Paper Titles
Analysis of the Pressure and Shrinkage in the Mould for PLA and PLLA
p.128
Behavior of Recycled Polypropylene with Glass Fibers at Different Temperature and their Charpy Impact and Hardness Properties
p.136
The Effect of Adding Halloysite Nanotubes as Filler on the Mechanical Properties of Low-Density Polyethylene
p.144
Study of Mechanical Properties and Modeling of Flax Reinforced Composites
p.152
The Influence of the Static Electrical Field on the Phase Transformation II-I of the Isotactic Polybutene-1
p.160
Natural Aerobic Degradation of Polylactic Acid (Composites) with Natural Fiber Additives
p.167
The Limits of Vacuum Infusion Technology during the Production of Filled Polymer Composite Systems
p.175
Observation of Shape and Dimensional Accuracy Changing of Parts in Time Intervals Manufactured by Additive Method Fused Deposition Modeling
p.182
The Influence of Laser Beam Technological Parameters on the Polymethyl Methacrylate Surface Quality
p.190

The Influence of the Static Electrical Field on the Phase Transformation II-I of the Isotactic Polybutene-1

Article Preview

Abstract:

The spontaneous phase transformation of the unstable phase II to the stable phase I of isotactic polybutene-1 can be affected by several factors (temperature, pressure, mechanical deformation, environments, nucleation agents or presence of –CH2- groups in polymer chains or in blends). Here we study the effect of the external static electrical field on the iPB-1 structure and phase II →I transformation rate. The phase transition II to I is accelerated by the effect of the static electrical field up to 36%. This effect increases with increasing macromolecular chain length and increasing voltage. The electrical field did not substantially influence the total amount of crystalline phase. The phase transformation of neutral type changed into minus type. This change decreases the transformation rate by blocking the transformation nuclei.

You might also be interested in these eBooks
Novel Trends in Production Devices and Systems IV View Preview

Info:

Periodical:

Materials Science Forum (Volume 919)

Pages:

160-166

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.919.160

Citation:

Cite this paper

Online since:

April 2018

Authors:

Martina Kaszonyiová*, František Rybnikář, Milena Kubišová

Keywords:

Isotactic Polybutene-1, Phase Transformation, Structure

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2018 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

References

[1] NATTA, G. Une Nouvelle Classe de Polymeres d'α-Olefines ayant une Régularité de Structure Exceptionnelle. Journal of Polymer Science Part A: Polymer Chemistry. 1996, 34(3), 321-332. DOI: 10. 1002/pola. 1996. 810. ISSN 0887-624x.

DOI: 10.1002/pola.1996.810

Google Scholar

[2] ANDROSCH, René, Maria Laura DI LORENZO, Christoph SCHICK a Bernhard WUNDERLICH. Mesophases in polyethylene, polypropylene, and poly(1-butene). Polymer. 2010, 51(21), 4639-4662. DOI: 10. 1016/j. polymer. 2010. 07. 033. ISSN 00323861.

DOI: 10.1016/j.polymer.2010.07.033

Google Scholar

[3] KASZONYIOVA, M., F. RYBNIKAR a P. H. GEIL. Crystallization and Transformation of Polybutene‐1. Journal of Macromolecular Science, Part B. 2004, 43(5), 1095-1114. DOI: 10. 1081/MB-200033322. ISSN 0022-2348.

DOI: 10.1081/mb-200033322

Google Scholar

[4] KASZONYIOVA, M., F. RYBNIKAR a P. GEIL. Polymorphism of Isotactic Poly(Butene‐1). Journal of Macromolecular Science, Part B: Physics. 2005, 44(3), 377-396. DOI: 10. 1081/MB-200057353. ISSN 0022-2348.

DOI: 10.1081/mb-200057353

Google Scholar

[5] ALFONSO, G. C.; AZZURRI, F.; CASTELLANO, M. J. Therm. Anal. Calorim. 2001, Vol. 66, p.197–207.

Google Scholar

[6] YAMASHITA M AND TAKAHASHI T, The Effect of Side Chain Entropy on Polymer Crystal Surfaces-Surface Free Energies of Isotactic Polybutene-1 Tetragonal and Trigonal Crystals, KOBUNSHI RONBUNSHU, 2008, č. 65, s. 218-227.

DOI: 10.1295/koron.65.218

Google Scholar

[7] RUBIN, I. D. J. Polym. Sci. 1964, Vol. B2, p.747–749.

Google Scholar

[8] KASZONYIOVA, M., F. RYBNIKAR a P. H. GEIL, The three processes of phase II - I transformation of isotactic polybutene - 1, Journal of Macromolecular Science, Part B (in preparation).

DOI: 10.1080/00222348.2019.1578521

Google Scholar

[9] MARUYAMA, Masanori, Yusuke SAKAMOTO, Koji NOZAKI, Takashi YAMAMOTO, Hiroshi KAJIOKA, Akihiko TODA a Koji YAMADA. Kinetic study of the II–I phase transition of isotactic polybutene-1. Polymer. 2010, 51(23), 5532-5538. DOI: 10. 1016/j. polymer. 2010. 09. 066. ISSN 00323861.

DOI: 10.1016/j.polymer.2010.09.066

Google Scholar

[10] BOOR, J. a J. C. MITCHELL. Kinetics of crystallization and a crystal-crystal transition in poly-1-butene. Journal of Polymer Science Part A: General Papers. 1(1), 59-84. DOI: 10. 1002/pol. 1963. 100010106. ISSN 04492951.

DOI: 10.1002/pol.1963.100010106

Google Scholar

[11] GOHIL, R. M., M. J. MILES a J. PETERMANN. On the molecular mechanism of the crystal transformation (tetragonal-hexagonal) in polybutene-1. Journal of Macromolecular Science, Part B. 2006, 21(2), 189-201. DOI: 10. 1080/00222348208204934. ISSN 0022-2348.

DOI: 10.1080/00222348208204934

Google Scholar

[12] CHAU, K. W., Y. C. YANG a P. H. GEIL. Tetragonal → twinned hexagonal crystal phase transformation in polybutene-1. Journal of Materials Science. 1986, 21(9), 3002-3014. DOI: 10. 1007/BF00553329. ISSN 0022-2461.

DOI: 10.1007/bf00553329

Google Scholar

[13] DI LORENZO, Maria Laura, Maria Cristina RIGHETTI a Bernhard WUNDERLICH. Influence of Crystal Polymorphism on the Three-Phase Structure and on the Thermal Properties of Isotactic Poly(1-butene). Macromolecules. 2009, 42(23), 9312-9320. DOI: 10. 1021/ma901882g. ISSN 0024-9297.

DOI: 10.1021/ma901882g

Google Scholar

[14] MARIGO, Antonio, Carla MAREGA, Giuliano CECCHIN, Gianni COLLINA and Giuseppe FERRARA. Phase transition II → I in isotactic poly-1-butene: wide- and small-angle X-ray scattering measurements. European Polymer Journal. 2000, 36(1), 131-136. DOI: 10. 1016/S0014-3057(99)00043-9. ISSN 00143057.

DOI: 10.1016/s0014-3057(99)00043-9

Google Scholar

[15] KOPP, S., J. C. WITTMANN and B. LOTZ. Phase II to phase I crystal transformation in polybutene-1 single crystals: a reinvestigation. Journal of Materials Science. 1994, 29(23), 6159-6166. DOI: 10. 1007/BF00354556. ISSN 0022-2461.

DOI: 10.1007/bf00354556

Google Scholar

[16] POWERS J, HOFFMAN JD, WEEKS JJ, QUINN, FA, Crystallization kinetics and polymorphic transformations in polybutene-1, Journal of research of the National Bureau of Standarts, section A- Physics and Chemistry, 1965, č. A 69, s. 335.

DOI: 10.6028/jres.069a.034

Google Scholar

[17] ZHANG B, YANG DC, YAN S, Direct formation of form I poly(1-butene) single crystals from melt crystallization in ultrathin films, Journal of Polymer Science, Part B – Polymer Physiscs, 2002, č. 40, s. 2641-2645.

DOI: 10.1002/polb.10327

Google Scholar

[18] LU K., YANG D. AND DAHOUN A. Stabilization of metastable phase I of isotactic polybutene-1 by coated carbon. Polymer Bulletin. 2007, Vol. 58, pp.731-736.

DOI: 10.1007/s00289-006-0705-1

Google Scholar

[19] KALOUS J., BENICEK L, CERMAK R. Influence of high pressure on thermal behaviour of poly(1-butene) homopolymers,. Chemical papers. 2014, 108, pp.21-25.

Google Scholar

[20] NAKAFUKU, Chitoshi a Tsuyoshi MIYAKI. Effect of pressure on the melting and crystallization behaviour of isotactic polybutene-1. Polymer. 1983, 24(2), 141-148. DOI: 10. 1016/0032-3861(83)90124-6. ISSN 00323861.

DOI: 10.1016/0032-3861(83)90124-6

Google Scholar

[21] ARMENIADES, Constantine and Eric BAER. Effect of pressure on the polymorphism of melt crystallized polybutene-1. Journal of Macromolecular Science, Part B. 1967-8-1, 1(2), 309-334. DOI: 10. 1080/00222346708212781. ISSN 0022-2348.

DOI: 10.1080/00222346708212781

Google Scholar

[22] HRIBOVA M., RYBNIKAR F, JAKUBICEK J. The effect of some physical factors on the phase structure of isotatic polybutene-1, Materials Structure. 2015, 22(3), 21-25.

Google Scholar

[23] KASZONYIOVA M., RYBNIKAR F., LAPCIK L., MANAS D. Effects of Beta Irradiation, Copolymers, and Blends on the Transformation Rate of Polybutene-1. Journal of Macromolecular Science, Part B: Physics. 2012, č. 51, s. 926-945. DOI: 10. 1080/00222348. 2011. 610253.

DOI: 10.1080/00222348.2011.610253

Google Scholar

[24] HRIBOVA M., RYBNKAR F., MANAS D., The Effect of Electron Irradiation on Polybutene -1 and its Ethylene Copolymers, ACTA PHYSICA POLONICA A, 2012, č. 122, s. 569 – 571.

DOI: 10.12693/aphyspola.122.569

Google Scholar

[25] BUSFIELD W.K.; WATSON G.S. Free radical activity in gamma-irradiated polyethylene film, drawn tape and ultra-high-modulus fibres determined by grafting performance, Polymer International, 2005, 54, 1047–1054.

DOI: 10.1002/pi.1807

Google Scholar

[26] LEHRLE, R.S.; PATTENDEN C.S.; Gamma irradiation of a polyisobutylene rubber: effects on the molecular weight and the subsequent thermal stability, Polym. Degrad. Stabil. 1998, Vol. 62, p.211.

DOI: 10.1016/s0141-3910(97)00278-4

Google Scholar

[27] KASZONYIOVA, M., F. RYBNIKAR a P. H. GEIL, The environment influence on the phase II - I transformation of isotactic polybutene – 1, Journal of Macromolecular Science, Part B (in preparation).

DOI: 10.1080/00222348.2019.1574424

Google Scholar

[28] KASZONYIOVA M, RYBNIKAR F, GEIL PH, Structure and morphology of isotactic poly(butene-1) phase III, Journal of Macromolecular Science, Part B, 2006, č. 46, s. 195-205.

DOI: 10.1080/00222340601044391

Google Scholar

[29] HUMMEL R.E. (2001) Electrical Properties of Polymers, Ceramics, Dielectrics, and Amorphous Materials. In: Electronic Properties of Materials. Springer, Berlin, Heidelberg, s. 166-193. ISBN 9783642865404.

DOI: 10.1007/978-3-642-86538-1_9

Google Scholar

[30] ALEXANDER, Leroy E. X-ray diffraction methods in polymer science. New York: Wiley-Interscience, 1969. ISBN 04-710-2183-0.

Google Scholar