Determination of 1-methyl-3-butyl Imidazole Nitrate in Ethanol

Abstract:

1-methyl-3-butyl Imidazole chloride is synthesized by 1–methyl imidazole and chlorinated n-butane. BMINO₃ ionic liquid is synthesized by BMIC and NaNO₃ in the acetone. The structure is characterized by infrared spectrometer. UV-spectrum curve is doned by scanning ionic liquid in 200~400nm wavelength range. The ionic liquid used in the experiment has obvious absorption in 200~400nm wavelength range, and the maximum absorption wavelength which is determined by ultraviolet spectrometry method is 228nm. Linear regression equation is y =0.02317x+0.06483. Correlation coefficient is 0.9995, which is high related degree between the absorbance value and the solution concentration. The recovery rate is between 99.8%~102%.

• Periodical: Applied Mechanics and Materials (Volume 685)
• Pages: 106-109
• DOI: https://doi.org/10.4028/www.scientific.net/AMM.685.106
• Online since: October 2014
• Authors: Qi Yang*
• Keywords: BMINO₃ Ionic Liquid, Determination, Ethanol

References

[1] T. Welton, Chem. Rev., 1999, 99, 2071–(2083).

[2] T. Koddermann, C. Wertz, A. Heintz and R. Ludwig, Angew. Chem., Int. Ed., 2006, 45, 3697–3702.

[3] M. J. Earle, U. Hakala, C. Hardacre, J. Karkkainen, B. J. McAuley, D. W. Rooney, K. R. Seddon, J. M. Thompson and K. Wahala, Chem. Commun., 2005, 903–905.

DOI: 10.1039/b413132k

[4] J. Y. Weng, C. M. Wang, H. R. Li and Y. Wang, Green Chem., 2006, 8, 96–99.

[5] H.M. Luo, G. A. Baker, J. S. Lee, R. M. Pagni and S. Dai, J. Phys. Chem. B, 2009, 113, 4181–4183.

[6] A. Heintz, J. Chem. Thermodyn., 2005, 37, 525–535.

[7] J. F. Huang, H. M. Luo, C. D. Liang, I. W. Sun, G. A. Baker and S. Dai, J. Am. Chem. Soc., 2005, 127, 12784–12785.

[8] A. Arce, M. J. Earle, H. Rodriguez, K. R. Seddon and A. Soto, Green Chem., 2009, 11, 365–372.

[9] L. P. N. Rebelo, J. N. C. Lopes, J. Esperanca, H. J. R. Guedes, J. Lachwa, V. Najdanovic-Visak and Z. P. Visak, Acc. Chem. Res., 2007, 40, 1114–1121.

DOI: 10.1021/ar7000556

[10] C. M. Wang, L. P. Guo, H. R. Li, Y. Wang, J. Y. Weng and L. H. Wu, Green Chem., 2006, 8, 603–607.

[11] X. Han and D. W. Armstrong, Acc. Chem. Res., 2007, 40, 1079–1086.

[12] A. Arce, M. J. Earle, H. Rodriguez and K. R. Seddon, J. Phys. Chem. B, 2007, 111, 4732–4736.

[13] J. L. Anderson, J. Ding, T. Welton and D. W. Armstrong, J. Am. Chem. Soc., 2002, 124, 14247–14254.

[14] J. L. Anderson, D. W. Armstrong and G. T. Wei, Anal. Chem., 2006, 78, 2892–2902. T.

[15] D. W. Armstrong, L. F. He and Y. S. Liu, Anal. Chem., 1999, 71, 3873–3876.

[16] J. S. Wilkes, Green Chem., 2002, 4, 73–80.

[17] J. Dupont, C. S. Consorti and J. Spencer, J. Braz. Chem. Soc., 2000, 11, 337–344.

[18] A. Stark, J. Ranke, O. Braun, P. Behrend, A. Müller, B. Jastorff, and B. Ondruschka, Green Chem., in preparation.

DOI: 10.1039/b808532c

[19] R. de Souza, V. Rech, and J. Dupont, Adv. Synth. Catal., 2002, 344, 153.