Efficient Production of Biodiesel from Rapeseed Oil Deodorizer Distillate: One-Pot Esterification and Transesterfication with Compound Lipases

Article Preview

Abstract:

A novel concept and efficient method for producing biodiesel from rapeseed oil deodorizer distillate (RODD) was developed by using compound lipases for one-pot esterification of FFA and transesterification of triglyceride with methanol in a solvent-free system. Compound lipases Novozyme435 and immobilized Pseudomonas cepacia G63 at 1:1(wt/wt) gave FAME about 96% yield under optimal conditions, being better than that with single lipase or other compound lipases. Besides, the loss rate of vitamin E was 18% much lower than that of using chemical catalyst, which shows that the compound lipases Novozyme435 and immobilized P. cepacia G63 can be ideal catalysts for biodiesel production from rapeseed oil deodorizer distillate.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

267-275

Citation:

Online since:

February 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] M. Dumont, S. S. Narine: Food Res. Int. Vol. 40 (2007), p.957.

Google Scholar

[2] L.C. Meher, D. Vidya Sagar and S.N. Naik: Renew. Sust. Energ. Rev. Vol. 10 (2006), p.248.

Google Scholar

[3] A. Bajaj, P. Lohan, P.N. Jha and R. Mehrotra: J. Mol. Catal. B-Enzym. Vol. 62 (2010), p.9.

Google Scholar

[4] A. emirbas: Energ. Convers. Manage. Vol. 50 (2009), p.14.

Google Scholar

[5] A. Robles-Mwdina, P.A. Gonzalez-Moreno, L. Esteban-Cerdan and E. molina-Grima: Biotechnol. Adv. Vol. 27 (2009), p.398.

Google Scholar

[6] M.G. Kulkarni, A.K. Dalai: Ind. Eng. Chem. Res. Vol. 45 (2006), p.2901.

Google Scholar

[7] M. Canakci: Bioresource Technol. Vol. 98 (2007), p.183.

Google Scholar

[8] M. Kima, C.D. Maggio, S. Yan, H. Wang and S.O. Salley: Bioresource Technol. Vol. 102 (2011), p.2380.

Google Scholar

[9] G.K. Nagesha, B. Manohar and K. Udaya Sankar: J. Supercrit. Fluid Vol. 32 (2004), p.137.

Google Scholar

[10] N.A. Zafiropoulos, H.L. Ngo, T.A. Foglia, E.T. Samulski and W. Lin: Chem. Commun. Vol. 35 (2007), p.3670.

Google Scholar

[11] L. Wang, W. Du, D.H. Liu, L.L. Li and N.M. Dai: J. MOL. CATAL. B-Enzym. Vol. 43(2006), p.29.

Google Scholar

[12] T. Czuppon, Z. Kemeny, E. Kovari and K. Recseg, W.O. Patent 2, 004, 000, 979. (2003).

Google Scholar

[13] C.F. Torres, G. Torrelo, F.J. Senorans and G. Reglero: Process Biochem. Vol. 42 (2007), p.1335.

Google Scholar

[14] T. Fang, M. Goto, X . Wang, X.L. Ding, J.G. Geng, M. Sasaki and T. Hirose: J. Supercrist. Fluid Vol. 40 (2007), p.50.

Google Scholar

[15] P.F. Martins, V.M. Ito, C.B. Batistella and M.R.W. Maciel: Sep. Purif. Technol. Vol. 48 (2006), p.78.

Google Scholar

[16] W. Panpipat, X. Xu and Z . Guo: Process Biochem. Vol. 47 (2012), p.1256.

Google Scholar

[17] J.Y. Yan, A. T Li, Y. Xu, T.P.N. Ngo, S.C. Phua and Z. Li: Bioresource Technol. Vol. 123 (2012), p.332.

Google Scholar

[18] S. Arai, K. Nakashima, T. Tanino, C. Ogino, A. Kondo and H. Fukuda: Enzyme Microb. Tech. Vol. 46 (2010), p.51.

Google Scholar

[19] M. Canakci, J. Van and Gerpen: T. Asabe. Vol. 46 (2003), p.945.

Google Scholar

[20] E. Lotero, Y. Liu, D.E. Lopez, K. Suwannakarn, D.A. Bruce and J.G. Goodwin Jr: Ind. Eng. Chem. Res Vol. 44 (2005), p.5353.

DOI: 10.1021/ie049157g

Google Scholar

[21] Y. Xu, X. Shi, X. Du, M. Xing, T. Xu, J. Meng and Z. Feng: C.N. Patent ZL 10, 114, 851.X. (2005).

Google Scholar

[22] J. Meng, X.M. Shi, B. Wei, Y.L. Xu and J. Meng: China Oil Vol. 29 (2004), p.32. In Chinese.

Google Scholar

[23] H. Fukuda, A. Kondo and H. Noda: J. Biosci. Bioeng. Vol. 92 (2001), p.405.

Google Scholar

[24] H. Fukuda, S. Hama, S. Tamalampudi and H. Noda: Trends. Biotechnol. Vol. 26 (2008), p.668.

Google Scholar

[25] Y. Shimada, Y. Watanabe, T. Samukawa, A. Sugihara, H. Noda and H. Fukuda: Jam. Oil. Chem. Soc. Vol. 76 (1999), p.789.

Google Scholar

[26] Tang N C. Enzymatic Methylesterification and Purification of VE fron Soybean Oil Deodorizer Distillate [D]. Jiangnan University, 2008. In Chinese.

Google Scholar

[27] Q. Li, J. Zheng and Y. Yan: Fuel Process Technol. Vol. 91 (2010), p.1229.

Google Scholar

[28] Y. Liu, Y. Yan and F. Hu: Aiche. Journal Vol. 56 (2010), p.1659.

Google Scholar

[29] T. Liu, Y. Liu, X. Wang, Q. Li, J. Wang and Y. Yan: J. Mol. Catal. B-Enzym. Vol. 71 (2011), p.45.

Google Scholar

[30] Y. Liu, L. Wang: Chemical Engineering and Proce. Vol. 48 (2009), p.1152.

Google Scholar

[31] M. Igarashi, T. Tsuzuki, T. Kambe and T. Miyazawa: J. Nutr. Sci. Vitaminol. Vol. 50 (2004), p.121.

Google Scholar