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Introduction Pulse electron beams are applied in development of radiation technologies (a rating of powerful gas lasers, formation of impulses of the microwave oven and x-ray radiation, plasma chemistry, purification of gases, sterilization of sewage, etc).
Modifications create certain requirements on conditions at which there is an interaction of a pulse electron beam to gas (pressure, temperature and structure of environment of interaction), and on a drift pipe (material of walls, geometrical sizes, diagnostics elements).
Advantages of a pulse plasmochemical method of synthesis of nanodimensional powders of oxides of metals: low specific energy consumption to 0.02 eV by molecule, potentially low prime cost of nanopowders, possibility to perform reactions at the room temperature and in one stage, universality of technology and the equipment for synthesing various oxides, high purity of the synthesized product - purity is limited only by purity of initial raw materials, synthesing ultrapure products (purity on a basic element of 99.99 – 99.99999%), a variation of parameters of synthesized product – the size (20-200 nanometers), a form of particles, chemical purity, phase structure (for TiO2 and composite powders), the high expected specific efficiency of the equipment (scores kg/h of a ready-made product, for trial installation) is possible [4].

A complementary approach is to develop homogeneous model systems, not only to gain understanding of the chromium-centred chemistry of the supported systems, but also to advance chromium olefin polymerization catalysis into an era of well-defined, single-site catalysts [1].
The substituents in ligands have a great influence on the structure and catalytic activity of complexes.
Effect of the electronic effect of fluoro substituents on the catalytic behavior It is well known that the coordination environment of ligands can significantly affect the catalytic behaviors of complexes, i.e., the catalyst activities and polymer properties can effectively be tuned by the ligand structures and properties.

Oxygen Reduction Electrode Properties of Oxide Nanosheet-based Materials Yuya Akeboshi1, Naotaka Ohno 1 , Hirohito Tokuno 1 , Morihiro Saito 1 , Jun Kuwano1 and Hidenobu Shiroishi2 1 Department of Industrial Chemistry, Faculty of Engineering, Tokyo University of Science, 12-1 Ichigayafunagawara-machi, Shinjuku-ku, Tokyo 162-0826, JAPAN 2 Department of Chemical Science and Engineering, Tokyo National College of Technology, 1220-2 Kunugida-machi, Hachioji-shi, Tokyo 193-0997, JAPAN Keywords: Oxide nanosheet, Oxygen reduction , 4-electoron reduction, Titanate, Electrocatalyst ABSTRACT Two types of oxide nanosheet-based materials, a H3O +-exchanged layered titanate and restacked titania nanosheets (H3O+-RE) were synthesized by soft chemical methods, and their oxygen reduction reaction (ORR) activities were examined by semi-steady-state voltammetry with a rotating ring-disc electrode at 70°C in 0.05 M H2SO4.
Crystal structure of Cs0.7Ti1.8250.175O4. possibility of designing unique advanced ORR catalysts that have been not yet developed so far.
The Cs+-RG and H3O +-RG were a single phase of the lepidocrocite-type structures (Fig. 1).

From a structure view of BF3-anisole, there are six electrons in the SP2 hybrid orbital for boron atom and the rest P orbital which is square across the three SP2 hybrid orbital is vacant, while the oxygen atom could supply line pair electrons and forms covalent bond with boron atom, stable structure of eight electrons which is similar to SP3 hybrid orbital is therefore generated.
GuiZhou：Guizhou People's Publishing House，1987，53-58 (In Chinese) [5] Guangqi Liu, Lianxiang Ma, Jie Liu Chemistry and Chemical Engineering data manul(organic)，Beijing：Chemical Industry Press，2002 (In Chinese)

The influence of mechanical disturbance of human activities, such as destroying forests, drying wetlands, stripping sod, and urban construction, on the permafrost degradation have been intensively investigate; but the effect of leachates from industrial waste on soil properties and its physical chemistry processes on permafrost degradation are often overlooked.
And the contaminants migration into the frozen soil leads to depression of freeing temperature, increase of unfrozen water content, and decrease of bearing capacity of frozen ground, and affect on the stability of structure.
If the freezing depth increases with the maximum thaw depth as the result of the salt contamination, the frost action on the structure would be enhanced.

As we know, the triglyceride structure of vegetable oils provides qualities desirable in a lubricant.
Thus, based on the XPS analysis in the present study, the NRO additive, in the molecules of which nitrogen was chemically bonded into the triglyceride structure of rapeseed oil, could also strongly adsorb onto the friction surfaces due to the long and polar molecular origin of rapeseed oil.
Green Chemistry, 2002, 12 (4): 293-307 [5] Willing A.

Their absorption and emission properties have been studied so as to get some structure-property relationship of such kind of system.
Structures and synthesis scheme of chromophores A-E Synthesis and characterizations.
Yu: Inorganic Chemistry Communications Vol. 13 (2010), p. 81 [11] D.F.

Sintering and Crystallization of Al2O3-La2O3-ZrO2 Eutectic Glass Gang He1,a, Jiaxi Liu1,2,b, Nan Lu1,2,c, Guanghua Liu1,2,d, Jiangtao Li1,2,e* 1Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China 2University of Chinese Academy of Sciences, Beijing 100049, China aipchg@mail.ipc.ac.cn, bliujiaxi@mail.ipc.ac.cn, clunan@mail.ipc.ac.cn, dliugh02@mail.ipc.ac.cn, elijiangtao@mail.ipc.ac.cn Keywords: Sintering, Crystallization, Eutectic glass, Hardness, Nanoceramics Abstract.
It is believed that the fracture toughness of the ceramic materials would benefit from that lamellar structure [17, 18].
Powder-less processing for nano-structured bulk ceramics:realization of Direct fabrication from solution and/or melts, J.

Thermal Stability and Morphology Analysis of Polymer Electrolyte Membranes Prepared from Cellulose Acetate-LiClO4 Tety Sudiarti1,a*, Deana Wahyuningrum2, Bunbun Bundjali2 and I Made Arcana2,b* 1Chemistry Department, State Islamic University Sunan Gunung Djati Bandung, Bandung, Indonesia 2Department of Chemistry, Faculty of Mathematics and Natural Sciences, Bandung Institute of Technology, Bandung, Indonesia as_tety70@yahoo.com, barcana@chem.itb.ac.id Keywords: cellulose acetate, lithium perchlorate, polymer electrolyte membrane, thermal stability, morphology analysis.
Morphology analysis of the polymer electrolyte membrane using the scanning electron microscopy (SEM) was very important to investigate the compatibility of the mixture [14], membrane micro porous structure which favors for the transmission of lithium ions [15].
This reaction would continue until the ends of the molecular chains reached or, due to structure or other factors, a limiting stage was reached to which may be the carbonization end point [19].

Summary In this study, the PAN and the TPU were used to prepare composite nanofibers films with different structures by using three different composite methods.
Considering most of current researches are focused on mixed spinning and there is no research on multilayer superposition spinning, our future work is to try to study the sandwich structure of superposition spinning method and explore the most appropriate superposition and sandwich mode.
Preparation of electrospun PA6/PET composite film and its air filtration performance, Environmental Chemistry, 2012,31(10):1575-1579