Photoluminescence Properties of ZnO Thin Film Prepared by Sol-Gel Route

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Temperature dependent photoluminescence (PL) properties of ZnO thin film prepared by sol-gel route were investigated. The excitonic-related emission peak at 3.336 eV dominates the spectra, and is attributed to the recombination of excitons bound to structural defects (DBX). Moreover, its thermal activation energy is 5.7 meV obtained by using least-squares fitting method. Compared to its larger localization energy, we propose that there exists a nonradiative relaxation path with energy released during the formation of DBX. The observed peak position of blue emission is in line with theoretical energy interval between the interstitial zinc level and valence band.

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411-415

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October 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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