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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vols. 754-755Effect of Carbon Molecular Sieve (CMS)...

Effect of Carbon Molecular Sieve (CMS) Concentration on Mixed Matrix Membranes (MMMs) Performance for Carbon Dioxide Removal

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Abstract:

Different compositions of carbon molecular sieve (CMS) were incorporated in polyethersulfone (PES) matrix to fabricate mixed matrix membranes (MMMs) by solution casting method. The characterization was carried out using field emission scanning electron microscopy (FESEM) analysis to investigate the morphology of membrane. FESEM images showed acceptable contacts between the filler particles and the polymer chains. The performance of the developed membrane is analyzed by single gas permeation measurement of high purity CO₂ and CH₄. Both CO₂ permeance and CO₂/CH₄ selectivity increased with CMS loadings as compared to pure PES membrane. Experimental results showed that the highest value of CO₂ permeance (66.71 GPU) and CO₂/CH₄ selectivity (10.94) can be achieved with 30 wt. % loading of CMS particles. This can be credited to size discrimination of CMS pores that falls between CO₂ and CH₄ kinetic diameters.

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Advanced Materials Engineering and Technology III

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Periodical:

Applied Mechanics and Materials (Volumes 754-755)

Pages:

869-873

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.754-755.869

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Online since:

April 2015

Authors:

Rizwan Nasir, Hilmi Mukhtar, Maizatul Shima Shaharun, Zakaria Man

Keywords:

Carbon Molecular Sieves, CO₂ Permeance, CO₂/CH₄ Selectivity, Mixed Matrix Membrane

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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