For Libraries For Publication Open Access Downloads About Us Contact Us
Paper Titles
Experimental Study on the Crack Consequences of Shale Ceramsite Concrete Aggregate
p.3920
Application of Prepacked Aggregate Concrete Technology in Gravity Wharf Reinforcement
p.3926
Study on Structure and Performance of PTFE/YSZ Composite Microporous Membrane
p.3930
Research of Mechanical Properties of Asphalt Pavement Materials with WMA and RAP
p.3934
Preparation of Polyurethane-Poly(butyl acrylate) Hybrid Latexes via Miniemulsion Polymerization
p.3938
Orthogonal Experiment and Analysis of the Concrete which Use the Shell as Aggregate
p.3942
Experimental Research on the Change Rule of Frequency of Shale Ceramsite Reinforced Concrete Beam with Damage
p.3946
Synthesis and Characterization of SrSiO3 by Chemical Deposition Method
p.3952
Frost Resistance of Steel Fiber Reinforced Micro-Expansive Concrete Filled Steel Tube
p.3956

Preparation of Polyurethane-Poly(butyl acrylate) Hybrid Latexes via Miniemulsion Polymerization

Article Preview

Abstract:

Polyurethane prepolymer capped by vinyl group (PUV) was synthesized by reaction of hydroxyethyl methacrylate and toluene diisocyanate using di-n-butyltin dilaurate as catalyst, and then polyurethane-poly(butyl acrylate) hybrid latexes were prepared via miniemulsion polymerization of PUV and butyl acrylate (BA). Fourier transform infrared, differential scanning calorimeter were adapted to characterize the structure of PUV and PU-PBA and the properties of their films. The results show that the decrease of BA/PUV ratio result in an increase of the hardness and glass transition (Tg) of PU-PBA, but reduce the stability of miniemulsion and elasticity of final copolymer films.

You might also be interested in these eBooks
Progress in Industrial and Civil Engineering View Preview

Info:

Periodical:

Applied Mechanics and Materials (Volumes 204-208)

Pages:

3938-3941

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.204-208.3938

Citation:

Cite this paper

Online since:

October 2012

Authors:

Shi Jie Wang, Yu Li Wang, Peng Fei Yang, Tian Duo Li

Keywords:

Hybrid Latexes, Miniemulsion Polymerization, Poly(butyl acrylate), Polyurethane (PU)

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

References

[1] J.F. Zhang, X.F. Li, X.H. Shi, M. Hua, X.P. Zhou, X.Q. Wang: Progress in Natural Science: Materials International Vol. 22 (2012), p.71.

Google Scholar

[2] M. Barrere, K. Landfester, Macromolecules Vol. 36 (2003), p.5119.

Google Scholar

[3] C.P. Wang, F.X. Chu, L.W Jin, M.T. Lin, Y.Z. Xu, A. Guyot, Polymers Advanced Technologies Vol. 20 (2009), p.319.

Google Scholar

[4] D. Kukanja, J. Golob, A. Zupancic-Valan, M. Krajnc, Journal of Applied Polymer Science Vol. 78 (2000), p.67.

Google Scholar

[5] C.R. Hegedus, K.A. Kloiber, J. Coat. Technol. Vol. 68 (1996), p.39.

Google Scholar

[6] S.L. Chai, M.M. Jin, Journal of Applied Polymer Science Vol. 114 (2009), p.2030.

Google Scholar

[7] M. Hirose, J. Zhou, N. Katsutoshi, Progress in Organic Coatings Vol. 38 (2000), p.27.

Google Scholar

[8] K. Landfester, N. Bechthold, F. Tiarks, M. antonietti, Macromolecules Vol. 32 (1999), p.5222

DOI: 10.1021/ma990299+

Google Scholar

[9] K.A. Pigott, B.F. Frye, K.R. Allen, S. Steingiser, W.C. Darr, J.H. Saunders, J. Chem. Eng. Data Vol. 5 (1960), p.391.

Google Scholar

© 2025 Trans Tech Publications Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies. For open access content, terms of the Creative Commons licensing CC-BY are applied.
Scientific.Net is a registered trademark of Trans Tech Publications Ltd.