Adsorption Behavior of Polycarboxylate Superplasticizer on Cement Particles

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In this paper, the adsorption behavior of polycarboxylate superplasticizer (PC) on cement was examined. Through adsorption of PC, adsorption area of the molecule was calculated, and it is found that PC molecule would maintain curled shape when it was adsorbed on the surface of cement particles.

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2834-2838

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September 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] J. Plank, Schroefl, Christof, et al. Effectiveness of polycarboxylate superplasticizers in ultra-high strength concrete: The importance of PCE compatibility with silica fume [J]. Journal of Advanced Concrete Technology, 2009, 7(1): 5-12.

DOI: 10.3151/jact.7.5

Google Scholar

[2] Etsuo Sakai, Atsumu Ishida, Akira Ohta. New trends in development of chemical admixtures in Japan [J]. Journal of Advanced Concrete Technology, 2006, 4(2): 211-223.

DOI: 10.3151/jact.4.211

Google Scholar

[3] P. K. Mehta, P.C. Aitcin. Principles underlying production of high-performance concrete [J]. Cement Concrete and Aggregate, 1990, 12 (2): 71-73.

DOI: 10.1520/cca10274j

Google Scholar

[4] Habbaba Ahmad, Lange Alex, Plank Johann. Synthesis and performance of a modified polycarboxylate dispersant for concrete possessing enhanced cement compatibility [J]. Journal of Applied Polymer Science, in press.

DOI: 10.1002/app.38742

Google Scholar

[5] Hommer Herber. Interaction of polycarboxylate ether with silica fume [J]. Journal of the European Ceramic Society, 2009, 29(10): 1847-1853.

DOI: 10.1016/j.jeurceramsoc.2008.12.017

Google Scholar

[6] Kazuo Yamada, Tomoo Takaashi, Shunsuke Hanehara, et al. Effects of chemical structure on the properties of polycarboxylate-type superplasticizer [J]. Cement and Concrete Research, 2000, 30(3): 197-207.

DOI: 10.1016/s0008-8846(99)00230-6

Google Scholar

[7] M. Kinoshita, T. Nawa, M. Iida, et al. Effect of chemical structure on fluidizing mechanism of concrete superplasticizer containing polyethylene oxide graft chains [A]. Sixth CANMET/ACI International Conference on Superplasticizers and Other Chemical Admixtures in Concrete[C], Paris, France, 2000. 163-180.

DOI: 10.14359/9911

Google Scholar

[8] Kazuhiro Yoshioka, EI-ICHI Tazawa, Kenji Kawasi, et al. Adsorption characteristics of superplasticizers on cement component minerals [J]. Cement and Concrete Research, 2002, 32(10): 1507-1513.

DOI: 10.1016/s0008-8846(02)00782-2

Google Scholar

[9] Tung-Sheng Liao, Chao-Lung Huang, Yi-Shian Ye, et al. Effect of a carboxylic acid/sulfonic acid copolymer on the material properties of cementitious materials [J]. Cement and Concrete Research, 2006, 36(4): 650-655.

DOI: 10.1016/j.cemconres.2005.10.005

Google Scholar

[10] Andreas Griesser. Cement-superplasticizer interaction at ambient temperature [D]. Zurich: Swiss Federal Institute of Technology, 2002: 55-114.

Google Scholar

[11] Yutaka Nakajjima, Takahru Goto, Kazuo Yamada. A practical model for the interactions between hydrating Portland cements and poly-β-naphthalene sulfonate condensate superplasticizer[J]. Journal of the American Ceramic Society, 2005, 88(4): 850-857.

DOI: 10.1111/j.1551-2916.2005.00206.x

Google Scholar