XPS Analysis of Carbon and Oxygen in Coking Coal with Different Density Intervals

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Study on the occurrence state of carbon and oxygen in the coking coal has a certain guiding meaning to make the most use of coking coal. Divide coal samples into different density level by float-sink experiments, and then use XPS to investigate the types and content of carbon and oxygen. The XPS spectrum of raw coal shows that the elements of raw coal are mainly consists of carbon and oxygen, a little of sulfur and silicon. The fitting map indicates that the content of carbon decrease with the increasing density; oxygen is just the opposite. C-C and C-H are the main forms of carbon; Oxygen exists in the forms of C-O or C=O and-OH.

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1239-1243

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August 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] HUANG Wen-hui, YANG Qi, TANG Xiu-yi, et al. Distribution features of coal for coking resource in China and deep part potential analysis [J]. Coal Geology of China. 2010, 22(5): 01-06.

Google Scholar

[2] Yu Ji-shun. Coal chemistry [M]. Beijing: metallurgy industry press, (2005).

Google Scholar

[3] Yu Hong-Kun, X-ray photoelectron spectroscopy (XPS) [J]. Shanghai Measurement and Testing, 2003, 30(4): 45-47.

Google Scholar

[4] David C. Frost, W. Ross Leedert, Robert L. An XPS study of the oxidation of pyrite and pyrites in coal[J] Fuel, 1970, 49, 126.

Google Scholar

[5] LIU Fen-rong, LI Wen, GUO Hui-qing, et al. XPS study on the change of carbon-containing groups and sulfur transformation on coal surface[J] Journal o f Fuel Chemistry and Technology. 2011, 39(02): 0081-0084.

DOI: 10.1016/s1872-5813(11)60011-x

Google Scholar

[6] DUAN Xu-qin, WANG Zu-ne. XPS analysis of oxygen contained functional group in coal macerals [J] Journal of Liaoning Technical University(Natural Science). 2010, 29(03): 0498-0504.

Google Scholar

[7] T. Grzybek, R. Pietrzak, H. Wachowska, The comparison of oxygen and sulphur species formed by coal oxidation with O2/Na2CO3 or peroxyacetic solution. XPS studies, Energy Fuels 18 (2004) 804–809.

DOI: 10.1021/ef030153i

Google Scholar

[8] T. Grzybek, R. Pietrzak, H. Wachowska, The influence of oxidation with air in comparison to oxygen in sodium carbonate solution on the surface composition of coals of different ranks, Fuel 85 (2006) 1016–1023.

DOI: 10.1016/j.fuel.2005.09.017

Google Scholar

[9] R. Pietrzak, H. Wachowska, Low temperature oxidation of coals of different rank and different sulphur content, Fuel 82 (2003) 705–713.

DOI: 10.1016/s0016-2361(02)00364-2

Google Scholar

[10] C.D. Wagner, W.H. Riggs, L.E. Davis, J.F. Moulder, G.E. Muilenberg (Eds. ), A Reference Book of Standard Data for Use in X-ray Photoelectron Spectroscopy, Perkin Elmer Corp, Eden-Prairie, (1979).

Google Scholar

[11] D. Briggs, M.P. Seah (Eds. ), Practical Surface Analysis by Augler and XPS, John Wiley & Sons, New York, (1983).

Google Scholar

[12] M. Kozłowski, R. Pietrzak, H. Wachowska, J. Yperman, Study of sulphur in oxidised coals by AP-TPR, J. Therm. Anal. Calorim. 75 (2004) 125–134.

DOI: 10.1016/s0016-2361(02)00199-0

Google Scholar

[13] T. Grzybek, R. Pietrzak, H. Wachowska, The comparison of oxygen and sulphur species formed by coal oxidation with O2/Na2CO3 or peroxyacetic solution. XPS studies, Energy Fuels 18 (2004) 804–809.

DOI: 10.1021/ef030153i

Google Scholar

[14] YANG Zhi-yuan, ZHOU An-ning, ZHANG Hong, et al [J] Journalo fChina University of Mining & Technology. 2010, 39( 1) : 98-103.

Google Scholar

[15] SHINN J H. From coal to single stage and two-stage products: A reactive model of coal structure [J] . Fuel, 1984, 63 (9): 1187-1196.

DOI: 10.1016/0016-2361(84)90422-8

Google Scholar