Emulsification of Bio-Oil Heavy Fraction with Diesel by Mechanical and Ultrasonic Technologies

Article Preview

Abstract:

In the present work, the emulsion fuels from bio-oil heavy fraction and 0# diesel were prepared by mechanical and ultrasound emulsification technologies. The relationship between stable time of emulsions and HLB value of emulsifier was investigated. Results indicated that lower mechanical stirring speeds and lower ultrasonic amplitudes lead to longer stable time of bio-oil heavy fraction emulsions. The stable time of emulsions reduced as HLB values increasing, and it reached a maximal value of 14 minutes under a HLB value of 1.8. Zetasizer Nano S90 was adopted to measure the droplet distribution of emulsions. The major droplet size of emulsions was smaller than 90nm. Meanwhile, the droplet distribution curve of ultrasound emulsions was much complex than those of mechanical emulsions.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

1133-1137

Citation:

Online since:

April 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] S. Sensoz and I. Kaynar, Bio-oil production from soybean (Glycine max L.): fuel properties of Bio-oil. Industrial Crops and Products. 23(2006) 99-105.

DOI: 10.1016/j.indcrop.2005.04.005

Google Scholar

[2] Q. Lu, X.F. Zhu, Q.X. Li, Q.X. Guo and Q.S. Zhu, Biomass fast pyrolysis for liquid fuels, Progress in Chemistry. 19(2007) 1064-1071.

Google Scholar

[3] S. Czernik and A.V. Bridgwater, Overview of applications of biomass fast pyrolysis oil, Energy & Fuels. 18(2004) 590-598.

DOI: 10.1021/ef034067u

Google Scholar

[4] X.J. Guo, S.R. Wang, Q. Wang, Z.G. Guo and Z.Y. Luo, Properties of bio-oil from fast pyrolysis of rice husk, Chinese Journal of Chemical Engineering. 19(2011) 116–121.

DOI: 10.1016/s1004-9541(09)60186-5

Google Scholar

[5] D.C. Elliott, Historical developments in hydroprocessing bio-oils, Energy & Fuels. 21(2007) 1792-1815.

DOI: 10.1021/ef070044u

Google Scholar

[6] D.C. Elliott, T.R. Hart, G.G. Neuenschwander, L.J. Rotness and A.H. Zacher, Catalytic hydroprocessing of biomass fast pyrolysis bio-oil to produce hydrocarbon products, Environmental Progress & Sustainable Energy. 28(2009) 441-449.

DOI: 10.1002/ep.10384

Google Scholar

[7] J. Wildschut, J. Arentz, C.B. Rasrendra, R.H. Venderbosch and H.J. Heeres, Catalytic hydrotreatment of fast pyrolysis oil: model studies on reaction pathways for the carbohydrate fraction, Environmental Progress & Sustainable Energy. 28(2009) 450-460.

DOI: 10.1002/ep.10390

Google Scholar

[8] I. Graca, F.R. Ribeiro, H.S. Cerqueira, Y. L. Lam and M.B. Almeida, Catalytic cracking of mixtures of model bio-oil compounds and gasoil, Applied Catalysis B-Environmental. 90(2009) 556-563.

DOI: 10.1016/j.apcatb.2009.04.010

Google Scholar

[9] S.R. Wang, Z.G. Guo, Q.J. Cai and L. Guo, Catalytic conversion of carboxylic acids in bio-oil for liquid hydrocarbons production, Biomass and Bioenergy. 45(2012) 138-143.

DOI: 10.1016/j.biombioe.2012.05.023

Google Scholar

[10] J.D. Adjaye and N.N. Bakhshi, Production of hydrocarbons by catalytic upgrading of a fast pyrolysis bio-oil: 1. conversion over various catalysts, Fuel Processing Technology. 45(1995) 161-183.

DOI: 10.1016/0378-3820(95)00034-5

Google Scholar

[11] Y. Tang, W.J. Yu, Y. Mo, H. Lou and X.M. Zheng, One-step hydrogenation-esterification of aldehyde and acid to ester over bifunctional Pt catalysts: A model reaction as novel route for catalytic upgrading of fast pyrolysis bio-oil, Energy & Fuels. 22(2008) 3484-3488.

DOI: 10.1021/ef800148q

Google Scholar

[12] Z.G. Guo, Q.Q. Yin and S.R. Wang, Bio-oil emulsion fuels production using power ultrasound, Advanced Materials Research. 3(2012) 2709-2712.

DOI: 10.4028/www.scientific.net/amr.347-353.2709

Google Scholar

[13] J. Yu, Y. Peng, Z. Li, W. Yi and X. Bai, Stability of emulsion from bio-oil and diesel, Journal of Shandong University of Technology (Natural Science Edition). 21(2007) 101-103.

Google Scholar

[14] M. Ikura, M. Stanciulescu and E. Hogan, Emulsification of pyrolysis derived bio-oil in diesel fuel, Biomass & Bioenergy. 24(2003) 221-232.

DOI: 10.1016/s0961-9534(02)00131-9

Google Scholar

[15] Q. Wang, X.B. Li, S.R. Wang, Z.Y. Luo and K.F. Cen, Experimental research on emulsions from biomass pyrolysis liquid and diesel, Acta Energiae Solaris Sinica. 31(2010) 380-384.

Google Scholar

[16] Z.G. Guo, S.R. Wang, Y.L. Gu, G.H. Xu, X. Li and Z.Y. Luo, Separation characteristics of biomass pyrolysis oil in molecular distillation, Separation and Purification Technology. 76(2010) 52-57.

DOI: 10.1016/j.seppur.2010.09.019

Google Scholar

[17] S. R. Wang, Y.L. Gu, Q. Liu, Y. Yao, Z.G. Guo, Z.Y. Luo, and K.F. Cen, Separation of bio-oil by molecular distillation, Fuel Processing Technology. 90(2009) 738-745.

DOI: 10.1016/j.fuproc.2009.02.005

Google Scholar

[18] Z.G. Guo, S.R. Wang, Y.Y. Zhug, Z.Y. Luo and K.F. Cen, Separation of acid compounds for refining biomass pyrolysis oil, Journal of Fuel Chemistry and Technology. 37(2009) 49-52.

DOI: 10.1016/s1872-5813(09)60010-4

Google Scholar