graticule mesh was formed.
This organic-inorganic structure could provide weak polar circumstance and was favor to absorb bisphenol A which possesses weak polar too.
Mark Jr., Activated carbon: surface chemistry and Adsorption from Solution, Marcel Dekker, New York, 1971
Online since: May 2019
Authors: Naphat Albutt, Suejit Pechprasarn, Phitsini Suvarnaphaet, Wattapong Pinyo
Moreover, the structure of carbon nanodot (CND) can be passivated by oxygen, hydrogen and doped elements in order to be controllable the photoluminescence-color changing and for specific abilities [2].
The major structures are possibly analogous to either amorphous or nanocrystalline carbon nanoparticles comprising sp2-sp3 hybridized domains and functionalized oxygen, hydrogen and nitrogen based groups [16].
The existence of such passivated oxide groups on the carbon based structure during the carbonization of hydrocarbon were confirmed in FT-IR spectrum of R-CNDs as shown in Fig. 4.
Lei, Fluorescent carbon dots and their sensing applications, TrAC Trends in Analytical Chemistry 89 (2017) 163-180
The major structures are possibly analogous to either amorphous or nanocrystalline carbon nanoparticles comprising sp2-sp3 hybridized domains and functionalized oxygen, hydrogen and nitrogen based groups [16].
The existence of such passivated oxide groups on the carbon based structure during the carbonization of hydrocarbon were confirmed in FT-IR spectrum of R-CNDs as shown in Fig. 4.
Lei, Fluorescent carbon dots and their sensing applications, TrAC Trends in Analytical Chemistry 89 (2017) 163-180
Synthesis and Self-Assemble Behavior of Block Copolymerization of Vinyl Acetate and N-Vinylacetamide
Online since: January 2013
Authors: Ming Qing Chen, Wei Fu Dong, Yu Lou, Dong Jian Shi
Introduction
Block copolymers with well-defined structures can self-assembly into micelles, rods, vesicles, and so on.
To prepare the well-defined block copolymer structures, controlled/”living” radical polymerizations, such as nitroxide-mediated polymerizations (NMP)[1], atom transfer radical polymerization (ATRP)[2] and the reversible addition-fragmentation chain transfer (RAFT)[3], generally utilized in connection with suitable purification methods.
The structures and properties of PVAc-b-PNVA were characterized.
The Chemistry of Free Radical Polymerization, Pergamon.Oxford, (1995), p. 257
To prepare the well-defined block copolymer structures, controlled/”living” radical polymerizations, such as nitroxide-mediated polymerizations (NMP)[1], atom transfer radical polymerization (ATRP)[2] and the reversible addition-fragmentation chain transfer (RAFT)[3], generally utilized in connection with suitable purification methods.
The structures and properties of PVAc-b-PNVA were characterized.
The Chemistry of Free Radical Polymerization, Pergamon.Oxford, (1995), p. 257
Online since: March 2013
Authors: Jiang Cheng, Xiu Fang Wen, Pi Hui Pi, Zhuo Ru Yang, Andre Lee, Yang Lu
Processing Science of Isotactic Polypropylene Fiber reinforced with Halloysite Nanotubes Based on Masterbatch Dilution Technique
Yang Lu1, a, Andre Lee2, b, Xiufang Wen1, c, Pihui Pi1, d, Jiang Cheng1, e
and Zhuoru Yang1,f
1 College of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China
2 Department of Chemical Engineering & Materials Science, Michigan State University, East Lansing, United States
alu.lyang@mail.scut.edu.cn, bleea@egr.msu.edu, cxfwen@scut.edu.cn, dphpi@scut.edu.cn, ecejcheng@scut.edu.cn, fzhryang@scut.edu.cn
Keywords: Isotactic Polypropylene, Halloysite Nanotubes, Processing
Abstract.
Halloysite nanotubes, a type of minerals with needle structures, are classified as hydrated HNT with a crystalline structure of 10Å d-spacing ().
It can be concluded that the air cooling time has greater impact on the mechanical behavior of iPP0.8 compared to that of iPP because of the thermodynamically unstable and anisometric structure which needs more time for iPP0.8 to solidify, relax or lead to the decreasing disentanglement of short chains upon crystallization.
Halloysite nanotubes, a type of minerals with needle structures, are classified as hydrated HNT with a crystalline structure of 10Å d-spacing ().
It can be concluded that the air cooling time has greater impact on the mechanical behavior of iPP0.8 compared to that of iPP because of the thermodynamically unstable and anisometric structure which needs more time for iPP0.8 to solidify, relax or lead to the decreasing disentanglement of short chains upon crystallization.
Online since: November 2013
Authors: Mohamad Rusop, Saifollah Abdullah, A.Z. Zainurul, M.F. Achoi
Both exist in tetragonal structure.
The outside stability and the transition between different phases of TiO2 also change the shape, size, and crystal structure of TiO2 nanomaterials .
Reynders, Angle-Dependent Optical Effects Deriving from Submicron Structures of Films and Pigments, Chemical Reviews 99 (1999) 1963-1982
Lim, Low-temperature synthesis and microstructural control of titania nano-particles, Journal of Solid State Chemistry 177 (2004) 1372–1381
The outside stability and the transition between different phases of TiO2 also change the shape, size, and crystal structure of TiO2 nanomaterials .
Reynders, Angle-Dependent Optical Effects Deriving from Submicron Structures of Films and Pigments, Chemical Reviews 99 (1999) 1963-1982
Lim, Low-temperature synthesis and microstructural control of titania nano-particles, Journal of Solid State Chemistry 177 (2004) 1372–1381
Online since: August 2019
Authors: Svetoslav Isaakovich Volfson, Ildar N. Musin, Anton A. Nikiforov, Ilnur Z. Fayzullin
Influence of the Type of Wood Flour and Nano-Additives on Structure and Mechanical Properties of Wood-Polymer Composites Based on Polypropylene / I.Z.
Nikiforov // Mechanics, Resource and Diagnostics of Materials and Structures (MRDMS-2016) AIP Conf.
Influence of Nanofillers on the Structure of Wood-Polymer Composites / I.Z., Fayzullin, S.I.
Filippov // XX Mendeleev Congress on general and applied chemistry.
Nikiforov // Mechanics, Resource and Diagnostics of Materials and Structures (MRDMS-2016) AIP Conf.
Influence of Nanofillers on the Structure of Wood-Polymer Composites / I.Z., Fayzullin, S.I.
Filippov // XX Mendeleev Congress on general and applied chemistry.
Online since: January 2017
Authors: Zhao Hui Gong, Ya Xin Wang, Tong Sheng Xia
Particularly, graphene, a two-dimensional crystal with honeycomb lattice structure, discovered by Geim and Novoselov in 2004[1], has attracted a huge interest among the scientists for its special electronic properties[2] and excellent electrical, mechanical, thermal and optical properties[3].
They measured double carbon atomic chains and some doped structures for different length chains[19].
The perfect structure they adopt shows a perfect spin filter.
Wang: Physical Chemistry Chemical Physics, Vol.18 (2016), No.16
They measured double carbon atomic chains and some doped structures for different length chains[19].
The perfect structure they adopt shows a perfect spin filter.
Wang: Physical Chemistry Chemical Physics, Vol.18 (2016), No.16
Online since: September 2014
Authors: Kirill S. Kostikov, Valeriy M. Pogrebenkov, K.S. Kamyshnaya, Yu.P. Azhel
The muscovite, obtained from the Kuletskoye deposit schists, is characterized by more homogeneous breakup and better flake structure than the same from the Mamskoye deposit.
To investigate the grinding and thermal decomposition processes the muscovite from the Kuletskoye deposit having better structure and chemical purity was chosen.
The provided data, due to the mica flake and plate structure, differ from the data, obtained for brittle materials with a particle shape close to spherical.
In addition, the grinding of the muscovite was carried out in an industrial planetary mill having drums with a volume capacity of 2 liters at the Institute of Solid State Chemistry and Mechanochemistry (Novosibirsk).
To investigate the grinding and thermal decomposition processes the muscovite from the Kuletskoye deposit having better structure and chemical purity was chosen.
The provided data, due to the mica flake and plate structure, differ from the data, obtained for brittle materials with a particle shape close to spherical.
In addition, the grinding of the muscovite was carried out in an industrial planetary mill having drums with a volume capacity of 2 liters at the Institute of Solid State Chemistry and Mechanochemistry (Novosibirsk).
Online since: December 2023
Authors: Nur Ayuni Jamal, Farah Diana Mohd Daud, Norhuda Hidayah Nordin, Nur Hudawiyah Abu Hassan, Nor Akmal Fadil
Furthermore, the use of advanced analytical techniques including high-resolution transmission electron microscopy (HRTEM) and X-ray photoelectron spectroscopy (XPS), can provide significant insights into the surface chemistry and structure of the catalyst hence allowing the optimization of its properties and performance [5].
For example, their high surface area and complex surface structure can increase the number of active sites available for catalytic reactions, thus increasing the reaction rate.
The combination of unique crystal structure with severe lattice distortion, residual stress and stored plastic deformation energy of HEAs provided higher potential energy and active sites [12] which were responsible for excellent degradation capacity of HEAs powder toward an azo dye (methyl orange).
For example, their high surface area and complex surface structure can increase the number of active sites available for catalytic reactions, thus increasing the reaction rate.
The combination of unique crystal structure with severe lattice distortion, residual stress and stored plastic deformation energy of HEAs provided higher potential energy and active sites [12] which were responsible for excellent degradation capacity of HEAs powder toward an azo dye (methyl orange).
Online since: January 2016
Authors: Kristine Salma-Ancane, Dagnija Loca, Sintija Pastare, Liga Stipniece
Synthesis of strontium substituted hydroxyapatite through different precipitation routes
Liga Stipniece1,a, Kristine Salma-Ancane1,b, Dagnija Loca1,c, Sintija Pastare1,d
1Rudolfs Cimdins Riga Biomaterials Innovations and Development Centre of RTU, Institute of General Chemical Engineering, Faculty of Materials Science and Applied Chemistry, Riga Technical University, Pulka 3, Riga, LV-1007, Latvia
aliga.stipniece@rtu.lv, bkristine.salma-ancane@rtu.lv, cdagnija.loca@rtu.lv, dsintija.pastare@gmail.com
Keywords: hydroxyapatite, precipitation route, strontium ions, substitution
Abstract.
Substitution of various (Sr2+, Zn2+, Mg2+, Cu2+ etc.) cations in the Ca site of hydroxyapatite (HAp) crystal structure is accompanied by changes in the lattice parameters [1-4].
Molecular structure of the powders were studied using Fourier transformation infrared spectroscopy (FT-IR, Varian 800).
Rossi, The structure of strontium - doped hydroxyapatite: an experimental and theoretical study, Phys.
Substitution of various (Sr2+, Zn2+, Mg2+, Cu2+ etc.) cations in the Ca site of hydroxyapatite (HAp) crystal structure is accompanied by changes in the lattice parameters [1-4].
Molecular structure of the powders were studied using Fourier transformation infrared spectroscopy (FT-IR, Varian 800).
Rossi, The structure of strontium - doped hydroxyapatite: an experimental and theoretical study, Phys.