Geological and Geochemical Characteristics of Chang 7 Uranium-Enriched Hydrocarbon Source Rocks in Ordos Basin and the Possible Reasons for its Formation

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The Ordos basin Chang 7 hydrocarbon source rocks are the most important rock strata of premium oil source formed during the largest lake flood period of the terrestrial lacustrine. Our study found that the bottom of the rocks are rich in radioactive uranium. Element geochemical studies showed that the rocks are also rich in C, S, P, Cu, V, Mo and other pro-life elements but not rock-forming minerals-related lithophile elements Li, Zr, Sr, etc. Their uranium content has obvious positive correlation with phosphorus, sulfur, iron, organic carbon content, but not with major rock-forming elements. Petrography and scanning electron microscopy revealed the rocks are rich in pyrite, phosphate rock and striped organic matters. These features indicate that uranium enrichment and the presence of these minerals are closely related. The significantly positive correlation of the ratio of uranium to trace elements such as U/ (U+Ni) and U/Sc indicates that anoxic environment played an important role in uranium enrichment. Electron microprobe analysis found for the first time uranium ore and independent titanium-containing uranium minerals in phosphate rocks in the area. α radiation photography and sequential chemical extraction found that 50% of uranium present as independent uranium and its isomorphic minerals in the phosphate rocks, 20% is absorbed to pyrite and organic matter, and less than 10% is absorbed on clay minerals.

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16-22

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May 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Liu C.Y., Wu B.L. and Qiu X.W., 2007. Characteristics of mineralization domain coexisting various energy resources in the same basin in the middle East Asian and the dynamic environment of its formation. Science in China (D Series) 37 (supplement I), 1-15.

Google Scholar

[2] Liu J.S., 1992. The Geological characteristics of carbonate-siliceous-argillitic type uranium deposits in south China. Geological and Mineral Resources Research 7(1), 103-110.

Google Scholar

[3] Levsm and Filer J.K., 2004. Assessing the impact to black shale processes on REE and the U Pb isotope system in the southern Appeal chain Basin. Chemical Geology 206, 393-406.

DOI: 10.1016/j.chemgeo.2003.12.012

Google Scholar

[4] Levsm and Filer K. T., 2008. Orogenesisvs diagenesis: Can we use organic rich shale stosinterpret the tectonic volition of a depositional basin? Earth Science Reviews 86, 1-14.

DOI: 10.1016/j.earscirev.2007.07.001

Google Scholar

[5] Doveton J.H. and Merriam D.F., 2004. Borehole petro physical chemostratigraphy of Pennsylvanian black shale in the Kansas subsurface. Chemical Geology 206, 249-258.

DOI: 10.1016/j.chemgeo.2003.12.027

Google Scholar

[6] Kochenovav and Babur in GN, 2002. The Para genesis of organic matter phosphorus and uranium in marine sediments. Lithology and Mineral Resources 37, 107-120.

Google Scholar

[7] Galindoc, Mouginl, Fakhis, Nourreddinea, Lamgharia and Hannacheh, 2007. Distribution of naturally occurring radio nuclides (U, Th) in Timahdit black shale (Morocco). Journal of Environmental Radioactivity 92, 41-54.

DOI: 10.1016/j.jenvrad.2006.09.005

Google Scholar

[8] Fisher Q.J., 2001. Palate environmental control sontheunanium distribution in an Upper Carboniferous black shale (Gastrologer assister Marine Band) and associated strata; England. Chemical Geology 175, 605-621.

DOI: 10.1016/s0009-2541(00)00376-4

Google Scholar

[9] Fisher Q.J., Cliff R.A. and Dodson M.H., 2003. U-Pb systematizes of an Upper Carboniferous black shale from South Yorkshire, UK. Chemical Geology 194, 331-347.

DOI: 10.1016/s0009-2541(02)00383-2

Google Scholar

[10] Lu H.J. and Wang J., 2005. Ore potential and modes of occurrence of associated elements in lower cambran black shale of Western Xhejiang, Mineral Deposits 24(5), 567-574.

Google Scholar

[11] Yang H. and Zhang W.Z., 2005. The leading effects of the premium Chang 7 source rocks of Yanchang formation in Ordos Basin during the enrichment of low-penetrating oil-gas accumulation: geology and geochemistry, Geochemistry 34(2), 147-154.

Google Scholar

[12] Zhang W.Z., Yang H. and Li J.F., 2006. Leading effect of high-class source rock of Chang 7 in Ordos Basin on enrichment of low-permeability oil-gas accumulation–hydrocarbon generation and expulsion mechanism. Petroleum Exploration and Development 33(3), 289-193.

Google Scholar

[13] Zhang W.Z., Yang H., Yang Y.H., Kong Q.F. and Wu K., 2008. Petrology and element geochemistry and development environment of Yanchang formation Chang 7 high quality source rocks in Ordos Basin. Geochemical 37(1), 59-63.

Google Scholar

[14] Li Y.H., Lin F.X., Du J.L., Huang J.X. and Cheng D.X., 2007. Sedimentary features of Yanchang formation Chang 8 shallow delta Ordos Basin Triassic. Oil and gas exploration 19-23.

Google Scholar

[15] Qin Y., Zhang W.Z., Peng P.A. and Zhou Z.J., 2009. Occurrence and concentration of uranium in the hydrocarbon source rocks of Chang 7 member of Yanchang formation in Ordos Basin. Acta Petrologica Sinica 25(10), 2469-2476.

Google Scholar

[16] Min M.Z. and Zhang F.S., 1992. Introduction to causes of uranium mineral. Atomic Energy Press.

Google Scholar