Characterization and Hydrolization of Acetate Fiber by Sodium Hydroxide

Article Preview

Abstract:

Acetate fiber arouses a great interest by the people with a soft silk feel, bright color, weather resistant and good drapability. Acetate fiber is obtained by reacting cellulose with glacial acetic acid in the presence of acetic anhydride a trace of sulfuric acid in refluxing methylene chloride. The ester group (-COO-) in acetate fiber is converted to hydroxyl group (–OH) after hydrolysis in sodium hydroxide aqueous solution. This research explores the hydrolization of acetate fiber in sodium hydroxide solution and characterization used staining method with reactive dyes. The optimum technology of hydrolysis is sodium hydroxide mass fraction is 6g/L, the time of hydrolysis is 30min at the room temperature. The strength of the hydrolyzed fiber is decline and the moisture regain is increased compared with the acetate fiber.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

472-475

Citation:

Online since:

September 2014

Authors:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Yamashita Y, Endo T. Deterioration behavior of cellulose acetate films in acidic or basic aqueous. J Appl Polym Sci, Vol. 9(2004), p.3354.

DOI: 10.1002/app.13547

Google Scholar

[2] Adebajo M O, Frost R L, Kloprogge J T, et al. Raman spectroscopic investigation of acetylation of raw cotton. Spectrochimica Acta, Part A, Vol. 6 (2006), p.448.

DOI: 10.1016/j.saa.2005.07.045

Google Scholar

[3] Miyamoto T, Sato Y, Shibaya T. J Polym Sci. Vol. 2(1985), p.1373.

Google Scholar

[4] Xiao Changfa, Liu Zhaofeng: Microvoid formation of acrylic copolymer cellulose acetate blends fibers, Journal of Applied Polymer Science. Vol. 41 (1990), p.439.

DOI: 10.1002/app.1990.070410136

Google Scholar

[5] J. Koh. Dyes and Pigments. Vol. 64(2005), p.9.

Google Scholar