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Optical Activity of Deuterated Analog of L-Arginine Phosphate Single Crystals

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Abstract:

The complete optical gyration tensor of monoclinic pure L-arginine phosphate monohydrate (LAP) and deuterated LAP (d-LAP) crystals has been determined. Variation of the optical activity in the presence of birefringence of d-LAP crystal with pure LAP is found from the high-accuracy universal polarimeter (HAUP) method at a wavelength of 632.8 nm. The gyration tensor components in terms of rotatory power were found to be r11 = -6.6(3) º/mm, r22 = 19(2) º/mm; r33 = 49.7(7) º/mm; and r13 = -43.7(8) º/mm for the LAP, and r11 = -1.2(1) º/mm, r22 = 5.0(4) º/mm; r33 = 41.4(3) º/mm; and r13 = -38.0(4) º/mm for d-LAP at room temperature.

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Periodical:

Materials Science Forum (Volumes 480-481)

Pages:

43-52

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.480-481.43

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Online since:

March 2005

Authors:

J. Herreros-Cedrés, C. Hernández-Rodríguez, R. Guerrero-Lemus

Keywords:

Birefringence, D-LAP, HAUP, LAP, Optical Activity, Optical Anisotropy

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© 2005 Trans Tech Publications Ltd. All Rights Reserved

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