Research on Mass Transfer Process of AMD Corrosion Reaction and Model of Deposition Calculation for Acid Load

Article Preview

Abstract:

Evaluate the influence instability by AMD corrosion based on the slope of a large-scale sulfide mine. On the basis of the corrosion experiment, carry out the researches on the solution ion change rules before vs. after evaluation; set up the mathematical expression of the AMD corrosion amount through the analysis of the corrosion mass transfer; establish the acid load deposition calculation model by AMD based on the oxidation mechanism analysis of sulfide ores; the engineering application indicates that, at the puddle, wells, sump and fracturing catchment areas, AMD acid load deposition was accumulated and the acid load is significantly higher than other area which is up to 500 mg/L; on the slope surface, as the time period affected by AMD is shorter, acid load is between 166~300mg/L; for the streams far away from mines, the acid load, less than 20mg/L, is at the minimum level. The model calculation result is consistent with the spot reality.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

2823-2829

Citation:

Online since:

January 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Jun Wang, Fucai Yin, Xiaochun Xu. Study of AMD from the discarded rocks in the Xinqiao pyrite, Tongling [J]. Journal of Hefei University of Technology (Natural Science), 2007, 30(3): 367-370. (in Chinese).

Google Scholar

[2] Renjun Xiang, Liyuan Chai, Qingmei Zhang, et al. Ions distributional characteristics of wet precipitation in typical acid rain of China [J]. Journal of Central South University (Science and Technology), 2012, 43(1): 38-45. (in Chinese).

Google Scholar

[3] Xiating Feng, Chuanying Wang, Sili Chen. Testing study and real-time observation of rock meso-cracking process under chemical erosion [J]. Chinese Journal of Rock Mechanics and Engineering, 2002, 21(7): 935-939. (in Chinese).

Google Scholar

[4] Liansheng Tang, Pengcheng Zhang. Influence of Chemical Damage of Water on Elastic Modulus of Rocks [J]. Acta Scientiarum Naturalium Universitatis Sunyatseni, 2000, 39(5): 126-128. (in Chinese).

Google Scholar

[5] Lichun Jiang, Shenhua Yin. Slope Instability in high sulfur open mine by Acid Mine Drainage Erosion. [C]. The 2nd SREE Conference on Hydraulic Engineering (CHE 2013), 2013, 55-61.

DOI: 10.1201/b16025-11

Google Scholar

[6] Lichun Jiang, Yong Wen. Damage constitutive model of sandstone during corrosion by AMD [J]. Journal of Central South University (Science and Technology), 2011, 42(11): 3502-3506. (in Chinese).

Google Scholar

[7] Lichun Jiang, Yong Wen, Aixiang Wu. Mesoscopic mechanical effect on sandstone corroded by acid mine drainage [J]. Journal of the China Coal Society, 2012, 37(6): 931-935. (in Chinese).

Google Scholar

[8] Xiating Feng, Wuxiu Ding Coupled chemical-stress on rock fracturing process [M]. Beijing: Science Press, (2010).

Google Scholar

[9] Lichun Jiang, Jiasheng Chen, Aixiang Wu. Erosion characteristic of slope sandstone soaking in acid mine drainage [J]. Journal of Central South University of Technology (English Edition), 2007, 14(2): 236-242.

DOI: 10.1007/s11771-007-0047-7

Google Scholar

[10] Nan Wang, Xiaoyun Yi, Zhi Dang, et al. Investigation on Mechanism of Pyrite Oxidation in Acidic Solutions [J]. Environmental Science, 2012, 33(11): 3916-3921. (in Chinese).

Google Scholar

[11] Mihaela Simaet. Sulfide oxidation and acid mine drainage formation within two active tailings impoundments in the Golden Quadrangle of the Apuseni Mountains, Romania [J]. Journal of Hazardous Materials, 2011(189): 624–639.

DOI: 10.1016/j.jhazmat.2011.01.069

Google Scholar

[12] Jianchun Guo, Chaogang Chen, Jinzhou Zhao. Research and application of sandstone matrix acidizing model [J]. Journal of Oil and Gas Technology (J. JPI), 2005, 27(4): 485-488.

Google Scholar

[13] Yanjun Du, Mingli Wei, Krishna R. Reddy. Effect of acid rain pH on leaching behavior of cement stabilized lead-contaminated soil [J]. Journal of Hazardous Materials, 2014, 2(271): 2-2.

DOI: 10.1016/j.jhazmat.2014.02.002

Google Scholar

[14] Ata Akcil, Soner Koldas. Acid Mine Drainage (AMD): causes, treatment and case studies [J]. Journal of Cleaner Production, 2006(14): 1139-1145.

DOI: 10.1016/j.jclepro.2004.09.006

Google Scholar