Research on New Pervaporation Membranes and the Effect of Treatment of Wastewater Containing Phenol

Article Preview

Abstract:

The pervaporation membranes were prepared by using poly dimethyl siloxane (PDMS) as precursor, toluene as solvent, triethoxy methylsilane as cross linker, dibutyltin dilaurate as catalyst. The PDMS membranes were evaluated with permeation flux and separation factor. The effects of cross linker dosage and the operation parameters during the process of pervaporation were investigated. It was shown from the results that: The selectivity of the membranes increased while the permeation flux first increased and then decreased as the linker dosage increased; the selectivity of the membranes decreased while the permeation flux increased as the feed temperature increased; the selectivity and the permeation flux of the membranes both increased as the feed concentration increased; the selectivity and the flux also both increased as the feed flow rate increased; the selectivity increased while the permeation flux decreased as the separation press increased. When the proportion of the PDMS, solvent, cross linker and catalyst were immobile, The permeation flux and separation factor could be 98mg/(m2·h) and 5.12 when the feed temperature was 60°C, feed concentration was 0.5g/L, feed flow rate was 0.6L/min and separation press was 6KPa.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

466-469

Citation:

Online since:

December 2014

Authors:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Bakker A, Fasano J B, et al. Pinpoint mixing problems with lasers and simulation software [J]. Chem Eng, 1994, 1: 94-100.

Google Scholar

[2] Mann R, Pillai S K, et al. Computational fluid mixing for stirred vessels progress from seeing to believing [J]. Chem Eng J, 1995, 59: 39-50.

DOI: 10.1016/0923-0467(95)02998-2

Google Scholar

[3] Mann R, Williams R A, et al. Development of mixing models using electrical resistance tomography [J]. Chem Eng Sci. 1997, 52(13): 2073-(2085).

DOI: 10.1016/s0009-2509(97)00035-3

Google Scholar

[4] Mckee S L, Williams R A, et al. Development of solid-liquid mixing models using tomography techniques [J]. Chem Eng J, 1995, 56: 101-107.

Google Scholar

[5] Wang S J, Dyakowski C G, et al. Real time capacitance imaging of bubble formation at the distributor of a fluidized bed [J]. Chem Eng J, 1995, 56: 95-100.

DOI: 10.1016/0923-0467(94)02916-4

Google Scholar

[6] Peng M, Vane L M, Liu S X. VOC removal from contaminated groundwater through membrane pervaporation [J]. Journal of Environmental Sciences, 2003, 15 (6): 821-826.

Google Scholar