Benzoylformamides as New Photocaged Bases for Free Radical Photopolymerization

Rui Xin Xu; Li Jie Wang; Ming Hui He

doi:10.4028/www.scientific.net/AMM.731.573

Paper Titles

Synthesis of Polyfunctional Castor Oil-Based Polyurethane Acrylate by the Auxiliary of Thiol-Ene Click Reaction
p.553

Studies on the Relations between Dispersivity and Covering Property of White Water-Based Ink
p.558

Modification of Soy Protein Isolate-Polyethylene Glycol Composite Packaging Films with Ethylene Glycol
p.565

Preparation and Characterization of Poly(Dimethyl Diallyl Ammonium Chloride)/Modified SiO₂ Spherical Brushes
p.569

Benzoylformamides as New Photocaged Bases for Free Radical Photopolymerization
p.573

Preparation and Properties of Poly(L-Lactid Acid)/Organo-Montmorillonite Composites by Solution Casting Method
p.578

Study on Aluminium Coating Process of Holographic Anti-Counterfeiting Cigarette Packet
p.584

Study on Shrinkage of Cured Volume for UV-Curing Coatings
p.588

Synthesis of Silver Nanowires and its Application on Stretchable Conductor
p.593

HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 731Benzoylformamides as New Photocaged Bases for Free...

Benzoylformamides as New Photocaged Bases for Free Radical Photopolymerization

Abstract:

Benzoylformamide (BFA) derivatives are proposed as new photocaged bases. Initially their abilities as photoinitiators to initiate the free radical photopolymerization of acrylic monomers have been investigated. Next, we detail regarding the model photopolymerization in the presence of BFA-dBA (N,N-Dibenzyl-2-oxo-2-phenylacetamide) as a photocaged base. In combination with a benzoyl peroxide initiator, BFA-dBA is able to initiate the amine-mediated redox photopolymerization of acrylates, and photopolymerization rate is markedly enhanced.

You might also be interested in these eBooks

Advanced Printing and Packaging Materials and Technologies

View Preview

Info:

Periodical:

Applied Mechanics and Materials (Volume 731)

Pages:

573-577

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.731.573

Citation:

Cite this paper

Online since:

January 2015

Authors:

Rui Xin Xu, Li Jie Wang, Ming Hui He*

Keywords:

Free Radical Photopolymerization, Peroxide, Photocaged Base, Redox

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] K. Suyama, H. Araki and M. Shirai: J. Photopolym. Sci. and Technol. Vol. 19 (2006), p.81.

Google Scholar

[2] K. Arimitsu and R. Endo: J. Photopolym. Sci. and Technol. Vol. 23 (2010), p.135.

Google Scholar

[3] X. Sun, J. P. Gao and Z. Y. Wang: J. Am. Chem. Soc. Vol. 130 (2008), p.8130.

Google Scholar

[4] C. E. Hoyle, A. B. Lowe and C. N. Bowman: Chem. Soc. Rev. Vol. 39 (2010), p.1355.

Google Scholar

[5] T. Ibe, R. B. Frings, A. Lachowicz, S. Kyo and H. Nishide: Chem. Commun. Vol. 46 (2010), p.3475.

Google Scholar

[6] K. Suyama and M. Shirai: Prog. Polym. Sci. Vol. 34 (2009), p.194.

Google Scholar

[7] M. He, X. Huang, Z. Zeng and J. Yang: Macromolecules. Vol. 46 (2013), p.6402.

Google Scholar

[8] M. He, X. Huang, Z. Zeng and J. Yang: J. Polym. Sci. Part A: Polym. Chem. Vol. 51 (2013), p.4515.

Google Scholar

[9] M. He, X. Huang, Y. Huang, Z. Zeng and J. Yang: Polymer. Vol. 53 (2012), p.3172.

Google Scholar

[10] T. Lavy, Y. Sheynin and M. Kaftory: Eur. J. Org. Chem. Vol. 2004 (2004), p.4802.

Google Scholar

[11] J. L. Jesuraj and J. Sivaguru: Chem. Commun. Vol. 46 (2010), p.4791.

Google Scholar

[12] A. Natarajan, J. T. Mague and V. Ramamurthy: J. Am. Chem. Soc. Vol. 127 (2005), p.3568.

Google Scholar

[13] A. J. Ayitou, J. L. Jesuraj, N. Barooah, A. Ugrinov and J. Sivaguru: J. Am. Chem. Soc. Vol. 131 (2009), p.11314.

DOI: 10.1021/ja9050586

Google Scholar

[14] U. Zehavi: J. Org. Chem. Vol. 42 (1977), p.2821.

Google Scholar

[15] Y. Gnanou and M. Fontanille, Organic and physical chemistry of polymers, Wiley. com, (2008).

Google Scholar

[16] S. Chiba, L. Zhang and J-Y. Lee: J. Am. Chem. Soc. Vol. 132 (2010), p.7266.

Google Scholar