Effect of Nitrite Concentration and pH on Steel Corrosion Induced by Chloride in Simulated Concrete Pore Environment

Article Preview

Abstract:

The influence of nitrite concentration on the corrosion of steel immersed in three simulated pH environments that really exist on the surface of steel in concrete has been investigated by comparing and analyzing the change of threshold level of Cl- and NO2-/Cl- mole ratio. The results indicate that with the presence of nitrite, the corrosion of steel can be inhibited effectively. Chloride threshold level increases with the increasing of nitrite concentration and highly alkaline environment plays an important role in assisting nitrite to inhibit corrosion. The use of NO2-/Cl- mole ratio as the parameter to guarantee the inhibition efficiency is suitable in highly alkaline environment, but not appropriate in weakly alkaline and neutral environments.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

314-318

Citation:

Online since:

August 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] K.K. Sideris, A.E. Sawa. Cement and Concrete Composites, 27(2005) 277-287.

Google Scholar

[2] K.Y. Ann, N.R. Buenfeld. Magazine of Concrete Research, 59 (9) (2007) 689-697.

Google Scholar

[3] C.Alonso, C.Andrade. ACI Materials Journal, 87 (2) (1990) 130-137.

Google Scholar

[4] V.T. Ngala, M.M. Page. Corrosion Science 44 (2002) 2073-2087.

Google Scholar

[5] P.Montes, T.W. Bremner, D.H. Lister. Cement and Concrete Composites, 26(2004) 243-253.

Google Scholar

[6] I.L. Kondratova, P.Montes, T.W. Bremner. Cement and Concrete Composites 25 (2003) 483-490.

DOI: 10.1016/s0958-9465(02)00088-4

Google Scholar

[7] M.B. Valcarce, M.Vazquez. Electrochimica Acta 53 (2008) 5007-5015.

Google Scholar

[8] L.Mammoliti, C.M. Hansson, B.B. Hope. Cement and Concrete Research 29 (1999) 1583-1589.

DOI: 10.1016/s0008-8846(99)00137-4

Google Scholar

[9] M.B. Valcarce, M.Vazquez. Materials Chemistry and Physics 115 (2009) 313-321.

Google Scholar

[10] M.Reffass, R.Sabot, M.Jeannin et al. Electrochemica Acta 52 (2007) 7599-7606.

Google Scholar

[11] P.Garces, P.Saura, A.Mendez et al. Corrosion Science 50 (2008) 498-509.

Google Scholar

[12] M.J. Pryor. Journal of the Electrochemical Society 106 (7) (1959) 557-562.

Google Scholar

[13] H.J. Engell. Electrochemica Acta 22 (9) (1977) 987-993.

Google Scholar