Synthesis of Light Olefins from CO2 Hydrogenation on Fe/ZSM-5 Catalyst

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A Fe/ZSM-5 catalyst was prepared by impregnation method and evaluated in the synthesis of light olefins from CO2 hydrogenation. It is found that The conversion of CO2, the yield of light olefins and hydrocarbons content reach 82.42%, 12.65%, 0.4885mol respectively under the conditions as follow, mass concentration of ferric nitrate 9%, silica to alumina ratio 25, calcination temperature of the catalyst 500°C. By the studies of NH3 temperature programmed desorption, performance changes of the catalysts was analysis. A possible mechanism is proposed on the basis of mineral composition changes of Fe/ZSM-5 catalyst in the synthesis of light olefins through XRD analysis.

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463-466

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September 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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