Study on the Corrosion Resistance of ZrN Films on the Aluminium Alloys Surface

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Abstract:

Aluminum alloy have the active chemical properties,low standard electrode potential, and the surface will be easily forming about 1-3nm oxide film in dry air, therefore aluminum alloy have the poor corrosion resistance.ZrN film deposited by mid frequency reactive magnetron sputtering process on aluminium alloy surface in order to improve the corrosion performance. Study the influences of nitrogen flow rate, sputtering time and temperature to the corrosion performance. The results show that: The corrosion performance of ZrN films will be improved with the nitrogen flow rate increase,but when the nitrogen flow rate was more than 18sccm, ZrN film corrosion resistance will be reduce;The corrosion performance improved with the sputtering time increase,when the time reach 15min, ZrN film corrosion resistance was no longer increase;The corrosion performance improved with the temperature, when the temperature reach 130°C, the corrosion resistance was no longer increase.The best process parameters was: nitrogen flow rate 18sccm, sputtering time 15min, temperature 130°C.

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245-249

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December 2012

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] Wang Qiwei. Antiwear and Anticorrosion Behaviors of Magnetron Sputtered (TixAly)N Film on 6063 aluminum alloy [J]. MaterialsProtection, 2009, 42(01): 59-77.

Google Scholar

[2] AltunH, Sen S. The effect ofDC magnetron sputtering AlN coatings on the corrosion behaviourofmagnesium alloys[J]. Surface& CoatingsTechnology, 2005, 197: 193~200.

DOI: 10.1016/j.surfcoat.2004.06.001

Google Scholar

[3] Farkas,N. The role of subsurface oxygen in the local oxidation of zirconium and zirconium nitride thin films. Thin Solid Films, v 447-448, 30 Jan. 2004: 468~473.

DOI: 10.1016/s0040-6090(03)01252-5

Google Scholar

[4] Zhang. High temperature erosion resistant property of ZrN. Cailiao Gongcheng/Journal of Materials Engineering, 1998(7): 27~29.

Google Scholar

[5] Wen-Jun Chou Corrosion resistance of ZrN films on AISI 304stainless steel substrate. Surface&Coatings Technology, v 167, n 1, 1 April 2003: 59~67.

DOI: 10.1016/s0257-8972(02)00882-4

Google Scholar

[6] FloresM, BlancoO, MuhlS, et a. l Corrosion of a Zn-Al-Cu alloy coated with TiN/Ti films [ J]. Surface and Coatings Technology, 1998, 108~109: 449~453.

DOI: 10.1016/s0257-8972(98)00639-2

Google Scholar

[7] Del Re. Study of the moisture and thermal resistance of AlN/ZrN/AlNmultilayers coating. Surface and CoatingsTechnology, v200, n 1-4 SPEC. ISS., Oct 1, 2005: 94~99.

DOI: 10.1016/j.surfcoat.2005.02.155

Google Scholar

[8] Musil,J. Magnetron sputtering of hard nanocomposite coatingsand their properties. Surface & Coatings Technology, v 142-144, July, 2001: 557~566.

DOI: 10.1016/s0257-8972(01)01139-2

Google Scholar

[9] Aouadi, S M. Correlation between interfacial electronic structureand mechanical properties of ZrN-Me (Me=Ag, Au, or Pd)nanocomposite films. Applied Physics Letters, v 87, n 4, 25 Ju-ly, 2005: 41902~1~3.

DOI: 10.1063/1.2001141

Google Scholar

[10] YinRenhe,N. Taniguehi,Y. Hayashi. On the Corrosion Resistanee of SUS304BA Sputtered With Metal Oxide Films[J]. JOURNAL OF CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY, 1994, 24(01): 252-256.

Google Scholar