Papers by Author: Bai Mei Tan

Abstract: The effects of the polyamine chelating agent and nonions surfactant additive on the surface defectivity reduction in the final polishing of the mono silicon wafers were investigated using high-purity nano colloidal silica based organic alkaline slurry. Experimental results reveal that the chemical enhanced silicon final polishing slurry containing FA/O polyamine chelating agent and FA/O nonions surfactant changed the chemistry character of silicon surface, can realize the chemical uniform etch the surface areas with defects and defect-free area, deeply lower the surface microroughness of silicon polished wafer, achieving defect-free with perfect quality of flat mirror-surface.

Abstract: Indium antimony(InSb) is one of the important materials which can be used to make semiconductor devices such as infrared detection device. Due to the low hardness and great brittleness, the surface scratching always appears and surface roughness is hard to lower during surface preparation. So it should be increasing the InSb surface quality during ultra precision machining. In this paper the InSb surface adsorption-control technology was introduced. Through controlling surface roughness during chemical mechanical polishing(CMP) and using preferential adsorption during cleaning, the adsorptions of InSb surface were controlled. Through experiments, the CMP optimal process parameters under the alkaline conditions were gotten. Under such conditions, the preferable surface state was realized. According to the preferential adsorption model, through using FA/O non-ionic surfactant the polished wafer surface can be kept in physical adsorption and easy cleaning state, so the wafer surface adsorption can be controlled effectively and the clean surface was obtained.

Abstract: Chemical mechanical planarization (CMP) of Cu pattern wafer based alkaline Cu slurry in GLSI was investigated. The performance of Cu removal rate and dishing condition were discussed in this paper. Different formation of alkali CMP slurry (Cu1 and Cu2 slurry) were observed by removal rate experiments and showed that alkaline slurry provided a robust polishing performance on initial removal rate, which Cu1 and Cu2 slurry were higher than that of commercial acidity slurry, and in addition, alkaline slurry also have good ending removal rate both in Cu1 and Cu2 slurry and favorable dishing in Cu2 slurry. Furthermore, the result indicated that Cu alkaline slurry with a complexing agent of R(NH2)n, compared with commercial acidity slurry with a inhibitor of Benzotriazol (BTA), have better application foreground for 45nm nod and more advanced nodes.

Abstract: Along with the feature size reducing and the increase of integration level rapidly in ULSI，the request for metal impurities contamination on silicon substrate surface appears specially rigorous. In this paper the chelating agent was added in cleaning solution in order to removing copper ion. FA/O, a new kind of chelating agent was studied in RCA cleaning solutions, which has 13 chelating rings and is free of sodium, stable and easily soluble. The XPS and GFAAS measured results indicate that FA/O is more efficient than NH4OH as a ligand. Cu contaminations on silicon wafer can be removed remarkably when adding a little FA/O to the cleaning solution or polishing slurry. When the chelating agent concentration of cleaning solution is 0.1% the removal rate of Cu atom reaches 83 percent. The FA/O chelating agent substituting NH4OH in SC-1 may simplify cleaning steps, and one cleaning step can remove Cu pollution on silicon wafer surface and meet the requirements of microelectronics technology.

Abstract: Sapphire (α-Al2O3) single crystal, as an important photoconducting device substrate material, stringent surface quality requirements, i.e. surface finish and flatness, are required. The use of chemical mechanical polishing (CMP) technique can produce high quality surface finishes at low cost and with fast material removal rates. The polishing mechanism was studied in this paper, and it was pointed that there were chemical and mechanical kinetics process respectively. The chosen polishing temperature was 40 oC. SiO2 sol was chosen as abrasive and the particle size is 40nm. The pH value was determined at 11.5~12. During CMP process C6382I-W/YJ single side polisher and SUBA 600 pad were used. After polishing and cleaning of sapphire surface, the measured removal rate was above 183.3nm /min and the surface roughness by using AFM was lower than Ra 0.3 nm. From the results, it was found that using such method, the optimal sapphire surface can be gotten, which is advantaged for epitaxial growth and device making-up.

Abstract: In this paper, the chemical character of NiP substrate of computer disk is analyzed, the CMP kinetics processing is discussed to indicate that the chemical reaction is the slowest and the control process. By analyzing essentiality of slurry on NiP film CMP, it is indicated that the chemical component of slurry acts the important role in CMP. New type of alkali slurry for NiP substrate was prepared and its CMP mechanism is studied with alkali slurry. Strong complexation of complex agent improved selectivity of concave area and convex area to get higher removal rate. Low roughness is realized with small size and low hardness silica sol as abrasive.

Abstract: SiO2 is a kind of widely used dielectric material in ULSI and its chemical mechanical planarization (CMP) is one of the most difficult processes. In this paper, the CMP mechanism and the effect of abrasive on SiO2 dielectric were analyzed; the different factors of affecting the CMP were analyzed. A kind of organic alkali was chosen to act as the pH regulator and complexation agent to enhance the chemical effect. The silica sol was selected as abrasive to realize no contamination, low viscidity, proper hardness and easy to clean. The effect of different concentration of abrasive on the removal rate and surface performance were studied. Further more the influence of polishing slurry flow and surfactant on removal rate were analyzed. The final planarization was realized.