Process Optimization and Characterization of Copper Oxide/Zeolite for Heterogeneous Catalytic Wet Oxidation of Dyeing Wastewater

Article Preview

Abstract:

Waste coal fly ash was used, as a cheap and handy material, to synthesize zeolite.The synthesized zeolite was then taken, as a carrier, to load CuO by dipping method for heterogeneous catalytic wet oxidation of acid bright red GR wastewater. The optimal process parameters of CuO loading were determined by orthogonal test. The comparison of XRD patterns of zeolite and CuO/zeolite displayed that CuO was successfully loaded on the zeolite.The SEM morphology of CuO/zeolite revealed that the cotton shape structure with more loose surface of CuO/zeolite was obtained compared with the SEM morphologies of fly ash and synthesized zeolite. The experimental results of water treatment showed that high CODCr and chroma removal rates of 88.27% and 99.97% were achieved by the prepared CuO/zeolite sample,respectively.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

73-78

Citation:

Online since:

January 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Carrian Richard S, Ghosh Arun, Dyer Jolon M. The effects of zeolite molecular sieve based surface treatments on the properties of wool fabrics. Applied Surface Science, 287 (2013) 467-472.

DOI: 10.1016/j.apsusc.2013.09.181

Google Scholar

[2] Ahmed Muthanna J, Theydan Samar K. Modeling of propane separation from light hydrocarbons by adsorption on 4A molecular sieve zeolite. Journal of Natural Gas Science and Engineering, 18(2014) 1-6.

DOI: 10.1016/j.jngse.2014.01.012

Google Scholar

[3] Corina Bradu, Ligia Frunza, Nicoleta Mihalche, Sorin-Marius Avramescu and Ion Udrea. Removal of reactive black 5 azo dye from aqueous solutions by catalytic oxidation using CuO/ A2O3 and NiO/A2O3. Applied Catalysis B: Environmental, 96(2010).

DOI: 10.1016/j.apcatb.2010.03.019

Google Scholar

[4] Jianxin Chen. Optimization Methods of Technology and formula. Hangzhou: Zhejiang Science and Technology Press, China, (1986).

Google Scholar

[5] Tanaka H, Sakai Y, Hino R. Formation of Na-A and –X zeolite from waste solutions in conversion of coal fly ash to zeolites. Materials Research Bulletin, 307(2002) 1883-1884.

DOI: 10.1016/s0025-5408(02)00861-9

Google Scholar

[6] Hidekazu T, Hajime E, Satoshi F. Two-step process for synthesis of single phase Na-A zeolite from coal fly ash by dialysis. Fuel, ; 85(2006) 1329-1334.

DOI: 10.1016/j.fuel.2005.12.022

Google Scholar