Experimental Comparative Study of Carbon Nanotubes Synthesized from CO and CH4 by Flame Pyrolysis Method

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In this paper, carbon nanotubes (CNTs) were synthesized by catalytic pyrolysis of CO and CH4 using flame pyrolysis method. The effects of using the two different carbon sources to the preparation of CNTs with all other conditions being equal were comparatively studied. The results showed that: the morphology of CNTs synthesized from different carbon source gases had certain difference. Higher yield of carbon nanotubes could be synthesized using CH4 as carbon source than using CO. At the same time, the former had less number of tube walls and the vascular bundles arranged more neatly. Synthetizing CNTs via catalytic decomposition of CH4 had more advantages than using CO by flame pyrolysis method.

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55-60

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April 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] Iijima S. Helical microtubules of graphitic carbon. Nature, 1991, 354: 56-58.

DOI: 10.1038/354056a0

Google Scholar

[2] Zhang Q, Huang J Q, Zhao M Q, et al. Macro Preparation and Industrialization of Carbon Nanotubes[J]. SCIENTIA SINICA: Chimica, 2013, 06: 641-666 (in Chinese).

Google Scholar

[3] Dillon A C, Jones K M, Bekkedahl T A, et al. Storage of Hydrogen in Single-walled Carbon Nanotubes[J]. Nature, 1997, 386: 377-379.

DOI: 10.1038/386377a0

Google Scholar

[4] Heer WA, Chatelain A, Ugarte D. A Carbon Nanotube Field-emission Source [J]. Science, 1995, 270(5239): 1179-80.

DOI: 10.1126/science.270.5239.1179

Google Scholar

[5] Che G, Lakshmi BB, Fisher ER, et al. Carbon Nanotubule Membranes for Electrochemical Energy Storage and Production [J]. Nature, 1998, 393(1869): 18-21.

DOI: 10.1038/30694

Google Scholar

[6] Choi E S, Brooks J S, Eaton D L, et al. Enhancement of Thermal and Electrical Properties of Carbon Nanotube Polymer Composites by Magnetic Field Processing[J]. J. Appl. Phys, 2003, 94(9): 6034-6039.

DOI: 10.1063/1.1616638

Google Scholar

[7] Iijima S, Ichihashi T. Single-Shell Carbon Nano-tubes of 1nm Diameter [J]. Nature (London), 1993, 363: 603.

Google Scholar

[8] Guo T, Nikolaev P, Thess A, et al. Catalytic Growth of Single-Walled Nanotubes by Laser Vaporization [J]. Chemical Physics Letters, 1995, 243(1-2): 49-54.

DOI: 10.1016/0009-2614(95)00825-o

Google Scholar

[9] Kong Jing, Cassell, Alan M. Chemical Vapor Deposition of Methane for Single-Walled Carbon Nanotubes [J]. Chemical Physics Letters, 1998, 292(4-6): 567-574.

DOI: 10.1016/s0009-2614(98)00745-3

Google Scholar

[10] Qiu J, An Y, Zhao Z, et al. Catalytic synthesis of single-walled carbon nanotubes from coal gas by chemical vapor deposition method[J]. Fuel Processing Technology, 2004, 85(8-10): 913- 920.

DOI: 10.1016/j.fuproc.2003.11.033

Google Scholar

[11] Vander Wal R L, Ticich T M., Curtis V E. Substrate- support interactions in metal-catalyzed carbon nanofiber growth [J]. Carbon, 2001, 39(15): 2277-2289.

DOI: 10.1016/s0008-6223(01)00047-1

Google Scholar

[12] Li M, Saito K, Li T. Synthesis of multi-walled carbon nanotubes using methane/air diffusion flames [J]. Proceedings of the Combustion Institute, 2002, 29(1): 1087-1092.

DOI: 10.1016/s1540-7489(02)80137-7

Google Scholar

[13] Zhou Qiuling, Li Chunzhong, Gu Feng, et al. Flame synthesis of carbon nanotubes with high density on stainless steel mesh [J]. Journal of Alloys and Compounds, 2007, 1-6.

DOI: 10.1016/j.jallcom.2007.09.021

Google Scholar

[14] Liu Y C, Sun B M, Zhao H F, et al. Study and Analysis of Factors Affecting on Synthesis of Carbon Nanotubes from V-type Pyrolysis Flame[J]. Journal of Synthetic Crystals, 2009, 38(6): 1506-1510(in Chinese).

Google Scholar

[15] Sun B M, Cao W H, Guo Y H, et al. Growth of Directional Carbon of Nanotubes by Flame Pyrolysis[J]. Journal of Synthetic Crystals, 2013, 40(009): 1773-1778(in Chinese).

Google Scholar