Green Biodiesel Production Catalyzed by Basic Ionic Liquid

Article Preview

Abstract:

Transesterification were carried out under microwave irradiation conditions and the effects of imidazolium hydroxide with different branched alkyl side-chains ([Cnmim]OH, n = 2, 3, 4) were investigated. The results showed that less than conventional amount of NaOH, and the alkaline ionic liquids formed clearly biphasic systems immediately after the transesterification of soybean oil with methanol was finished. The method offers significant improvement over conventional techniques in terms of operational simplicity, processing time reduction and excellent yields. Among the imidazolium salts studied, [C2mim]OH proved to be the most efficient catalyst, affording 96 % yield.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

379-382

Citation:

Online since:

February 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] S. Sivaprakasam and C.G. Saravanan: Energ. Fuel Vol. 21 (2007), p.2998.

Google Scholar

[2] M.G. Kulkarni, R. Gopinath, L.C. Meher and A.K. Dalai: Green Chem. Vol. 8 (2006), p.1056.

Google Scholar

[3] S.F.A. Halim, A.H. Kamaruddin and W.J. N Fernando: Bioresource Technol. Vol. 100 (2009), p.710.

Google Scholar

[4] N.S. Kasim, T.H. Tsai, S. Gunawan and Y.H. Ju: Bioresource Technol. Vol. 100 (2009), p.2399.

Google Scholar

[5] X.Z. Liang, G.Z. Gong, H.H. Wu and J.G. Yang: Fuel Vol. 88 (2009), p.613.

Google Scholar

[6] N. Azcan and A. Danisman: Fuel Vol. 86 (2007), p.2639.

Google Scholar

[7] B.C. Ranu and S. Banerjee: Org. Lett. Vol. 7 (2005), p.3049.

Google Scholar