Recovery Value Metals from Mixed Spent Li-Ion Batteries

Abstract:

With the rapid development and wide application of Li-ion batteries, cathode materials containing value metals Co, Ni and Mn are blended by several kind of metal oxide presently for pursuing high safe stability and low cost. The composition of spent Li-ion batteries has become complicated and optimum leaching condition varied. In this paper, leaching process for the mixture of pure LiCoO₂ and Li (Ni_1/3Co_1/3Mn_1/3)O₂ was studied. With an increase in component of LiCoO₂ in mixed materials, the optimum leaching condition varied as: temperature from 60°C to 90°C, H₂O₂ addition amount from 0.54 to 0.75ml/g and liquid-solid ratio from 10 to 20. According to this result, a real mixed spent batteries materials was recovered by being leached in 2M H₂SO₄ at temperature of 90°C, liquid-solid ratio 20 and 0.6ml/g H₂O₂added. The leaching efficiencies of Co, Ni, Mn, Li were 96.88%, 93.71%, 92.12%, 99.43% respectively. Cu, Al and Fe in solution were removed by precipitation and solvent extraction. Finally, Ni, Co, Mn were extracted by D2EHPA for separating with Na⁺ and other impurities, which is used as a raw materials for preparation of cathode active materials in batteries.

• Periodical: Applied Mechanics and Materials (Volume 540)
• Pages: 267-271
• DOI: https://doi.org/10.4028/www.scientific.net/AMM.540.267
• Online since: April 2014
• Authors: Xin Liu, Lin Yan Li*, Fan Yun Zeng, Xue Jun Wang, Sheng Ming Xu
• Keywords: Cobalt, Leaching, Manganese, Mixed Spent Li-Ion Battery, Nickel, Recovery

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