Synthesis of the Mono-Disperse Magnetic Cross-Linked Composite Micro-Spheres Containing the Functional Group

Article Preview

Abstract:

The mono-disperse magnetic cross-linked composite micro-spheres containing carboxyl groups have been prepared by an improving method of emulsion polymerization in this paper. Firstly, Fe3O4 magnetic nanoparticles were synthesized by co-precipitation, and the Fe3O4 magnetic nanoparticles were modified by oleic acid. Secondly, DVB as cross-linker, SDBS as emulsifier and AIBN as initiator, the mono-disperse magnetic cross-linked composite micro-spheres were obtained in aqueous, and consisted of the copolymer of styrene and acrylic acid as shell and the Fe3O4 magnetic nanoparticles as core. The magnetic cross-linked micro-spheres would be the rudiment of the magnetic nanonetwork, and be expected to apply a great deal of fields in the future.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

50-53

Citation:

Online since:

October 2013

Authors:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Z. Bílková, M. Slováková, D. Horák and J. Lenfeld: J. Chromatogr B Analyt Technol Biomed Life Sci Vol. 770 (2002), p.177.

Google Scholar

[2] A. Kondo, H. Hiroko Kamura and K. Higashitan: J. Appl. Microbiol Biotechnol Vol. 41 (1994), p.99.

Google Scholar

[3] G. D Moeser, W. H. Green, P. E. Laibinis, P. Linse and T.A. Hatton: Langmuir Vol. 20 (2004), P. 5223.

Google Scholar

[4] H. Yu, J.W. Raymonda, T.M. Mcmahon and A. A Campagnari: Biosens. Bioelectron. Vol. 14 (2000), p.829.

Google Scholar

[5] A. Garg and E. Matijevic: J. Colloid Interface Sci Vol. 126 (1988), p.243.

Google Scholar

[6] N. Kawahashi and E. Matijevic: J. Colloid Interface Sci Vol. 138 (1990), p.534.

Google Scholar

[7] L.P. Ramríez and K. Landfeste: Chem. Phys Vol. 204 (2003), p.22.

Google Scholar

[8] T.Y. Cao, Q. P Liu, and J.S. Hu: Synthetical Theory, Properties and Application of polymer latex (Chemical industry press, Beijing 1997).

Google Scholar

[9] J. Ugelstad, P. C. Mork,  R. Schmid, T. Ellinqsen and A. Berqe : Polym Int Vol. 30 (1993), p.157.

Google Scholar

[10] H. Shiho and N. Kawahashi: J. Colloid Interface Sci Vol. 226 (2000), p.91.

Google Scholar

[11] W. Y. Zhao and Y. J. Wang: Chemistry of Functional Polymer Materials ( Chemical industry press, Beijing, 1996).

Google Scholar

[12] A.V. Chernyshev,  A. E. Soini, I.V. Surovtsev and V. P. Maltsev: Polym Sci, Part A: Polym Chem Vol. 35 (1997), p.1799.

DOI: 10.1002/(sici)1099-0518(19970715)35:9<1799::aid-pola20>3.0.co;2-#

Google Scholar

[13] Wang,Y. J., Liu, J. M., Yuan, C. D. Liu, J. F., Xin,T. , Cao, T. Y.; Studyof kinetics and mechanisms of dispersion polymerization of 2-hydreopropylmethacrylate. , Polym. Int. 50, 326-330, (2001).

Google Scholar

[14] X. Q. Liu, Y. P. Guan, Z. Y. Ma and H. Z. Liu: Langmuir Vol. 20 (2004), p.10278.

Google Scholar

[15] Z. L. Liu, Z. H. Ding, K. L. Yao, J. TAO, G. H. Du AND Q. H. Lu: J. Magn. Magn. Mater Vol. 265 (2003), 98.

Google Scholar